Methodology for the Selection of Technological Modes for the Synthesis of Transparent Conducting Oxides with Desired Properties

Transparent conducting oxides (TCOs) are widely used as a transparent electrode in various fields of opto-and semiconductor electronics. The main materials used today are indium-tin oxide, tin-antimony oxide and zinc-aluminum oxide. The authors have developed and improved the spray-pyrolysis method, which is one of the most promising methods of implementation in production. In this work, the study of tin dioxide doped with antimony coatings and the development of a methodology for the controlled synthesis of TCO, taking into account the effect of technological modes of deposition on the TCO parameters. The results of the performed studies contribute to the development of an automated technology for the synthesis of transparent conducting oxides with desired properties.

Stability analysis on the kerosene nanofluid flow with hybrid zinc/aluminum-oxide (ZnO-Al2O3) nanoparticles under Lorentz force

Purpose The flow and heat transfer of a hybrid nanofluid composed of kerosene and ZnO-Al2O3 nanoparticles (NPs) is investigated. The flow occurs over complex surfaces with stretching and shrinking features. The base fluid is electrically conducting, and an external magnetic field is added so that the nanofluid and the electric field are in equilibrium. Irrotational flow with viscous dissipation effects is considered. Design/methodology/approach The governing equations of the system are formulated, and a similarity transformation is used to convert the system of equations into ordinary differential equations, which are solved numerically. The friction coefficient of the flow and the Nusselt number are calculated for a wide range of parameters, and the results are presented in graphical form. In addition, dual solutions of the problem were noticed to occur for a certain range of the unsteadiness parameter. A stability analysis has been performed and presented to elucidate the behavior of these dual solutions. Findings For the solution of the upper branch, the velocity and temperature profiles of the nanofluid are enhanced by increasing the magnetic field parameter M, but the same variables decrease in the solution of the lower branch. The same trend is detected for the velocity of the fluid with the suction parameter. The temperature of the nanofluid decreases in both branches of the solution by increasing the Prandtl number. Similarly, they decrease with the suction parameter. The temperature of the nanofluid slightly increases in both branches of the solution by increasing the Eckert number. With the stability analysis the authors performed, it was determined that the solution is stable in the upper branch, but unstable in the lower branch. Originality/value The kerosene nanofluid with hybrid Zinc/Aluminum-oxide is presented for the first time in the literature.

Effective optical nanoparticles and nanocomposites based on a carbon nanotubes-organic—inorganic nanohybrid for industrial pollutant removal

Improving the optical properties of zinc oxide to meet the practical requirements of photocatalytic reactions and solar cells is an ongoing challenge. To address this challenge, different nanostructures of ZnO were prepared from an organic—inorganic-CNTs nanohybrid. The nanohybrid was formed through intercalation of the long chain fatty acid C17H35COOH and carbon nanotubes into Zn–Al nanolayered structures. X-ray diffraction revealed an increase in the interlayer spacing of the Zn–Al layered double hydroxides from 0.75 nm to 2.1 nm after admixing with the CNTs and organic fatty acid. Thermal analyses and FTIR confirmed the formation of the CNTs–C18–Zn–Al nanohybrid. Three different thermal treatments were used to transform the nanohybrid into nanostructures of doped zinc oxide nanoparticles and zinc aluminum oxide nanocomposites. As a result of changes in the nano size and structure, the band gap energy of the products decreased from 3.3 eV to 1.8 eV, to give efficient photocatalysts. The nanomaterials were used to purify water through the photocatalytic degradation of colored pollutants under UV light. A kinetic study showed that water purification was achieved within a short time, demonstrating the effectiveness of the nanomaterials. The nanohybrid and its derivatives are attractive materials for designing-efficient photocatalysts for pollutant degradation.