Rhodamine 6G based efficient chemosensor for the trivalent metal ions (Al3+, Cr3+ and Fe3+) upon single excitation with applications in combinational logic circuits and memory devices

A new rhodamine 6G based chemosensor (L3), has been synthesized and characterized by 1H, 13C, IR and Mass spectroscopy studies. It exhibits an excellent selective and sensitive CHEF based recognition...

Response of a Zn(II)-based Metal-Organic Coordination Polymer towards Trivalent Metal Ions (Al3+, Fe3+, Cr3+) Probed by Spectroscopic Approaches

A new zinc-based two-dimensional coordination polymer, [Zn(5-AIP)(Ald-4)]·H2O (5-AIP = 5-amino isophthalate, Ald-4 = aldrithiol-4), 1, has been synthesized at room temperature by layer diffusion technique. Single-crystal X-ray diffraction analysis of...

Complexes of In(III) with 8-hydroxyquinoline-5-sulfonate in solution: Structural studies and the effect of cationic surfactants on the photophysical behaviour

Following previous studies on the complexation in aqueous solutions of 8-hydroxyquinoline-5-sulfonate (8-HQS) with the trivalent metal ions, Al(III) and Ga(III) and various other metal ions, using multinuclear NMR, DFT calculations,...

INVESTIGATION OF THE PROCESS OF CHEMICAL CROSSLINKING OF NA-CMC POLYVALENT METAL IONS

This article is devoted to the study of the Na-CMC structuring process under various conditions: structuring with polyvalent metal ions, structuring with polyvalent metal ions in the presence of polybasic acids. Structuring in a Na-CMC solution was investigated by adding polyvalent metal ions to it at various ratios Me+p / COO-, pH, which allowed us to characterize the structuring process as a reaction of macromolecules with low molecular weight compounds.It was found that the probability of intermacromolecular crosslinking, responsible for gelation, increases with an increase in the initial concentration of Na-CMC solution and with the additional presence of polybasic acids. When salts of polyvalent metals interact with solutions of polybasic acids in the presence of a 2N NaOH solution, their complex salts are formed.Titration calculations and IR spectra of dried salts confirmed the conclusion made about the formation of salts of structure I, II, III, IV. Crosslinking of Na-CMC has been shown to occur via compounds of the M2+ (3+) - OOS-R-type. It has been established that strong, transparent jellies are formed by trivalent metal ions, divalent metal ions also form brittle, cloudy jellies that stratify during a day.A suggestion has been made that the main reaction during gelation of the Na-CMC solution is the interaction of -COOH groups along the chain of the Na-CMC macromolecule with the Al+3 salt and citric acid of structure III. The role of citric acid is that it is a transverse bridge in the binding of Na-CMC macromolecules. During the process of chemical crosslinking, the system turns from a fluid state into a non-fluid one, and the dynamic viscosity of the system increases from 3.548 Pa·s to 1585 Pa·s.

Water shut off gel

Injection of Partially Hydrolyzed Polyacrylamide gels using inorganic crosslinking agents has proven to be one of the best methods for isolating water and enhancing oil recovery. Partially hydrolyzed polyacrylamide forms a gel structure in the presence of trivalent metal ions such as Cr3+, Al3+, which act as a crosslinker. In this case, a sequential injection of a polymer solution and a crosslinking agent is carried out into the formation and the gel is formed directly in the formation. Numerous successful examples of the implementation of this technology to reduce the water cut of the produced products were the basis for the development of a new gel composition, taking into account the disadvantages of the existing ones. The paper presents the results of laboratory studies on core material using the proposed gel composition based on a partially hydrolyzed polyacrylamide polymer and various crosslinking agents (note: thiourea / K2Cr2O7).

Simultaneous separation of Am and Cm from Nd and Sm by multi-step extraction using the TODGA-DTPA-BA-HNO3 system

The simultaneous separation of Am and Cm from lanthanides is important for atomic energy fields. However, the process is difficult owing to the chemical behavior of trivalent metal ions with similar ionic radii. All lanthanides, Am, and Cm can be extracted by diglycolamide (DGA). In addition, relatively high separation factors between An and Ln were obtained by the extraction system of TODGA, DTPA (diethylenetriamine-N,N,N′,N″,N″-pentaacetic acid) and HNO3. In this work, DTPA-BA (diethylenetriamine-N,N′,N″-triacetic-N,N″-bisamide), which is an improved version of DTPA, was employed for the separation of Ln and An. After performing a basic study on DTPA-BA, a relatively high separation factor (approximately 8) for actinides/lanthanides was obtained. Then, the multi-step extraction was performed. Thus, the recoveries of 94.7 % for Nd and 4.7 % for Am and Cm in organic phase, and 5.3 % Nd and 95.3 % for Am and Cm in aqueous phase were obtained.