sodium cationization
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scholarly journals Sodium cationization can disrupt the intramolecular hydrogen bond that mediates the sunscreen activity of oxybenzone

2020 ◽  
Vol 22 (35) ◽  
pp. 19522-19531
Author(s):  
Jacob A. Berenbeim ◽  
Natalie G. K. Wong ◽  
Martin C. R. Cockett ◽  
Giel Berden ◽  
Jos Oomens ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Intramolecular Hydrogen Bond ◽  
Sodium Cation ◽  
Uv Filter ◽  
Ability To Act ◽  
Sodium Cationization ◽  
Intramolecular Hydrogen

Complexation with a sodium cation breaks the intramolecular hydrogen bond of oxybenzone, compromising its ability to act as an effective UV filter.

Impact of Sodium Cationization on Gas-Phase Conformations of DNA and RNA Cytidine Mononucleotides

2019 ◽  
Vol 30 (9) ◽  
pp. 1758-1767 ◽  
Author(s):  
L. A. Hamlow ◽  
Y.-w. Nei ◽  
R. R. Wu ◽  
J. Gao ◽  
J. D. Steill ◽  
...  
Keyword(s):  
Gas Phase ◽  
Dna And Rna ◽  
Sodium Cationization

Effects of sodium cationization versus protonation on the conformations and N-glycosidic bond stabilities of sodium cationized Urd and dUrd: solution conformation of [Urd+Na]+ is preserved upon ESI

2017 ◽  
Vol 19 (27) ◽  
pp. 17637-17652 ◽  
Author(s):  
Y. Zhu ◽  
H. A. Roy ◽  
N. A. Cunningham ◽  
S. F. Strobehn ◽  
J. Gao ◽  
...  
Keyword(s):  
Glycosidic Bond ◽  
Solution Conformation ◽  
Action Spectroscopy ◽  
Sodium Cationization ◽  
Spectroscopy Studies

The conformations of sodium cationized uridine and 2′-deoxyuridine are sensitive to the presence (or absence) of the 2′-hydroxyl substituent. IRMPD action spectroscopy studies suggest that the solution conformation of [Urd+Na]+ is preserved upon ESI.

Influence of Sodium Cationization versus Protonation on the Gas-Phase Conformations and Glycosidic Bond Stabilities of 2′-Deoxyadenosine and Adenosine

2016 ◽  
Vol 120 (34) ◽  
pp. 8892-8904 ◽  
Author(s):  
Y. Zhu ◽  
L. A. Hamlow ◽  
C. C. He ◽  
S. F. Strobehn ◽  
J. K. Lee ◽  
...  
Keyword(s):  
Gas Phase ◽  
Glycosidic Bond ◽  
Sodium Cationization
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