cf3 radical
Recently Published Documents


TOTAL DOCUMENTS

26
(FIVE YEARS 1)

H-INDEX

9
(FIVE YEARS 0)

2018 ◽  
Vol 34 (6) ◽  
pp. 2708-2715 ◽  
Author(s):  
Maher Khalid ◽  
Shireen Mohammed

This review highlights recent improvement in trifluoromethylene functionalization processes with CF3 reagents, includes: Togni’s, Umemoto’s, CF3SO2Cl, CF3I, Yagupol’skii-Umemoto, TMSCF3, Langlois (CF3SO2Na) and clarifies the several designing to result the corresponding trifluoromethylated products. In this article, the selective trifluoromethylation reactions with Togni’s reagents and their analogs are detailed, which work transition metals or photoactivated Ru or Ir catalysts as single electron giver to yield CF3 radical intermediate species. This issue is to introduce a draft of diverse reports, presenting the modern reaction collect and mechanics produced during the past five years. This task is demanded by the key protocol connected with the trifluoromethylation reactions, designing to sustain researchers a straight forward understanding of such reactions and to award information for further implements.


2018 ◽  
Vol 116 (17) ◽  
pp. 2187-2195 ◽  
Author(s):  
Vanessa Cristina de Medeiros ◽  
Railton Barbosa de Andrade ◽  
Glauco Favilla Bauerfeldt ◽  
Elizete Ventura ◽  
Silmar Andrade do Monte
Keyword(s):  

2016 ◽  
Vol 14 (1) ◽  
pp. 206-210 ◽  
Author(s):  
M. Hartmann ◽  
Y. Li ◽  
A. Studer

A simple method for the determination of CF3-radical addition rate constants to various π-acceptors is introduced.


2015 ◽  
Vol 229 (10-12) ◽  
Author(s):  
Nicholas S. Shuman ◽  
Justin P. Wiens ◽  
Jordan C. Sawyer ◽  
Shaun G. Ard ◽  
Oscar Martinez Jr. ◽  
...  
Keyword(s):  

AbstractThe kinetics of reactions of the trifluoromethyl radical (CF


2015 ◽  
Vol 13 (44) ◽  
pp. 10917-10922 ◽  
Author(s):  
Xiaodan Zhang ◽  
Ping Huang ◽  
Yaming Li ◽  
Chunying Duan

A mild and fast Cu(i)-catalyzed trifluoromethylation of coumarins with CF3SO2Na and TBHP in a continuous-flow reactor has been developed.


2013 ◽  
Vol 155 ◽  
pp. 124-131 ◽  
Author(s):  
Satoshi Mizuta ◽  
Stefan Verhoog ◽  
Xin Wang ◽  
Norio Shibata ◽  
Véronique Gouverneur ◽  
...  

2013 ◽  
Vol 568-569 ◽  
pp. 55-58 ◽  
Author(s):  
J.R. Brunton ◽  
L.R. Hargreaves ◽  
S.J. Buckman ◽  
G. García ◽  
F. Blanco ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document