Relating Diffusion Couple Experiment Results to Observed As-Fabricated Microstructures in Low-Enriched U-10wt.% Mo Monolithic Fuel Plates

Monolithic fuel system with U – 10 wt.% Mo (U10Mo) fuel alloy has been developed for the Materials Management and Minimization reactor conversion program to replace highly-enriched fuels in research and test reactors with low-enriched fuels. Interdiffusion and phase transformations in the system constituents, i.e., U10Mo fuel, AA6061 cladding, and Zr diffusion barrier, have been investigated using fuel plates fabricated via rolling and hot-isostatic pressing. Diffusion couples, utilizing the constituents of the fuel system were also carried out to help understand the findings from fuel plates based on phase equilibria and diffusion kinetics. Findings from both fuel plates and diffusion couples can provide a comprehensive knowledge to assess, model, and predict the performance of monolithic low-enriched fuel system from fabrication to irradiation. This paper summarizes the experimental results reported from characterization of the fuel plates and diffusion couples with emphasis on interactions at the fuel-cladding, fuel-diffusion barrier, cladding-diffusion barrier, and cladding-cladding interfaces. Constituent phases and relevant diffusion kinetics are compared and contrasted, taking into account differences in thermodynamics and kinetics variables such as pressure, temperature, and cooling rate.

Anisotropic Diffusion Behaviour of Al and Zn in HCP Mg: Diffusion Couple Experiment Using Mg Single Crystal

Diffusion couple experiments for Mg-Al and Mg-Zn were carried out with Mg single crystal to determine the anisotropic diffusion coefficients of Al and Zn in hcp Mg at the temperature range between 553 and 693 K. Based on the experimental results, anisotropic diffusion coefficients of Al and Zn were calculated using multiphase diffusion simulations. Al diffusion in hcp Mg is slightly faster than Mg self-diffusion itself, but the diffusion of Zn is slightly slower than Mg self-diffusion. The diffusion coefficients of Al and Zn along the a-axis (basal plane) of hcp Mg is slightly higher (1.1-1.4 times) than those along the c-axis (normal to the basal plane), which is also similar to Mg self-diffusion behaviour.