Design and analysis of 3D-printed hybrid couplers for D-band applications

This work focuses on the impact of the build orientation on additively manufactured waveguide-based hybrid couplers for D-band frequency range and relates it to other sources of uncertainty within the overall manufacturing process and measurement instrumentation for the D-band frequency range. The designed specimens are first printed from UV curable photopolymer resin and subsequently metal coated by an electroless silver plating process, which in turn is improved by making use of the slotted waveguide approach. Although the requirements toward geometrical precision to achieve phase errors below 10° are in an order of 0.1 mm, a desktop grade DLP printer is utilized in this work in order to point out the prospects and limitations of additive manufacturing. Furthermore, waveguide paths with bends are part of the model and their impact on the measured attenuation is estimated explicitly. Despite this narrow field of tolerances, one specimen could have been realized, which achieves a measured output magnitude imbalance of 0.7 dB over the frequency range from 120 to 155 GHz while at the same time exhibiting a phase deviation of only <10° from the desired 90°. With these demonstrated results, the proposed approach provides suitability for future applications in the D-band frequency range.

Enhancing Effect of Chloride Ions on the Autocatalytic Process of Ag(I) Reduction by Co(II) Complexes

In this work, the possibilities of increasing the rate of electroless silver plating without a rise in the concentration of reactants or elevation of temperature were studied. The effect of halide additive, namely chloride ions, on the rate of electroless silver deposition was investigated, using conventional chemical kinetics and electrochemical techniques. It was found that the deposition rate of electroless silver increased 2–3 times in the presence of 10–20 mM of chlorides, preserving sufficient stability of the solution.

Preparation of Silver-Plated Para-Aramid Fiber by Employing Low-Temperature Oxygen Plasma Treatment and Dopamine Functionalization

Direct electroless silver plating of para-aramid (PPTA) is difficult due to its extremely low surface chemical energy. In order to facilitate the deposition of silver nanoparticles and to enhance the washing fastness, oxygen plasma treatment and dopamine modification were conducted before silver plating of PPTA fibers. Various techniques including scanning electron microscopy (SEM), attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), X-ray diffractometer (XRD) and thermogravimetric analyzer (TGA) were used to characterize the surface morphology, chemical composition and thermal stability of the silver-plated PPTA fibers. Electrical resistance and silver content of the silver-coated PPTA fibers before and after standard washing were also studied. The results showed that silver nanoparticles were successfully coated onto the surface of PPTA fibers with and without plasma treatment, but the coating continuity and the electrical conductivity of the silver-coated PPTA fibers were greatly enhanced with the assistance of plasma treatment. It was also demonstrated that the washing fastness of silver-coated PPTA fibers was improved after plasma treatment as indicated by electrical resistance and continuity of the silver nanoparticles after various washing cycles. It was found that the electrical resistance of plasma-treated PPTA-PDA/Ag fibers prepared at an AgNO3 concentration of 20 g/L reached 0.89 Ω/cm and increased slightly to 0.94 Ω/cm after 10 standard washing cycles. The silver-coated PPTA fibers also showed stable electrical conductivity under 250 repeated stretching-releasing cycles at a strain of 3%.