Improving Oil Recovery of the Heterogeneous Low Permeability Reservoirs by Combination of Polymer Hydrolysis Polyacrylamide and Two Highly Biosurfactant-Producing Bacteria

Polymer hydrolysis polyacrylamide and microbes have been used to enhance oil recovery in many oil reservoirs. However, the application of this two-method combination was less investigated, especially in low permeability reservoirs. In this work, two bacteria, a rhamnolipid-producing Pseudomonas aeruginosa 8D and a lipopeptide-producing Bacillus subtilis S4, were used together with hydrolysis poly-acrylamide in a low permeability heterogeneous core physical model. The results showed that when the two bacterial fermentation liquids were used at a ratio by volumeof 1:3 (v:v), the mixture showed the optimal physicochemical properties for oil-displacement. In addition, the mixture was stable under the conditions of various temperature (20–70 °C) and salinity (0–22%). When the polymer and bacteria were mixed together, it had no significant effects in the viscosity of polymer hydrolysis polyacrylamide and the viability of bacteria. The core oil-displacement test displayed that polymer hydrolysis polyacrylamide addition followed by the bacterial mixture injection could significantly enhance oil recovery. The recovery rate was increased by 15.01% and 10.03%, respectively, compared with the sole polymer hydrolysis polyacrylamide flooding and microbial flooding. Taken together, these results suggest that the strategy of polymer hydrolysis poly-acrylamide addition followed by microbial flooding is beneficial for improving oil recovery in heterogeneous low permeability reservoirs.

Fabrication and Characterization of Xanthan Gum-cl-Poly(Acrylamide-co-Alginic Acid) Hydrogel for Adsorption of Cadmium Ions from Aqueous Medium

The present research demonstrates the facile fabrication of xanthan gum-cl-poly(acrylamide-co-alginic acid) (XG-cl-poly(AAm-co-AA)) hydrogel by employing microwave-assisted copolymerization. Simultaneous copolymerization of acrylamide (AAm) and alginic acid (AA) onto xanthan gum (XG) was carried out. Different samples were fabricated by changing the concentrations of AAm and AA. A sample with maximum swelling percentage was chosen for adsorption experiments. The structural and functional characteristics of synthesized hydrogel were elucidated using diverse characterization tools. Adsorption performance of XG-cl-poly(AAm-co-AA) hydrogel was investigated for the removal of noxious cadmium (Cd(II)) ions using batch adsorption from the aqueous system, various reaction parameters optimized include pH, contact time, temperature, and concentration of Cd(II) ions and temperature. The maximum adsorption was achieved at optimal pH 7, contact time 180 min, temperature 35 °C and cadmium ion centration of 10 mg·L−1. The XG-cl-poly(AAm-co-AA) hydrogel unveiled a very high adsorption potential, and its adsorption capacities considered based on the Langmuir isotherm for Cd(II) ions was 125 mg·g−1 at 35 °C. The Cd(II) ions adsorption data fitted nicely to the Freundlich isotherm and pseudo-first-order model. The reusability investigation demonstrated that hydrogel retained its adsorption capacity even after several uses without significant loss.

Effect of Poly(acrylamide-acrylic acid) on the Fire Resistance and Anti-Aging Properties of Transparent Flame-Retardant Hydrogel Applied in Fireproof Glass

Poly(acrylamide-acrylic acid) (P(AM-co-AA)) was synthesized via the copolymerization of acrylamide and acrylic acid and well characterized by Fourier transform infrared spectroscopy. Afterward, the obtained P(AM-co-AA) was blended with flame retardants to prepare transparent flame-retardant hydrogel applied in the fireproof glass. The influence of poly(acrylamide-acrylic acid) on fire resistance and anti-aging properties of the transparent flame-retardant hydrogels were studied by assorted analysis methods. The optical transparency analysis shows that the light transmittance of the transparent flame-retardant hydrogel gradually decreases with the decreasing mass ratio of acrylamide to acrylic acid in P(AM-co-AA). Heat insulation testing shows that the heat insulation performance of fireproof glass applying the transparent flame-retardant hydrogel firstly decreases and then increases with decreasing mass ratio of acrylamide to acrylic acid in P(AM-co-AA). When the mass ratio of acrylamide to acrylic acid is 1:2, the obtained P(AM-co-AA) endows the resulting flame-retardant hydrogel applied in fireproof glass with the lowest light transmittance of 81.3% and lowest backside temperature of 131.4 °C at 60 min among the samples, which is attributed to the formation of a more dense and expanded char to prevent the heat transfer during combustion, as supported by the digital photos of char residues. The results of TG analysis indicate that P(AM-co-AA) imparts high thermal stability to the resulting hydrogels due to the hydrogen bonds between carboxyl and amide groups. The accelerated aging test shows that the transparent flame-retardant hydrogel containing P(AM-co-AA) is less affected by aging conditions. Especially, when the mass ratio of acrylamide to acrylic acid in P(AM-co-AA) is 4:1, the resulting transparent flame-retardant hydrogel shows a light transmittance of 82.9% and backside temperature of 173.1 °C at 60 min after 7 aging cycles, exhibiting the best comprehensive properties among the samples.

Development of pH-Sensitive Chitosan-g-poly(acrylamide-co-acrylic acid) Hydrogel for Controlled Drug Delivery of Tenofovir Disoproxil Fumarate

The present study aimed to develop a pH-sensitive chitosan-based hydrogel for controlled delivery of an anti-hepatitis B drug, tenofovir disoproxil fumarate (TDF). Free radical polymerization was utilized to graft acrylamide and acrylic acid using N,N-methylene bisacrylamide as the crosslinker. Physicochemical characterization confirmed the synthesis of thermally stable chitosan-g-poly(acrylamide-co-acrylic acid) hydrogels with well-defined pores within a fibrous surface. The prepared hydrogels exhibited pH and ionic strength sensitivity, with the swelling significantly lower under acidic and strong ionic strength conditions but higher in neutral and basic solutions. In addition, cytotoxicity studies on HeLa cell lines proved the cytocompatibility of the drug delivery material and its readiness for physiological applications. The encapsulation of TDF in the hydrogels was optimized and an encapsulation efficiency and a drug loading percentage of 96% and 10% were achieved, respectively. More interestingly, in vitro release studies demonstrated a pH-dependent release of TDF from hydrogels. The release at pH 7.4 was found to be up to five times higher than at pH 1.2 within 96 h. This further suggested that the newly developed hydrogel-loaded TDF could be proposed as a smart delivery system for oral delivery of anti-hepatitis B drugs.