Study review of the electrical power generation: Wave energy converting device system from the swell

This paper presents the design of an innovative wave energy converter, namely, Electrical Power Generation - WEC Device System from the Swell, abbreviated as WECFS. This WEC device has been registered for a patent in the Spanish Office of the Patents and Brands (OEPM) with the registration number of the innovative utility model-Patent Model: 202131440(5). The study reported in this paper endeavours to demonstrate the technical feasibility, functional mechanical-kinematic behaviour, and the performance of the proof-of-concept WEC device system, in order to determine their energy extraction capacities and functionalities. The overall energy extracted with eight electrical generators A/C is 0.185 MWatts calculated analytically. The levelized cost of energy is a very important metric in determining whether to move forward with the project, where the cost of energy target has been as cheap as $0.07kWh; this value of LCOE could be improved with optimisations on the practical design parameters. This preliminary study investigates the factors influencing standardized and industrialized for the new WEC device system and can be used to guide the optimization of this type of device technology.

Cardiolipin, Non-Bilayer Structures and Mitochondrial Bioenergetics: Relevance to Cardiovascular Disease

The present review is an attempt to conceptualize a contemporary understanding about the roles that cardiolipin, a mitochondrial specific conical phospholipid, and non-bilayer structures, predominantly found in the inner mitochondrial membrane (IMM), play in mitochondrial bioenergetics. This review outlines the link between changes in mitochondrial cardiolipin concentration and changes in mitochondrial bioenergetics, including changes in the IMM curvature and surface area, cristae density and architecture, efficiency of electron transport chain (ETC), interaction of ETC proteins, oligomerization of respiratory complexes, and mitochondrial ATP production. A relationship between cardiolipin decline in IMM and mitochondrial dysfunction leading to various diseases, including cardiovascular diseases, is thoroughly presented. Particular attention is paid to the targeting of cardiolipin by Szeto–Schiller tetrapeptides, which leads to rejuvenation of important mitochondrial activities in dysfunctional and aging mitochondria. The role of cardiolipin in triggering non-bilayer structures and the functional roles of non-bilayer structures in energy-converting membranes are reviewed. The latest studies on non-bilayer structures induced by cobra venom peptides are examined in model and mitochondrial membranes, including studies on how non-bilayer structures modulate mitochondrial activities. A mechanism by which non-bilayer compartments are formed in the apex of cristae and by which non-bilayer compartments facilitate ATP synthase dimerization and ATP production is also presented.

Diversity analysis of thermophilic hydrogenogenic carboxydotrophs by carbon monoxide dehydrogenase amplicon sequencing using new primers

The microbial H2-producing (hydrogenogenic) carbon monoxide (CO)-oxidizing activity by the membrane-associated CO dehydrogenase (CODH)/energy-converting hydrogenase (ECH) complex is an important metabolic process in the microbial community. However, the studies on hydrogenogenic carboxydotrophs had to rely on inherently cultivation and isolation methods due to their rare abundance, which was a bottleneck in ecological study. Here, we provided gene-targeted sequencing method for the diversity estimation of thermophilic hydrogenogenic carboxydotrophs. We designed six new degenerate primer pairs which effectively amplified the coding regions of CODH genes forming gene clusters with ECH genes (CODHech genes) in Firmicutes which includes major thermophilic hydrogenogenic carboxydotrophs in terrestrial thermal habitats. Amplicon sequencing by these primers using DNAs from terrestrial hydrothermal sediments and CO-gas-incubated samples specifically detected multiple CODH genes which were identical or phylogenetically related to the CODHech genes in Firmictes. Furthermore, we found that phylogenetically distinct CODHech genes were enriched in CO-gas-incubated samples, suggesting that our primers detected uncultured hydrogenogenic carboxydotrophs as well. The new CODH-targeted primers provided us with a fine-grained (~ 97.9% in nucleotide sequence identity) diversity analysis of thermophilic hydrogenogenic carboxydotrophs by amplicon sequencing and will bolster the ecological study of these microorganisms.

Diversified Photo-Energy Conversion Based on Single-Molecule FRET to Realize Enhanced Phototheranostics

Phototheranostic, the integration of phototherapy and multimodal imaging into one nanoagent, is greatly significant for precise cancer treatment, during which how the photo-energy converting plays critical roles. Förster resonance energy...

