Enthalpy of Formation of Gallium-Germanium-Tin Liquid Alloys: Evaluation of the Liquidus Surface of the Phase Diagram from Excess Functions of Mixing

With a differential high temperature Calvet calorimeter, the enthalpies of formation of Ga-Ge-Sn liquid alloys have been measured at 703, 798, 895, 1000 and 1230 K in the whole concentration area. The experimental results are compared with those obtained by using an interpolation relation on the basis of the excess functions of mixing of the bordering binary systems. The interpolation relation is used to calculate the partial excess functions and to determine the position of the liquidus surface of the Ga-Ge-Sn phase diagram: the experimental and calculated values agree fairly.

Excess energy–volume and cohesive energy density coefficients for binary systems. Comparison with constant pressure functions

Excess energy–volume and cohesive energy density coefficients have been calculated for the hexane + perfluoro-hexane, water + DMSO, water + tert-butanol, water + methanol, water + acetonitrile, and methanol + DMSO Systems. These parameters are compared with other constant pressure excess functions of mixing for these binary systems, and it is proposed that they represent additional criteria for the classification of liquid mixtures.