Mechanisms of passivation and chloride-induced corrosion of mild steel in sulfide-containing alkaline solutions

The pore fluid within many concretes is highly alkaline and rich in reduced sulfur species, but the influence of such alkaline-sulfide solutions on the surface film formed on steel reinforcement is poorly understood. This study investigates the critical role of HS− in defining mild steel passivation chemistry. The surface film formed on the steel in alkaline-sulfide solutions contains Fe(OH)2 and Fe–S complexes, and the critical chloride concentration to induce corrosion increases at high sulfide concentration. However, this behavior is dependent on the duration of exposure of the steel to the electrolyte, and the nature of the sulfidic surface layer.

Studying the impact of alkaline sulfide leaching parameters upon the efficiency of arsenic recovery from copper skimmings of lead production

The article is concerned with the problem of arsenic circulation as copper skimmings of lead production — the product of the lead bullion decopperization process at a metallurgical complex, uniting copper and lead plants. A brief overview of the methods of processing arsenic-containing middling products for the purpose of arsenic removal is given; the main advantages and disadvantages are indicated. The possibility of processing copper skimmings by the method of alkaline sulfide leaching with separation into arseniccontaining solution and lead-copper precipitate is studied. The results of the researches into the influence of temperature, process duration, solids content in the pulp, particle size, and the ratio of sodium hydroxide to elemental sulfur in the alkaline sulfide reagent on the process of alkaline sulfide leaching of copper skimmings af lead production are provided. Within the studied range of varied factors, the highest indexes of arsenic extraction into solution (85.04%) were achieved under the following conditions: temperature — 85 °C, duration — 4 hours, solids content in the pulp — 350 g/dm3, fraction (–0.08 mm), NaOH/S ratio = 100 g/100 g in 1 dm3 of the solution. The proposed method for processing copper skimmings will allow one to selectively isolate arsenic into the dump waste product during subsequent precipitation and separate contaminant from lead-copper cake, into which precious metals also pass. Such an approach provides the reduction of arsenic circulation between the lead and copper manufacturing facilities.

Optimization of Alkaline Sulfide Leaching of Gold-Antimony Concentrates

This article covers a hydrometallurgical method for processing of a gold-antimony flotation concentrate in alkaline sulfide solutions. Thermodynamic analysis of the reaction stibnite with sulfide sodium and sodium hydroxide was performed. The chemical and phase compositions of the investigated material, mainly represented by compounds of antimony, silicon, calcium, sulfur and iron are studied. Phase composition: quartz, stibnite, quicklime, pyrite, dolomite and arsenopyrite. The dependences of the influence of sulfide sodium and sodium hydroxide concentration, and the liquid to solid ratio on antimony extraction into solution were determined by methods of mathematical experiment planning. The calculated values ​​of the determination coefficients testify to the adequacy of the chosen two-level model. The optimum parameters of the process were obtained: L/S ratio = 4,5; the nitric acid sulfide sodium concentration was 61.09 g/L; sodium hydroxide concentration was 16.47 g/

Studying Kinetics of Arsenic Recovery from Copper Dross by Alkaline Sulfide Leaching

Copper dross are produced by rough decopperizing of blast furnace lead bullion. During liquation separation of copper dross from lead bullion most of arsenic and copper are concentrated in copper dross, arsenic content is approximately 4% As. Currently the processes for arsenic recovery from copper dross are understudied. In this work the focus is given to studying kinetics of the process for recovering arsenic from copper dross by alkaline-sulfide leaching. Alkaline sulfide leaching allows carrying out selective removal of arsenic into solution, keeping at this non-ferrous and precious metals in leaching residue. The studied method of alkaline sulfide leaching of copper dross provides backgrounds for developing technology that would allow processing of copper dross with selective arsenic removal from lead production cycle. By minimizing circulation of this harmful impurity in lead production it is possible to lessen destructive effect of its aggressive compounds on smelting-units refractory. Kinetics of alkaline sulfide leaching of copper dross was understudied up to date. This work is an attempt to fill the gap.