Facile Fabrication of Nanoemulsions through the Efficient Catanionic Surfactants for Spontaneous Imbibition in Tight Oil Reservoirs: Experimental and Numerical Simulation

Spontaneous imbibition (SI) is an essential method for accelerating mass exchange between fracture and matrix in tight oil reservoirs. However, conventional systems such as brine and surfactant solution have limited imbibition effects, so there is still abundant remaining oil in the matrix. Nanoemulsion holds the most promising potential in improving tight oil recovery owing to the favorable surface activity and nanoscale droplets, but it still lacks economic and facile methods to fabricate nanoemulsions. Therefore, in this paper, we prepared a kind of O/W nanoemulsion of catanionic surfactants with a low dosage of surfactant and energy consumption, which was then used to assess spontaneous imbibition performance in Changqing outcrop cores by experimental and numerical simulation. We have fully considered the possible imbibition mechanisms of nanoemulsion including wettability alteration, IFT reduction, solubilization and emulsification, etc., and successfully applied to the nanoemulsion imbibition model. The model and experimental data were found to be in good agreement. The results showed that the imbibition rate and oil recovery factor of the nanoemulsion in the first 100 hours are lower than that of brine. In the late stage, we observed a longer equilibrium time and a faster and higher oil imbibition process in nanoemulsion with ultralow IFT. Finally, we confirmed that solubilization and emulsification is one of the domiant mechanisms for nanoemulsion imbibition by comparing with the modelling without considering solubilization and emulsification.

Interplay between aggregation number, micelle charge and hydration of catanionic surfactants

Alkyltrimethylammonium alkanecarboxylates, [CxMe3N]+[Cy]−, with medium to long alkyl chains on both cation and anion (x,y = 6–10), were investigated in aqueous solution by density and zeta potential measurements, ITC, and DRS.