The Mechanism of Formation of Finely Dispersed Minerals on the Surface of Diamonds and the Application of Electrolysis Products of Water Systems for their Destruction

The composition of the surface of natural diamonds in interaction with kimberlite minerals and the aqueous phase in the depositand enriched ore is studied. The sequence and conditions for the formation of minerals on the surface of crystals under conditionsof processing of kimberlites have been determined. Confirmed the mechanism of hydrophilization of diamonds comprising crystallizationof hydroxides and oxides of iron as a mandatory initial stage. A method of destruction or subsequent dissolution of mineralsaggregates by the impact of electrolysis products of aqueous systems has been proposed, which allows to restore the hydrophobicityof diamonds. The use of electrochemically treated water in the froth separation cycle with high diamond recovery made it possibleto increase their recovery in the factory’s concentrate by 8.8%.

The electrochemical reduction mechanism of Fe3O4 in NaCl-CaCl2 melts

In order to study the process of Fe3O4 reduction by melt electro-deoxidation. Electrochemical method was used to analyze the reduction mechanism of Fe3O4 in NaCl-CaCl2 melts. The effects of cell voltage and time on the product were discussed through constant cell voltage electrolysis. The results showed: (1) The reduction of solid Fe3O4 to metallic Fe is a two-step process for obtaining electrons. (2) The transformation process (600 min, 0–1.0 V) of the electrolysis products with the increase of the cell voltage is as follows: Fe3O4 → FeO → FeO + Fe → Fe. (3) The intermediate product Ca2Fe2O5 was formed (2.0 V, 10–300 min), which inhibited the deoxygenation process in the early stage of the reaction. When the electrolysis time exceeds 60 min, the main reaction is the reduction of Ca2Fe2O5 to Fe.

Transformation of the Nanoporous Structure of Anodic Aluminium Oxide and its “Nonelectrolysis” Electroluminescence

On a film of aluminum oxide (Al2O3) formed by electrolytic oxidation in distilled water (DW), the growth, transformation of its nanoporous structure, and the generation of electroluminescence (EL) in ketones and related compounds containing carbonyl groups were studied. For those contributing to the brightest EL – acetylacetone and methylpyrrolidone, it was found that the processes described in these electrolytes proceed with the highest intensity. Under the same electrolytes and conditions, similar processes, but with a lower intensity, proceed for A2O3 formed on pure aluminum. It was found that, with the external voltage, thermodynamic and geometrical parameters of the electrolytic system being constant, the brightness characteristics of the EL of the anodic Al2O3 are influenced by its structural organization and the electrophysical characteristics of the electrolyte surrounding the oxide film, which is proposed to be arbitrarily called “nonelectrolysis” because electrolysis products are not revealed in it.

Method for determining bond energy in nanostructured water

ABSTRACTUsing water as an example, it is shown that monitoring the change in the loss tangent is a high sensitive method that allows determining the activation energy of relaxation processes in nanostructured water with high accuracy. The use of sensors, the electrodes of which are not in direct contact with the liquid under study is shown to be reasonable. The conditions for obtaining reliable information on the properties of water and its solutions are also justified, namely: measurements should be carried out using pulse methods for several seconds, and then measurements should be stopped to avoid contamination of the solutions studied by electrolysis products. The method of monitoring the magnitude of the loss tangent at fixed frequencies allows the acidity of solutions (pH value) to be controlled at the same time without using specialized instruments for acidity studying.

Efficiency Measurement Approach for a Hydrogen Oxyfuel Combustor

Higher shares of variable renewable generation have already raised the demand for energy storage and network services in the power sector. As this trend is expected to continue, the combination of these services in a large scale will be imperative toward a carbon-free power sector. A very promising way to perform this task without any additional emissions is through stoichiometric combustion of the electrolysis products (H2 and O2) in steam and the injection of the generated steam in a conventional steam cycle. However, this can be done only if the product steam has only traces of the two reactants in it, in order to avoid damage of downstream components. The amount of residual gas in the product steam is a direct function of the combustion efficiency. This work analyzes the combustion efficiency of a H2/O2 combustor under steam dilution. As the product gas of such a combustor is primarily steam, the intended efficiency measurement is very challenging and cannot be performed with conventional methods. Instead, an in situ measurement of oxygen and hydrogen is applied. The respective diagnostics and challenges are presented along with the combustion efficiency results. Moreover, a combustor design study is carried out and different flame types (jet and swirl-stabilized flames) are compared. The initial results demonstrate that steam-diluted H2/O2 combustion can achieve an efficiency close to 100%.

Electrochemical reduction of artemisinin: Chromatographic identification of bulk electrolysis products

Artemisinin is a naturally occurring sesquiterpene lactone with an endo-peroxide bond. This drug is used for treatment of many diseases including malaria. The reduction of this molecule on an electrode surface was carried out by cyclic voltammetry as well as amperometry. Cyclic voltammetry of artemisinin generated one prominent peak wave at -1.0 V and another, smaller one at -0.3 V vs Ag/AgCl reference electrode. The bulk electrolysis of artemisinin on a carbon electrode generated two other irreversible peak waves at around -0.7 and -0.1 V. The concentration of the products was dependent on the time of electrolysis. LC-MS was used to determine the bulk electrolysis products of artemisinin. Initially dihydroartemisinin was generated as the main reduction product. Other reduction products were formed after further reduction of dyhidroartemisinin.

A versatile and membrane-less electrochemical reactor for the electrolysis of water and brine

Separation of electrolysis products using fluidic inertial forces in a 3D printed flow cell.

Research on Stagger Coupling Mode of Pulse Duration and Tool Vibration in Electrochemical Machining

Tuning the coupling of pulse duration and tool vibration in electrochemical machining (PVECM) is an effective method to improve machining accuracy and surface quality. In general, the pulse is set at the same frequency as the tool vibration, and a symmetrical distribution is attained at the minimum inter-electrode gap. To analyse the characteristics of the electrolyte fluid flow and of the electrolysis products in the oscillating inter-electrode gap, a dynamic simulation of the PVECM process was carried out. The simulation results indicated that the electrolyte pressure and gas void fraction when the pulse arrived as the inter-electrode gap was narrowing clearly differed from those when the inter-electrode gap was expanding. Therefore, in addition to the traditional symmetry coupling mode, two other coupling modes called the pre-position and the post-position coupling modes are proposed which use a pulse either just before or just after the minimum inter-electrode gap. Comparative experiments involving the feed rate and machining localization were carried out to evaluate the influence of the three coupling modes. In addition, current waveforms were recorded to analyse the differences between the three coupling modes. The results revealed that the highest feed rate and the best machining localization were achieved by using the pre-position coupling mode.

On-chip label-free protein analysis with downstream electrodes for direct removal of electrolysis products

Single-layer lithography microfluidic devices for applying high and stable electric fields on chip.