Multitudes of Voigt - Reuss forks and Voigt - Christensen - Reuss tridents

In the literature, there are many studies of the representative volume of a composite material, in particular, those calculated using the formulas of Christensen, Voigt and Reiss. The aim of this work is to study the features of evaluating the set of forks of effective modules. Methods. On the basis of solving the Lame problem (for a thick-walled sphere), a spherical model of a representative volume (cell) of a composite material with a granular (spherical) filler is compiled and the value of the effective modulus of elasticity of a two-phase composite is determined. The study of the obtained formula for the effective modulus, expressed in dimensionless quantities, for the cell material revealed its identity with the R.M. Christensens formula, expressed in dimensional values, for the bulk modulus of composites with a spherical filler. In this case, Christensens solution was previously obtained by a different method when he considered the polydisperse model of the composite. The dimensionless form of the function (effective module) of three dimensionless parameters made it possible in flat spaces (two coordinate planes) to construct graphical images of the function of the named modules according to Christensen, which are compared and combined in one figure with similar images of the functions of estimating the values of the modules (real composites) according to Voigt and Reiss. Graphical studies in relation to the spherical representative volume model show that in the flat space of the set of Voigt - Reuss forks, these forks are not narrowed, but they are partially filled by the flat space of the set of Christensen - Reiss forks. The graphs of the functions of the modules, at the same time, form, simultaneously with the sets of two-toothed forks, a set of Voigt - Christensen - Reiss trident forks (tridents), which, depending on the size of the intervals of the numbers of the studied parameters, have forks of different sizes. Results. Graphic illustrations of numerical examples have been obtained showing that for given values of the module of the matrix and filler and the volume fraction of the latter, it is possible to determine the effective volumetric module and shear module of two-phase composites, and to perform a comparison with the conclusions of the applied plan. The dimensionless form of the obtained expressions makes it possible to solve the inverse problems of the mechanics of polydisperse composites, for example, to determine the volume module of the composite components by the effective modulus obtained by mechanical testing of standard samples.

COMPUTATIONAL INVESTIGATION OF THE EFFECTS OF SPHERICAL FILLER MORPHOLOGY AND LOADING ON DIFFUSION TORTUOSITY AND RUBBER PERMEABILITY

ABSTRACT Inflation pressure loss in tires degrades performance, raises rolling resistance, and reduces fuel economy. The incorporation of solid fillers, such as carbon black, at relatively high loadings in tire innerliners helps minimize these pressure losses by reducing innerliner permeability due to increases in average gas molecule diffusion path lengths (tortuosity), as well as reductions in diffusion pathway density (capacity). The effects of filler morphology and loading on diffusion path tortuosity can be explored by modeling biased random-walk diffusion through impermeable sphere-filled matrices. Modeled diffusion rate was found to decrease with increased filler loading, reduced filler sphere sizes, increased random-walk step sizes, and the aggregation of filler spheres. Initial correlations with limited empirical permeability measurements are used to validate the model approach.

Properties of a Dental Resin Composite with a Spherical Inorganic Filler

Clinical Relevance Of the materials tested in this study, the spherical filler composite (Estelite Σ) had similar properties as the nano-composite (Filtek Supreme). Thus, Estelite Σcan be used in anterior regions and restricted posterior restorations. All the materials had a similar shrinkage pattern, in that about 99% of the shrinkage occurred prior to 24 hours; thus, for direct resin composite restorations, a strong initial bonding strength with bonding agent would be necessary.