imidazole ligands
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2021 ◽  
Vol 214 ◽  
pp. 111303
Author(s):  
Gideon K. Yawson ◽  
Samantha E. Huffman ◽  
Samuel S. Fisher ◽  
Paige J. Bothwell ◽  
David C. Platt ◽  
...  

2020 ◽  
Author(s):  
Lachlan Sharp-Bucknall ◽  
Lachlan Barwise ◽  
Jason Bennetts ◽  
Mohammad Albayer ◽  
Jason Dutton

The reactivity of difluoro Au(III) cations supported by pyridine or imidazole ligands is reported. The Au(III)-F bond is found to be susceptible to metathesis by TMS reagents and reagents bearing acidic protons such as H-CC-Ph and HOAc. In the latter case the reactions are slower than analogous reactions reported by other groups where strong -trans donors are present opposite the Au-F bond. This, coupled with the inability to effect metathesis on only one Au-F bond in our system indicates the -trans effect is a key consideration in Au-F chemistry


2020 ◽  
Author(s):  
Lachlan Sharp-Bucknall ◽  
Lachlan Barwise ◽  
Jason Bennetts ◽  
Mohammad Albayer ◽  
Jason Dutton

The reactivity of difluoro Au(III) cations supported by pyridine or imidazole ligands is reported. The Au(III)-F bond is found to be susceptible to metathesis by TMS reagents and reagents bearing acidic protons such as H-CC-Ph and HOAc. In the latter case the reactions are slower than analogous reactions reported by other groups where strong -trans donors are present opposite the Au-F bond. This, coupled with the inability to effect metathesis on only one Au-F bond in our system indicates the -trans effect is a key consideration in Au-F chemistry


2020 ◽  
Vol 499 ◽  
pp. 119184 ◽  
Author(s):  
Fang-Hua Zhao ◽  
Long-Wei Huang ◽  
Yuan-Chun He ◽  
Xiao-Qing Yan ◽  
Zhong-Lin Li ◽  
...  

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