A bibliometric study on biomimetic and bioinspired membranes for water filtration

Insights into the biological channels and synthetic pore-forming assemblies have elucidated many fundamental aspects of selective water and solute transport over the last few decades. This has led to the development of novel technologies with unique selectivity and permeability. In terms of membrane separation technology, this development has proceeded by adapting either of two approaches: (i) one where biological channel proteins are reconstituted in suitable materials mimicking the biological bilayer membrane and (ii) one where selective transport is mimicked in synthetic structures. The development of water filtration membranes in the former approach takes advantage of aquaporin proteins as representative building blocks and that of carbon nanotubes and molecular pore-forming assemblies in the latter approach. The first approach is often referred to as the field dominated by biomimetic membranes and the latter referred to as artificial water channels. In this study, a bibliometric analysis was conducted to investigate trends in these two areas based on growing publication trends, peer-reviewed journal selection, countries, institutions, authors, and collaborative networks. A total of 3199 records available from Scopus between 1962 and 2021 were extracted and analyzed. The results showed strong international collaborations and highlighted leading researchers and hubs of excellence in these two areas. This is very timely considering that the UN climate change conference (COP26) in Glasgow, UK later this year will bring focus to the global need for water treatment technologies. This work can serve as a quick reference for early-career researchers and industries working in the area of membrane development for water purification/filtration.

On the Efficacy of Water Transport in Leaves. A Coupled Xylem-Phloem Model of Water and Solute Transport

In this paper, we present and use a coupled xylem/phloem mathematical model of passive water and solute transport through a reticulated vascular system of an angiosperm leaf. We evaluate the effect of leaf width-to-length proportion and orientation of second-order veins on the indexes of water transport into the leaves and sucrose transport from the leaves. We found that the most important factor affecting the steady-state pattern of hydraulic pressure distribution in the xylem and solute concentration in the phloem was leaf shape: narrower/longer leaves are less efficient in convecting xylem water and phloem solutes than wider/shorter leaves under all conditions studied. The degree of efficiency of transport is greatly influenced by the orientation of second-order veins relative to the main vein for all leaf proportions considered; the dependence is non-monotonic with efficiency maximized when the angle is approximately 45° to the main vein, although the angle of peak efficiency depends on other conditions. The sensitivity of transport efficiency to vein orientation increases with increasing vein conductivity. The vein angle at which efficiency is maximum tended to be smaller (relative to the main vein direction) in narrower leaves. The results may help to explain, or at least contribute to our understanding of, the evolution of parallel vein systems in monocot leaves.

Simulating preferential soil water flow and reactive solute transport using the Lagrangian Soil Water and Solute Transport Model (LAST)

<p>Recently, we proposed an alternative model concept to represent rainfall-driven soil water dynamics and especially preferential water flow and solute transport in the vadose zone. Our LAST-Model is based on a Lagrangian perspective on the movement of water particles (Zehe and Jackisch, 2016) carrying solute masses through the subsurface which is separated into a soil matrix domain and a preferential flow domain (Sternagel et al., 2019). The preferential flow domain relies on observable field data like the average number of macropores of a given diameter, their hydraulic properties and their vertical length distribution. These data may either be derived from field observations or by inverse modelling using tracer data. Parameterization of the soil matrix domain requires soil hydraulic functions which determine the parameters of the water particle movement and particularly the distribution of flow velocities in different pores sizes. Infiltration into the matrix and the macropores depends on their respective moisture state and subsequently macropores are gradually filled. Macropores and matrix interact through diffusive mixing of water and solutes between the two flow domains which again depends on their water content and matric potential at the considered depths.</p><p>The LAST-Model was evaluated using tracer profiles and macropore data obtained at four different study sites in the Weiherbach catchment in south Germany and additionally compared against simulations using HYDRUS 1-D as benchmark model. The results generally corroborated the feasibility of the model concept and particularly the implemented representation of macropore flow and macropore-matrix exchange. We thus concluded that the LAST-Model approach provides a useful and alternative framework for simulating rainfall-driven soil water and solute dynamics and fingerprints of preferential flow.</p><p>This study presents an extension of the model allowing for the simulation of reactive solute transport. Transformation kinetics are considered by transferring mass from the parent to the child components in each water particle according to the corresponding reaction rates, which is limited by the compound solubility. A retardation coefficient is not helpful in the particle-based framework, as the solute mass is carried by the water particles and travels thus by default at the same velocity. Ad- and desorption are explicit represented through transfer of dissolved mass from the water particles at a given depth to surrounding adsorption sites of the soil solid phase and vice versa. This may either operate under rate-limited or non-limited conditions. Adsorbed solute masses will be considered to be degraded following first-order reaction kinetics. The retardation process delays the solute displacement and enables a suitable time scale for the degradation process, which must be smaller than the time scale for the re-mobilization of the solutes. The proposed extension will be benchmarked against observations of pesticide transport in soil profiles and at tile-drained field sites.</p><p> </p><p>Zehe, E., Jackisch, C.: A Lagrangian model for soil water dynamics during rainfall-driven conditions, Hydrol. Earth Syst. Sci., 20, 3511–3526, https://doi.org/10.5194/hess-20-3511-2016, 2016.</p><p> </p><p>Sternagel, A., Loritz, R., Wilcke, W., and Zehe, E.: Simulating preferential soil water flow and tracer transport using the Lagrangian Soil Water and Solute Transport Model, Hydrol. Earth Syst. Sci., 23, 4249–4267, https://doi.org/10.5194/hess-23-4249-2019, 2019.</p>

