Supramolecular networks and Hirshfeld surfaces of oxydiacetic acid and iminodiacetic acid salts

Oxydiacetic acid (Oda) and iminodiacetic acid (Ida) have been combined with two diamines, namely ethylenediamine (en) and o-phenylenediamine (o-phen), to give three molecular crystals of compositions [(Oda2−)(en2+)]·H2O (Odaen), [(Ida−)(0.5en+)] (Idaen) and [(Oda−)(o-phen+)] (Odaophen). Single crystal X-ray structure determination of the three molecular salts revealed that the hydrogen bonding interactions form distinct supramolecular chains. In Odaen, water molecules and Oda2− anions generate one-dimensional supramolecular chains where two chains overlap each other in zigzag form. In Odaophen, Oda− anions generate a one-dimensional linear supramolecular chain. In Idaen, both intermolecular and intramolecular proton transfer occurs. Ida− anions generate a one-dimensional zigzag chain. These one-dimensional supramolecular chains extend to form different two-dimensional supramolecular chains by the interaction of diaminium and monoaminium cations. Intermolecular close contacts are also examined using Hirshfeld analysis to reveal similarities and differences in the crystal structures.

Influence of the lanthanide(iii) ion in {[Cu3Ln2(oda)6(H2O)6]·nH2O}n (LnIII: La, Gd, Yb) catalysts on the heterogeneous oxidation of olefins

{[Cu3Ln2(oda)6(H2O)6]·nH2O}n (LnIII: La, Gd, Yb; odaH2: oxydiacetic acid) are reported as reusable heterogeneous catalysts in the oxidation of olefins.

Novel three-dimensional coordination polymers of lanthanides with sulfate and oxydiacetic acid

Three three-dimensional coordination polymers,viz.poly[[diaqua-μ4-oxydiacetato-di-μ4-sulfato-dipraseodymium(III)] hemihydrate], [Pr2(C4H4O5)(SO4)2(H2O)2]·0.5H2O, (I), poly[[diaquadi-μ3-oxydiacetato-μ3-sulfato-dineodymium(III)] 1.32-hydrate], [Nd2(C4H4O5)2(SO4)(H2O)2]·1.32H2O, (II), and poly[[diaquadi-μ3-oxydiacetato-μ3-sulfato-disamarium(III)] 1.32-hydrate], [Sm2(C4H4O5)2(SO4)(H2O)2]·1.32H2O, (III), were obtained by hydrothermal reactions of the respective lanthanide oxides and ZnSO4with oxydiacetic acid (odaH2). The Nd3+and Sm3+compounds form isomorphous crystal structures in which the lanthanide cations are nine-coordinate, having a tricapped trigonal prismatic coordination. The Pr3+compound has an entirely different crystal structure in which two types of coordination polyhedra are observed,viz.nine-coordinate (trigonal prism) and ten-coordinate (bicapped square antiprism). The sulfate anions show various coordination modes, one of which has only rarely been observed crystallographically to date.

Synthesis, Structure, and Spectral and Magnetic Properties of a Three-dimensional Cobalt(II)-Neodymium(III) Heterometal-Organic Framework Based on Oxydiacetic Acid

A new 3d-4 f heteronuclear coordination polymer containing cobalt and neodymium, [Nd2Co3(oda)6(H2O)6]·3H2O}n (1) (H2oda = oxydiacetic acid), has been synthesized and structurally characterized. In 1, the oxydiacetate dianions (oda2−) act as pentadentate ligands, and each of them chelates one Nd3+ ion and bridges two Co2+ ions. The infinite connection of metal ions and ligands results in a highly ordered 3D hexagonal channel framework. The photoluminescent, EPR and magnetic properties of the complex were also investigated.