Stabilisation Treatments for Paper with Green Copper Pigment Verdigris

The focus of this research is the stabilisation of paper with Verdigris, a green copper pigment. Due to its corrosive effects on paper, many important documents, paintings and maps are in danger. The efficiency of several commercially available deacidification agents on paper samples with Verdigris was tested, including magnesium-based Bookkeeper® dispersion, nano calcium hydroxide containing Nanorestore® and CaLoSiL® dispersions as well as a recently developed dispersion of nano calcium carbonate. The antioxidant tetrabutylammonium bromide was tested either alone or in combination with nano calcium based deacidification agents. The effect of the treatments was evaluated using colour, tensile strength, degree of polymerization and pH measurements. The results indicate that acidic degradation does not play a major role during accelerated degradation of paper containing Verdigris with moderately acidic pH value and that oxidative decay could be the main culprit of the decay. The method described, which involves the use of antioxidant tetrabutylammonium bromide in combination with calcium carbonate based deacidification dispersion, was proved to have a superior effect against degradation of paper with Verdigris in comparison to the treatments which involve deacidification agents only. Nano calcium hydroxide based deacidification agents result in high pH values of the paper samples and therefore cannot be advised for use on paper documents.

PLGA/chitosan–heparin composite microparticles prepared with microfluidics for the construction of hMSC aggregates

P/C–h composite microparticles fabricated by microfluidics enhanced the biological functions of hMSC aggregates through neutralizing PLGA′ acidic degradation products.

Durability of Portland Concrete Containing Polymeric Fillers and Fly Ash

Portland concrete suffers in service brittle failure, extensive crack propagation, and wear rates increasing with time. In spite of all the effort expended, these problems persisted when we had started our project. We used several polymeric fillers and fly ash. Higher compressive moduli than the starting concrete are seen for some compositions, the highest for 5 % of one of the polymers + 5 % fly ash. The same composition has the lowest Taber abrasive wear loss. All composites show lower wear loss values than Portland concrete. After 25 days of acidic degradation in 4.0 molar aq. HCl, the starting Portland concrete suffers stronger degradation that our composites. Polymer swelling mitigates acidic degradation. Repetitive freeze-thaw cycles between 15oF and 85oF show disappearance of the deep voids present before the first cycle in our composites—but not in the Portland cement. While the use of fly ash mitigates contamination of the environment, it is the combination of fly ash with polymers which provides significantly improved properties - tribological, chemical and mechanical ones – of the Portland concrete.

Characterization and Optimization of PLA Stereocomplexed Hydrogels for Local Gene Delivery Systems

Localized gene delivery still remains as a challenging therapeutic method due to the multiple hurdles to overcome. One of the significant factors is a development of a matrix to carry and safely deliver genes at the local site in a controlled manner and then exit and disintegrate harmlessly. This report describes the structural and mechanistic studies on the in-situ forming hydrogels composed of the PEI/DNA multi-layered micelles to apply for gene therapy. The stereocomplexation-driven hydrogel systems from the DNA-loaded and DNA-free PLA-PEG-PLA triblock copolymer micelles that include enantiomeric polylactide blocks exhibited a sol-to-gel transitions between room and body temperatures. These hydrogels have well-described structure and compositions, and improved mechanical properties. Furthermore, the investigation of their degradation profiles and chemical analysis indicated the faster acidic degradation and stepwise degradation process of these micelle–hydrogel systems.

Accelerating the acidic degradation of a novel thermoresponsive polymer by host–guest interaction

Carboxylate modified pillar arenes can not only shift the LCST of acetalized polymers but can also accelerate their hydrolysis under acidic conditions.

Stewing in Its Own Juices? The Permeability of PET by Water and Acetic Acid

Historic documents are frequently protected by placing them in a sealed polyethylene-terephthalate (PET) envelope. Although the paper is mechanically stabilized, the PET film may limit transmission of moisture or acidic degradation by-products of the paper. This creates a microenvironment for the encapsulated document. The permeation of water and acetic acid vapor through the PET film was measured to understand the microenvironment within an encapsulated enclosure. For encapsulation with a 102 μm (4 mil) PET film, the water vapor mass flux through the encapsulated film was measured. The water vapor was found to flow into or out of the PET film depending on the sample and environmental conditions. Because the encapsulated paper needed a longer time to dry than paper in open air, PET encapsulation provides a microenvironment that will buffer the encapsulated object from large swings in humidity. Acetic acid either did not diffuse through the PET, or it diffused at such a slow rate as to not be measured, due to the larger size of the acetic acid molecule than the water molecule. Keeping one edge of an encapsulation open allowed a drying rate that was four times faster than when all four sides were sealed. Because acetic acid vapor does not readily diffuse through the PET, these results reinforce the recommendations for deacidification and/or addition of buffering agents to the paper or enclosure. The results of this study point to a critical need for the investigation of new materials in conjunction with further evaluation of currently used materials.