IMF effect on sporadic-E layers at two northern polar cap sites: Part I – Statistical study

In this paper we investigate the relationship between polar cap sporadic-E layers and the direction of the interplanetary magnetic field (IMF) using a 2-year database from Longyearbyen (75.2 CGM Lat, Svalbard) and Thule (85.4 CGM Lat, Greenland). It is found that the MLT distributions of sporadic-E occurrence are different at the two stations, but both are related to the IMF orientation. This relationship, however, changes from the centre of the polar cap to its border. Layers are more frequent during positive By at both stations. This effect is particularly strong in the central polar cap at Thule, where a weak effect associated with Bz is also observed, with positive Bz correlating with a higher occurrence of Es. Close to the polar cap boundary, at Longyearbyen, the By effect is weaker than at Thule. On the other hand, Bz plays there an equally important role as By, with negative Bz correlating with the Es occurrence. Since Es layers can be created by electric fields at high latitudes, a possible explanation for the observations is that the layers are produced by the polar cap electric field controlled by the IMF. Using electric field estimates calculated by means of the statistical APL convection model from IMF observations, we find that the diurnal distributions of sporadic-E occurrence can generally be explained in terms of the electric field mechanism. However, other factors must be considered to explain why more layers occur during positive than during negative By and why the Bz dependence of layer occurrence in the central polar cap is different from that at the polar cap boundary.

13C Fourier Transform Nuclear Magnetic Resonance. XI. Pyridine N-Oxide Derivatives

Formation of the N-oxide for several pyridine derivatives results in a large upfield shift of the 2-, 4-, and 6-carbons and a significant downfield shift of the 3- and 5-carbons. The chemical shifts (Δδ) are consistent with a resonance and electric field mechanism. Molecular orbital calculations using CNDO/2 show a qualitative correlation between excess charge density and Δδ.