stoichiometric relation
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2018 ◽  
Vol 35 (4) ◽  
pp. 73
Author(s):  
Flávio Junior Caires ◽  
Liliane Spazzapam Lima ◽  
Cláudio Teodoro De Carvalho ◽  
Massao Ionashiro

Thermal stability and thermal decomposition of succinic acid, sodium succinate and its compounds with Mn(II), Fe(II), Co(II),  Ni(II), Cu(II) and Zn(II) were investigated employing simultaneous thermogravimetry and differential thermal analysis (TG-DTA) in nitrogen and carbon dioxide atmospheres and TG-FTIR in nitrogen atmosphere. On heating, in both atmospheres the succinic acid melt and evaporate, while for the sodium succinate the thermal decomposition occurs with the formation of sodium carbonate. For the transition metal succinates the final residue up to 1180 ºC in N atmosphere was a mixture of metal and metal oxide in no 2 simple stoichiometric relation, except for Zn compound, where the residue was a small quantity of carbonaceous residue. For the CO atmosphere the final residue up to 980 ºC was: MnO, FeO, CoO, ZnO and 2 3 4 mixtures of Ni, NiO and Cu, Cu O.


2010 ◽  
Vol 35 (4) ◽  
pp. 73-80 ◽  
Author(s):  
CF. J. Caires ◽  
L. S. Lima ◽  
C. T. Carvalho ◽  
M. Ionashiro

Thermal stability and thermal decomposition of succinic acid, sodium succinate and its compounds with Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) were investigated employing simultaneous thermogravimetry and differential thermal analysis (TG-DTA) in nitrogen and carbon dioxide atmospheres and TG-FTIR in nitrogen atmosphere. On heating, in both atmospheres the succinic acid melt and evaporate, while for the sodium succinate the thermal decomposition occurs with the formation of sodium carbonate. For the transition metal succinates the final residue up to 1180 ºC in N2 atmosphere was a mixture of metal and metal oxide in no simple stoichiometric relation, except for Zn compound, where the residue was a small quantity of carbonaceous residue. For the CO2 atmosphere the final residue up to 980 ºC was: MnO, Fe3O4, CoO, ZnO and mixtures of Ni, NiO and Cu, Cu2O.


2009 ◽  
Vol 96 (1-2) ◽  
pp. 77-80 ◽  
Author(s):  
M. Taghizadeh ◽  
R. Ghasemzadeh ◽  
S.N. Ashrafizadeh ◽  
M. Ghannadi

2005 ◽  
Vol 42 (3) ◽  
pp. 301-304 ◽  
Author(s):  
Kayo SAWADA ◽  
Kazuyoshi URUGA ◽  
Tomozo KOYAMA ◽  
Takashi SHIMADA ◽  
Yukihide MORI ◽  
...  

1995 ◽  
Vol 38 (1) ◽  
pp. 7-13 ◽  
Author(s):  
Sung-Gyu Kim ◽  
Hwa-Young Lee ◽  
Jong-Kee Oh ◽  
Eung-Cho Lee

1994 ◽  
Vol 59 (11) ◽  
pp. 2454-2471 ◽  
Author(s):  
Jan Sedláček ◽  
Jiří Vohlídal ◽  
Jiří Kareš ◽  
Marta Pacovská ◽  
Bohumil Máca

Ripening of WOCl4/Ph4Sn binary catalyst of composition from 1 : 1 to 1 : 4 in benzene and toluene is a complex reaction in which initially homogeneous solution of the catalyst components continually changes to a colloidal solution, and utterly to a suspension of catalytically active particles consisted of lower-valent tungsten species in the solution of biphenyl, Ph3SnCl and, eventually, unreacted Ph4Sn (at composition 1 : 4). The yield of biphenyl is in a simple stoichiometric relation with the initial concentration of WOCl4 and a proof is given that the phenyl groups constituting biphenyl molecules come from Ph4Sn cocatalyst. The mechanism of the overall process is suggested. Above twenty, mostly phenylated derivatives of phenylacetylene (PhA) and oligomers of two degrees of unsaturation were detected as by-products of PhA reaction with the ripened catalyst formed in addition to main product, poly(phenylacetylene). The excess phenyls built in the oligomers are demonstrated to come from the supplied Ph4Sn. The mechanism is suggested for formation of the both oligomeric derivatives and growing carbene centers in which oxo ligands of tungsten centers are proposed to play a central role.


