Survival of presolar p-nuclide carriers in the nebula revealed by stepwise leaching of Allende refractory inclusions

The 87Rb-87Sr radiochronometer provides key insights into the timing of volatile element depletion in planetary bodies, yet the unknown nucleosynthetic origin of Sr anomalies in Ca-Al–rich inclusions (CAIs, the oldest dated solar system solids) challenges the reliability of resulting chronological interpretations. To identify the nature of these Sr anomalies, we performed step-leaching experiments on nine unmelted CAIs from Allende. In six CAIs, the chemically resistant residues (0.06 to 9.7% total CAI Sr) show extreme positive μ84Sr (up to +80,655) and 87Sr variations that cannot be explained by decay of 87Rb. The extreme 84Sr but more subdued 87Sr anomalies are best explained by the presence of a presolar carrier enriched in the p-nuclide 84Sr. We argue that this unidentified carrier controls the isotopic anomalies in bulk CAIs and outer solar system materials, which reinstates the chronological significance of differences in initial 87Sr/86Sr between CAIs and volatile-depleted inner solar system materials.

The partitioning of the inner and outer solar system by a structured protoplanetary disk

<p>Mass-independent isotopic anomalies in planets and meteorites define two cosmochemically distinct regions: the carbonaceous and non-carbonaceous meteorites, implying that the non-carbonaceous (terrestrial) and carbonaceous (jovian) reservoirs were kept separate during and after planet formation. The iron meteorites show a similar dichotomy.</p><p>The formation of Jupiter is widely invoked to explain this compositional dichotomy by acting as an effective barrier between the two reservoirs. Jupiter’s solid kernel possibly grew to ~20 Mearth in ~1 Myr from the accretion of sub meter-sized objects (termed “pebbles”), followed by slower accretion via planetesimals. Subsequent gas envelope contraction is thought to have led to Jupiter’s formation as a gas giant.</p><p>We show using dynamical simulations that the growth of Jupiter from pebble accretion is not fast enough to be responsible for the inferred separation of the terrestrial and jovian reservoirs. We propose instead that the dichotomy was caused by a pressure maximum in the disk near Jupiter’s location, which created a ringed structure such as those detected by the Atacama Large Millimeter/submillimeter Array(ALMA). One or multiple such long-lived pressure maxima almost completely prevented pebbles from the jovian region reaching the terrestrial zone, maintaining a compositional partition between the two regions. We thus suggest that our young solar system’s protoplanetary disk developed at least one and likely multiple rings, which potentially triggered the formation of the giant planets [1].</p><p><br>[1] Brasser, R. and Mojzsis, S.J. (2020) Nature Astronomy doi: 10.1038/s41550-019-0978-6</p>

Localized and delocalized bound states of the main isotopologue 48O3 and of 18O-enriched 50O3 isotopomers of the ozone molecule near the dissociation threshold

Knowledge of highly excited rovibrational states of ozone isotopologues is of key importance for modelling the dynamics of exchange reactions, for understanding longstanding problems related to isotopic anomalies of the ozone formation, and for analyses of extra-sensitive laser spectral experiments currently in progress.

Fingerprints of the protosolar cloud collapse in the Solar System: Refractory inclusions distribution and isotopic anomalies in meteorites

Increasing evidences suggest that the building blocks of Ca-Al-rich inclusions (CAIs) could have formed with the Sun, during the collapse of the parent cloud. However, determination of the relative age of CAIs relies on the homogeneous distribution of their short-lived radionuclide 26Al that is used as a chronometer. Some CAIs show evidence of 26Al/27 Al variation that is independent of decay.We investigate the dynamical and chemical evolution of refractories from the collapsing cloud to their transport in the protoplanetary disk focusing to the predicted isotopic anomalies resulting from 26Al heterogeneities.The interplay between the thermal properties of the dust, the isotopic zoning in the cloud and disk dynamics produce aggregates that resemble chondrites. An abrupt raise of 26Al close the center of the cloud followed by a plateau throughout the cloud best matches the observations. As a consequence, the 26Al -chronometer retains validity from the formation of canonical CAIs onward.

Atmospheric sulfur isotopic anomalies recorded at Mt. Everest across the Anthropocene

Increased anthropogenic-induced aerosol concentrations over the Himalayas and Tibetan Plateau have affected regional climate, accelerated snow/glacier melting, and influenced water supply and quality in Asia. Although sulfate is a predominant chemical component in aerosols and the hydrosphere, the contributions from different sources remain contentious. Here, we report multiple sulfur isotope composition of sedimentary sulfates from a remote freshwater alpine lake near Mount Everest to reconstruct a two-century record of the atmospheric sulfur cycle. The sulfur isotopic anomaly is utilized as a probe for sulfur source apportionment and chemical transformation history. The nineteenth-century record displays a distinct sulfur isotopic signature compared with the twentieth-century record when sulfate concentrations increased. Along with other elemental measurements, the isotopic proxy suggests that the increased trend of sulfate is mainly attributed to enhancements of dust-associated sulfate aerosols and climate-induced weathering/erosion, which overprinted sulfur isotopic anomalies originating from other sources (e.g., sulfates produced in the stratosphere by photolytic oxidation processes and/or emitted from combustion) as observed in most modern tropospheric aerosols. The changes in sulfur cycling reported in this study have implications for better quantification of radiative forcing and snow/glacier melting at this climatically sensitive region and potentially other temperate glacial hydrological systems. Additionally, the unique Δ33S–δ34S pattern in the nineteenth century, a period with extensive global biomass burning, is similar to the Paleoarchean (3.6–3.2 Ga) barite record, potentially providing a deeper insight into sulfur photochemical/thermal reactions and possible volcanic influences on the Earth’s earliest sulfur cycle.