Thermal And Kinetic Study of Electrochemical Deposition of Lead On FTO Substrate

We report the electrochemical deposition of lead (Pb) onto fluorine-doped tin oxide (FTO) electrodes in a sodium nitrate bath (0.4M NaNO3) at constant potential conditions. The kinetics electrodeposition processes have been in situ monitored for advanced nucleation stages by chronoamperometry for various temperature at fixed concentration of Pb2+, that is 0.1M. The microstructure and morphological characteristics of the deposit layers were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-Ray EDX techniques. The results show that the current density as well as the deposits density strongly depend on the temperature. The correlation between the experimental results and the theoretical process of the lead deposits was discussed and verified.

Electrodeposition of Zinc Oxide NanoSheets on Exfoliated Tips of Carbon Nanotube Films

Fast growth of ZnO nanosheets on exfoliated tips of multiwalled carbon nanotube films were investigated by electrodeposition from zinc nitrate bath. Variation of electrodeposition time showed the presence of ZnO at only 25s. At 100s, the ZnO crystal size is dominated by the dimension of carbon nanotube patterns formed after wet. Longer depositions (240-480s) produced dense films but with smaller nanosheets.

Monitoring of Tempering Behavior in Fe-C-Mn Alloys by Precise Measurement of Electrical Resistivity

Mechanical properties in metallic materials are generally determined by microstructure, which is controlled by thermo-mechanical treatment in addition to its composition. Tempering is the conventional process of heat-treated steel. Therefore, understanding microstructural change during the process is especially important. As is well known, electrical resistivity measurement gives useful information regarding microstructures and lattice defects. In this technique, average information can be obtained from larger volume of specimens than TEM specimens as 108 times. So the purpose of this study was to monitor electrical resistivity changes related to microstructural changes during tempering in Fe-0.19 C-1.5 Mn, Fe-0.35 C-1.5 Mn alloys. Bar shaped specimens were cut from the sheets of steels. The specimens were heat-treated in austenite region and then quenched with ice-water. Then tempering was cumulatively carried out by direct dipping in a nitrate bath held at 423-673 K. Electrical resistivities at 77 K (in liquid nitrogen) and 300 K were measured in each state by a direct current (DC) four-point method. The resistivities abruptly decreased and then gradually decreased by the tempering. First drop and following decreasing of resistivities are corresponding to vanishing vacancies in martensite and precipitation of carbide, respectively. The organized resistivites by Hollomon-Jaffe parameter showed infections during the carbide precipitation. The points must be related to transition of precipitation mode.