copper dimers
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scholarly journals Phosphonate Metal-Organic Frameworks: A Novel Family of Semiconductors

2020 ◽  
Author(s):  
Konrad Siemensmeyer ◽  
Craig A. Peeples ◽  
Patrik Tholen ◽  
Bünyemin Çoşut ◽  
Gabriel Hanna ◽  
...  
Keyword(s):  
Solid State ◽  
Dft Calculations ◽  
Band Gap ◽  
Narrow Band ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
One Dimensional ◽  
Metal Organic ◽  
Copper Dimers ◽  
Electrodes For Supercapacitors

<p>Herein is reported the first semiconducting and magnetic phosphonate metal-organic framework (MOF), TUB75, which contains a one-dimensional inorganic building unit composed of a zig-zag chain of corner-sharing copper dimers. The solid-state UV-Vis spectrum of TUB75 reveals the existence of a narrow band gap of 1.4 eV, which agrees well with the 1.77 eV one obtained from DFT calculations. Magnetization measurements show that TUB75 is composed of antiferromagnetically coupled copper dimer chains. Due to their rich structural chemistry and exceptionally high thermal/chemical stabilities, phosphonate MOFs like TUB75 may open new vistas in engineerable electrodes for supercapacitors. </p>

scholarly journals Phosphonate Metal-Organic Frameworks: A Novel Family of Semiconductors

2020 ◽  
Author(s):  
Konrad Siemensmeyer ◽  
Craig A. Peeples ◽  
Patrik Tholen ◽  
Bünyemin Çoşut ◽  
Gabriel Hanna ◽  
...  
Keyword(s):  
Solid State ◽  
Dft Calculations ◽  
Band Gap ◽  
Narrow Band ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
One Dimensional ◽  
Metal Organic ◽  
Copper Dimers ◽  
Electrodes For Supercapacitors

<p>Herein is reported the first semiconducting and magnetic phosphonate metal-organic framework (MOF), TUB75, which contains a one-dimensional inorganic building unit composed of a zig-zag chain of corner-sharing copper dimers. The solid-state UV-Vis spectrum of TUB75 reveals the existence of a narrow band gap of 1.4 eV, which agrees well with the 1.77 eV one obtained from DFT calculations. Magnetization measurements show that TUB75 is composed of antiferromagnetically coupled copper dimer chains. Due to their rich structural chemistry and exceptionally high thermal/chemical stabilities, phosphonate MOFs like TUB75 may open new vistas in engineerable electrodes for supercapacitors. </p>

Continuous Partial Oxidation of Methane to Methanol Catalyzed by Diffusion-Paired Copper Dimers in Copper-Exchanged Zeolites

2019 ◽  
Vol 141 (29) ◽  
pp. 11641-11650 ◽  
Author(s):  
Kimberly T. Dinh ◽  
Mark M. Sullivan ◽  
Karthik Narsimhan ◽  
Pedro Serna ◽  
Randall J. Meyer ◽  
...  
Keyword(s):  
Partial Oxidation ◽  
Partial Oxidation Of Methane ◽  
Oxidation Of Methane ◽  
Copper Dimers

Evidence for Copper Dimers in Low-Loaded CuOx/SiO2Catalysts for Cyclohexane Oxidative Dehydrogenation

ACS Catalysis ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 9775-9789 ◽  
Author(s):  
Scott L. Nauert ◽  
Andrew S. Rosen ◽  
Hacksung Kim ◽  
Randall Q. Snurr ◽  
Peter C. Stair ◽  
...  
Keyword(s):  
Oxidative Dehydrogenation ◽  
Copper Dimers

Long-Distance Magnetic Interaction of Exchange-Coupled Copper Dimers with Nitronyl Nitroxide andtert-Butyl Nitroxide Radicals

2009 ◽  
Vol 48 (15) ◽  
pp. 7244-7250 ◽  
Author(s):  
Martin Jung ◽  
Ajay Sharma ◽  
Dariush Hinderberger ◽  
Sebastian Braun ◽  
Ulrich Schatzschneider ◽  
...  
Keyword(s):  
Magnetic Interaction ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals ◽  
Long Distance ◽  
Copper Dimers

Flame-Synthesized Ceria-Supported Copper Dimers for Preferential Oxidation of CO

2009 ◽  
Vol 19 (3) ◽  
pp. 369-377 ◽  
Author(s):  
Richard Kydd ◽  
Wey Yang Teoh ◽  
Kenneth Wong ◽  
Yong Wang ◽  
Jason Scott ◽  
...  
Keyword(s):  
Preferential Oxidation ◽  
Oxidation Of Co ◽  
Preferential Oxidation Of Co ◽  
Copper Dimers

Flame-Synthesized Copper Dimers: Flame-Synthesized Ceria-Supported Copper Dimers for Preferential Oxidation of CO (Adv. Funct. Mater. 3/2009)

2009 ◽  
Vol 19 (3) ◽  
pp. NA-NA
Author(s):  
Richard Kydd ◽  
Wey Yang Teoh ◽  
Kenneth Wong ◽  
Yong Wang ◽  
Jason Scott ◽  
...  
Keyword(s):  
Preferential Oxidation ◽  
Oxidation Of Co ◽  
Preferential Oxidation Of Co ◽  
Copper Dimers

Metal−Organic Frameworks from Copper Dimers withcis- andtrans-1,4-Cyclohexanedicarboxylate andcis,cis-1,3,5-Cyclohexanetricarboxylate

2007 ◽  
Vol 46 (15) ◽  
pp. 5949-5956 ◽  
Author(s):  
Hitoshi Kumagai ◽  
Motoko Akita-Tanaka ◽  
Katsuya Inoue ◽  
Kazuyuki Takahashi ◽  
Hayao Kobayashi ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Copper Dimers
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