Evaporation-Induced Water and Solute Coupled Transport in Saline Loess Columns in Closed and Open Systems

Evaporation-induced water and solute coupled transport is a significant cause for soil salinization that leads to a series of engineering and environmental problems. In the artificial evaporation environment, including relative humidity, atmospheric temperature, atmospheric pressure, radiation intensity, and wind speed, evaporation of loess columns with sodium sulfate, temperature profile, and water and solute transport in closed and open systems were investigated. In the former case, a range of stability was noted in the lower part of the column where the heat, water, and solute coupled transport only exhibited a weak response to a specified evaporation environment. As the environment was more favorable for evaporation, or at a higher gradient of temperature, this range extended downwards, while above this range the heat, water, and salt profiles in the evaporation-affected domain changed dramatically, characterized by a basic law that solutes moved with water and were then retained with water desalinated. Evidences were found from the profiles that the water contents in the evaporation-affected range decreased but the salt contents increased, especially in the surface. In an open system, by contrast, there was little difference in temperature but greater in water and salt profiles. Three stages were found from the supply of external water during evaporation. In the initial stage, the higher gradient formed between the initial moisture state and the preset external water level led to a rapid supply of external water. As the evaporation proceeded, a relatively stable water profile was reached as the intensity of water supply approached to that of evaporation, accompanied by a continual migration of solutes towards the surface. Due to the accumulation of precipitated salts, water transport was slowed down, and the intensity of water supply decreased. The changes in soil suction may account for the above behavior.

Simulating preferential soil water flow and tracer transport using the Lagrangian Soil Water and Solute Transport Model

We propose an alternative model concept to represent rainfall-driven soil water dynamics and especially preferential water flow and solute transport in the vadose zone. Our LAST-Model (Lagrangian Soil Water and Solute Transport) is based on a Lagrangian perspective of the movement of water particles (Zehe and Jackisch, 2016) carrying a solute mass through the subsurface which is separated into a soil matrix domain and a preferential flow domain. The preferential flow domain relies on observable field data like the average number of macropores of a given diameter, their hydraulic properties and their vertical length distribution. These data may be derived either from field observations or by inverse modelling using tracer data. Parameterization of the soil matrix domain requires soil hydraulic functions which determine the parameters of the water particle movement and particularly the distribution of flow velocities in different pore sizes. Infiltration into the matrix and the macropores depends on their respective moisture state, and subsequently macropores are gradually filled. Macropores and matrix interact through diffusive mixing of water and solutes between the two flow domains, which again depends on their water content and matric potential at the considered depths. The LAST-Model is evaluated using tracer profiles and macropore data obtained at four different study sites in the Weiherbach catchment in southern Germany and additionally compared against simulations using HYDRUS 1-D as a benchmark model. While both models show qual performance at two matrix-flow-dominated sites, simulations with LAST are in better accordance with the fingerprints of preferential flow at the two other sites compared to HYDRUS 1-D. These findings generally corroborate the feasibility of the model concept and particularly the implemented representation of macropore flow and macropore–matrix exchange. We thus conclude that the LAST-Model approach provides a useful and alternative framework for (a) simulating rainfall-driven soil water and solute dynamics and fingerprints of preferential flow as well as (b) linking model approaches and field experiments. We also suggest that the Lagrangian perspective offers promising opportunities to quantify water ages and to evaluate travel and residence times of water and solutes by a simple age tagging of particles entering and leaving the model domain.