Mesoporous SnO2–SiO2 and Sn–silica–carbon nanocomposites by novel non-hydrolytic templated sol–gel synthesis

A novel non-hydrolytic sol–gel (NHSG) synthesis of mesoporous tin silicate xerogels is presented.

Development of Borosilicate Glass Compositions for the Immobilisation of the UK's Separated Plutonium Stocks

The UK inventory of separated civil plutonium is expected to exceed 100 tonnes by 2010. Whilst the majority of this could be used in the manufacture of MOx (Mixed Oxide) fuel in future power generation scenarios, options for the disposal of surplus plutonium are currently being investigated by Nexia Solutions Ltd on behalf of the UK's Nuclear Decommissioning Authority (NDA). One of the options being considered is immobilisation in a durable glass matrix followed by long term storage and subsequent final repository disposal.A preliminary experimental survey assessed a selection of potential glass systems on the basis of Pu-surrogate (cerium) loading, durability, and ease of processing. Following this, a number of borosilicate compositions have been taken forward into a more detailed investigation in order to fully qualify their potential for Pu-immobilisation. The selected compositions are lanthanide borosilicate (LaBS), alkali tin silicate (ATS) and high-lanthanide alkali borosilicate (modified-MW). For this second series of experiments, hafnium was selected as the Pu surrogate, and a study of the potential waste loading as a function of temperature for the three selected compositions is described in this paper. Furthermore, several variations of the LaBS composition were fabricated in order to investigate the effect of total lanthanide content on melting temperature. The benchmark of 10 wt% HfO2 incorporation is achievable for all three glasses with temperatures of 1200, 1300 and 1400 °C required for ATS, modified-MW and LaBS respectively.