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γ-Radiolyses of DNA in Oxygenated Aqueous Solution. Structure of an Alkali-Labile Site

Zeitschrift für Naturforschung C ◽

10.1515/znc-1977-11-1226 ◽

1977 ◽

Vol 32 (11-12) ◽

pp. 1021-1022 ◽

Cited By ~ 38

Author(s):

Miral Dizdaroglu ◽

Dietrich Schulte-Frohlinde ◽

Clemens von Sonntag

Keyword(s):

Aqueous Solution ◽

Solution Structure ◽

Oh Radicals ◽

Phosphatase Treatment ◽

Alkali Labile Site

Abstract Erythritol-1-d1 has been isolated from γ-irradiated aqueous oxygenated solution of DNA after reduction with NaBD4 , alkali and phosphatase treatment. It is concluded that this product stems from a ᴅ-erythrose 2,4-diphosphate unit in the DNA which is formed via a sequence of reactions following H-abstraction at C-2′ by OH radicals..

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