A new ultrafast energy funneling material harvests three times more diffusive solar energy for GaInP photovoltaics

There is no theoretical limit in using molecular networks to harvest diffusive sun photons on large areas and funnel them onto much smaller areas of highly efficient but also precious energy-converting materials. The most effective concept reported so far is based on a pool of randomly oriented, light-harvesting donor molecules that funnel all excitation quanta by ultrafast energy transfer to individual light-redirecting acceptor molecules oriented parallel to the energy converters. However, the best practical light-harvesting system could only be discovered by empirical screening of molecules that either align or not within stretched polymers and the maximum absorption wavelength of the empirical system was far away from the solar maximum. No molecular property was known explaining why certain molecules would align very effectively whereas similar molecules did not. Here, we first explore what molecular properties are responsible for a molecule to be aligned. We found a parameter derived directly from the molecular structure with a high predictive power for the alignability. In addition, we found a set of ultrafast funneling molecules that harvest three times more energy in the solar’s spectrum peak for GaInP photovoltaics. A detailed study on the ultrafast dipole moment reorientation dynamics demonstrates that refocusing of the diffusive light is based on ∼15-ps initial dipole moment depolarization followed by ∼50-ps repolarization into desired directions. This provides a detailed understanding of the molecular depolarization/repolarization processes responsible for refocusing diffusively scattered photons without violating the second law of thermodynamics.

Metabolic potential for reductive acetogenesis and a novel energy-converting [NiFe] hydrogenase in Bathyarchaeia from termite guts – a genome-centric analysis

Symbiotic digestion of lignocellulose in the hindgut of higher termites is mediated by a diverse assemblage of bacteria and archaea. During a large-scale metagenomic study, we reconstructed 15 metagenome-assembled genomes (MAGs) of Bathyarchaeia that represent two distinct lineages in subgroup 6 (formerly MCG-6) unique to termite guts. One lineage (TB2; Candidatus Termitimicrobium) encodes all enzymes required for reductive acetogenesis from H2 and CO2 via an archaeal variant of the Wood–Ljungdahl pathway. This includes a novel 11-subunit hydrogenase, which possesses the genomic architecture of the respiratory Fpo-complex of other archaea but whose catalytic subunit is phylogenetically related to and shares the conserved [NiFe] cofactor-binding motif with [NiFe] hydrogenases of subgroup 4g. We propose that this novel Fpo-like hydrogenase provides the reduced ferredoxin required for CO2 reduction and is driven by the electrochemical membrane potential generated from the ATP conserved by substrate-level phosphorylation. Members of the other lineage (TB1; Candidatus Termiticorpusculum) are not capable of lithotrophic acetogenesis because they consistently lack hydrogenases and/or methylene-tetrahydromethanopterin reductase, a key enzyme of the pathway. Both lineages have the genomic capacity to reduce ferredoxin by oxidizing amino acids and might conduct methylotrophic acetogenesis using unidentified methylated compound(s). Our results indicate that Bathyarchaeia of subgroup 6 contribute to acetate formation in the guts of higher termites and substantiate the genomic evidence for reductive acetogenesis from organic substrates, including methylated compounds, in other uncultured representatives of the phylum.

RANKING OF FUEL-AIR MIXTURES IN TERMS OF THEIR PROPENSITYTO DEFLAGRATION-TO-DETONATION TRANSITION

The term "detonability" with respect to fuel-air mixtures (FAMs) implies the ability of a reactive mixture of a given composition to support the propagation of a stationary detonation wave in various thermodynamic and gasdynamic conditions. The detonability of FAMs, on the one hand, determines their explosion hazards during storage, transportation, and use in various sectors of the economy and, on the other hand, the possibility of their practical application in advanced energy-converting devices operating on detonative pressure gain combustion.

A Numerical Investigation on the Collision Behavior of Unequal-Sized Micro-Nano Droplets

Micro-nano droplet collisions are fundamental phenomena in the applications of nanocoating, nano spray, and microfluidics. Detailed investigations of the process of the droplet collisions under higher Weber are still lacking when compared with previous research studies under a low Weber number below 120. Collision dynamics of unequal-sized micro-nano droplets are simulated by a coupled level-set and volume of fluid (CLSVOF) method with adaptive mesh refinement (AMR). The effects of the size ratio (from 0.25 to 0.75) and different initial collision velocities on the head-on collision process of two unequal-sized droplets at We = 210 are studied. Complex droplets will form the filament structure and break up with satellite droplets under higher Weber. The filament structure is easier to disengage from the complex droplet as the size ratio increases. The surface energy converting from kinetic energy increases with the size ratio, which promotes a better spreading effect. When two droplets keep the constant relative velocity, the motion tendency of the droplets after the collision is mainly dominated by the large droplet. On one hand, compared with binary equal-sized droplet collisions, a hole-like structure can be observed more clearly since the initial velocity of a large droplet decreases in the deformation process of binary unequal-sized droplets. On the other hand, the rim spreads outward as the initial velocity of the larger droplet increases, which leads to its thickening.