PISTIL, a reactivity modulation device to probe the transfer function of the nuclear reactor CROCUS

The present article summarizes the development and testing of a reactivity modulation device developed by the French Atomic and Alternative Energies Commission (CEA). It was installed in the CROCUS reactor of the Swiss Federal Institute of Technology in Lausanne (EPFL). Experimental tests were performed in the framework of a collaboration between CEA and EPFL. The so-called PISTIL device aims at measuring the nuclear reactor transfer function in the frequency range of interest between 1 mHz and 200 Hz, in order to probe the in-core kinetic behavior of prompt and delayed neutrons. The reactivity modulation is obtained from the rotation of cadmium foils. The design of the system was driven with the objective of installing PISTIL at the center of the CROCUS reactor. Neutronic simulations with TRIPOLI-4 Monte Carlo code were performed to select the suitable design parameters and meet the safety requirements of the reactor operation. The total reactivity worth of the device, as estimated by TRIPOLI-4 Monte Carlo calculation, was approximately 0.16 $ and the maximum amplitude of the reactivity modulation was about 0.013 $. In-core reactivity calibration was then performed and were consistent as compared to TRIPOLI-4 estimations.

Direct diversification of unmasked quinazolin-4(3H)-ones through orthogonal reactivity modulation

An orthogonal reactivity modulation strategy affords diverse synthetic analogues from unmasked quinazolin-4(3H)-ones.

Molecular containers in complex chemical systems

This review discusses recent advances in the use of molecular containers in complex chemical systems, focusing on three aspects: host–guest behaviour, structural transformations and reactivity modulation.