Influence of Line Pair Selection on Flame Tomography Using Infrared Absorption Spectroscopy

We report the influence of absorption line selection on the tomographic results for high-temperature flames by numerical and experimental methods. Different combinations of infrared H2O absorption transitions are utilized with the Tikhonov-regularized Abel inversion to reconstruct the radial distribution of temperature and H2O concentration in a flat flame. It is shown that besides using the mathematical algorithm such as regularization, selecting a line pair with a large Δ E″ (>1390 cm−1) also reduces the reconstruction uncertainty at 300–2000 K. In this study, a proper selection of absorption line pairs reduces the reconstruction uncertainty by 25% at the same level of noise. The line pair of H2O transitions at 4029.524 cm−1 and 4030.729 cm−1 is recommended for the tomography of high-temperature flames at 1000–3000 K, whereas the line pair of 7185.597 cm−1 and 7444.352 cm−1 can be used at 300–1000 K.

Interpenetration between a polymer brush and a polymer star at thermal equilibrium: A theoretical approach

By means of the density functional theory framework I tackle the long-standing problem of a polymer star interpenetrating with a polymer brush at thermal equilibrium. Remarkably, the star is repelled to the outside of the brush once it sucks into the brush. It turns out that there could be a highly fluctuating region at the brush edge. The highly fluctuating region would be responsible for discontinuous absorption transitions by brushes. However, up to an small interpenetration length, below which asphericity of the star is maintained, the star gets collapsed by sucking more and more into the brush.

Crystallographic Features and Nature of Luminescence Centres of the Niobate and Tantalate Compounds with Layered Perovskite-Like Structure

Aim and Objectives The ultrafine powders of the perovskite-like layered AII3LaM3O12 (AII = Sr, Ba; M = Nb, Ta) compounds have been synthesized by heat treatment of co-precipitated hydroxy-carbonates. The luminescence of these compounds is reported for the first time. Methods: Luminescence spectra of all studied compounds are complex and contain two main wide bands with maxima near 2.9 and 2.5 eV. These luminescence bands were assigned to radiation electron transitions in the MoO67- molecular groups of different symmetry located in the various lattice positions. Conclusion: The energy levels scheme of the MoO67- group and related radiation and absorption transitions had been proposed.

Optically Stimulated Luminescence Dosimetry: An Introduction

A subset of solid state materials have long been used as integrating dosimeters because they store energy deposited as a result of their interactions with ionizing radiation and then, when stimulated appropriately, release a proportionate amount of visible or near-visible light. During the 1960s, thermoluminescent dosimeters (TLDs), for which heat is used to extract the stored dosimetric signal, began to replace the photographic film as occupational dosimeters of record and for medical dosimetry. At the end of the twentieth century, a viable optically stimulated luminescent (OSL) material was developed which is now gaining in popularity as both an occupational and medical dosimeter. This paper reviews the related stored luminescence processes, presenting a simple conceptual model for optical absorption transitions in OSL materials along with a basic mathematical model for delayed luminescence. The approaches for extracting signal from the OSLs are enumerated.

Natures of optical absorption transitions and excitation energy dependent photostability of diketopyrrolopyrrole (DPP)-based photovoltaic copolymers

The photostability of diketopyrrolopyrrole (DPP)-based copolymers is examined by investigating the natures of the two dominant optical absorption transitions.