1985 ◽  
Vol 249 (3) ◽  
pp. G389-G398 ◽  
Author(s):  
D. L. Ochs ◽  
J. I. Korenbrot ◽  
J. A. Williams

Pancreatic acini were loaded with the Ca-selective fluorescent indicator quin-2 by incubation with its acetyoxymethyl ester. Loading acini with 844 +/- 133 microM quin-2 altered neither their ultrastructure nor their viability. The rate of amylase release from quin-2-loaded acini in response to the secretagogue carbachol, however, was significantly smaller than that of control acini. Studies in which acini were loaded with both quin-2 and a similar Ca-chelating compound, BAPTA, indicated that this reduced amylase release was related to the Ca buffering properties of quin-2. The concentration of free intracellular Ca calculated from the fluorescence of quin-2 was 90 +/- 18 nM. Stimulation by carbachol of acini suspended in media containing 1.25 mM Ca caused a rapid, transient enhancement of this value. After stimulation amylase release, the onset of the rise in free cytosolic Ca levels was observed in 1.1 +/- 0.1 s following the addition of agonist, and peak Ca levels (545 +/- 112 nM) were obtained within 5.3 +/- 0.3 s. For concentrations of carbachol less than or equal to 10(-6) M, a stoichiometric relation was found between stimulated amylase release and the peak concentration of free cytosolic Ca achieved. At higher concentrations of carbachol, however, the peak free cytosolic Ca remained constant while amylase release declined. The latency of the rise in intracellular Ca following stimulation of acini suspended in Ca-free media was not different from that observed for acini suspended in normal media, but the rise time was significantly prolonged. In the presence of extracellular Ca, the intracellular level of Ca remained elevated 2.8-fold above basal levels for at least 15 min following stimulation with 10(-6) M carbachol, whereas it had returned to near resting levels by 15 min when either 3 X 10(-7) or 3 X 10(-5) M carbachol was the stimulus. The Ca ionophore ionomycin (10–6 M) induced changes in the level of free cytosolic Ca similar to those caused by 10(-6) M carbachol. Ionomycin, however, stimulated only approximately one-third as much amylase release. These data suggest that factors in addition to changes in free cytosolic Ca may be important in regulating enzyme secretion by pancreatic acinar cells.


1985 ◽  
Vol 31 (8) ◽  
pp. 1355-1357 ◽  
Author(s):  
R A McPherson ◽  
K D Brown ◽  
R P Agarwal ◽  
G A Threatte ◽  
R J Jacobson

Abstract Measured triglyceride concentrations were extremely low (less than 100 mg/L) in the serum of some patients who were receiving hydroxyurea for myeloproliferative diseases. The assay being used to quantify triglycerides was a "cascaded" enzymatic method involving (a) lipase, to generate glycerol from triglycerides; (b) glycerol oxidase, to convert glycerol to glyceraldehyde, with generation of hydrogen peroxide; and (c) peroxidase, which acts on the hydrogen peroxide with subsequent coupled generation of a red-violet quinone (reagent system used in the Technicon RA-1000). Hydroxyurea added to serum samples appeared to inhibit the action of glycerol oxidase, with a stoichiometric relation to the concentration of substrate (a decrease of roughly 2.4 mmol/L in measured triglyceride per 1 mmol of hydroxyurea per liter). A different enzymatic assay for triglycerides, which involves glycerol kinase (Beckman Instruments) did not show this effect of hydroxyurea.


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