Physicochemical implications of surface alkylation of high-valent, Lindqvist-type polyoxovanadate-alkoxide clusters

Modeling physicochemical consequences of surface functionalization of metal oxide nanocrystals using polyoxovanadate clusters.

Modelling local structural and electronic consequences of proton and hydrogen-atom uptake in VO2 with polyoxovanadate clusters

We report the synthesis and characterization of a series of siloxide-functionalised polyoxovanadate-alkoxide (POV-alkoxide) clusters, [V6O6(OSiMe3)(OMe)12]n (n = 1-, 2-) that serve as molecular models for proton and hydrogen-atom uptake in...

A series of organic hybrid polyoxovanadate clusters incorporating tris(hydroxymethyl)methane derivatives

A series of new organic hybrid polyoxovanadate clusters [V4O4(µ-OH)2(acac)2(Htri)2] (1, H3tri = tris(hydroxymethyl) aminomethane, acac = acetylacetone), [V4O4(acac)2(Htri)2(L)2] {HL = methanol (2), ethanol (3a and 3b), ethylene glycol (4) and...

Oxygen-atom vacancy formation and reactivity in polyoxovanadate clusters

Overview of recent work detailing oxygen-deficient polyoxovanadate clusters as models for reducible metal oxides: toward gaining a fundamental understanding the consequences of vacancy formation on metal oxide surfaces during catalysis.

A simple one-step synthetic route to access a range of metal-doped polyoxovanadate clusters

A simple one-step synthetic route to access a range of metal-doped polyoxovanadate clusters.