Hydrogeochemistry and Groundwater Quality Assessment in the High Agri Valley (Southern Italy)

The High Agri Valley (southern Italy) is one of the largest intermontane basin of the southern Apennines affected by intensive agricultural and industrial activities. The study of groundwater chemical features provides much important information useful in water resource management. In this study, hydrogeochemical investigations coupled with multivariate statistics, saturation indices, and stable isotope composition (δD and δ18O) were conducted in the High Agri Valley to determine the chemical composition of groundwater and to define the geogenic and anthropogenic influences on groundwater quality. Twenty-four sampling point ( including well and spring waters) have been examined. The isotopic data revealed that groundwater has a meteoric origin. Well waters, located on recent alluvial-lacustrine deposits in shallow porous aquifers at the valley floor, are influenced by seasonal rainfall events and show shallow circuits; conversely, spring waters from fissured and/or karstified aquifers are probably associated to deeper and longer hydrogeological circuits. The R -mode factor analysis shows that three factors explain 94% of the total variance, and F1 represents the combined effect of dolomite and silicate dissolution to explain most water chemistry. In addition, very low contents of trace elements were detected, and their distribution was principally related to natural input. Only two well waters, used for irrigation use, show critical issue for NO3- concentrations, whose values are linked to agricultural activities. Groundwater quality strongly affects the management of water resources, as well as their suitability for domestic, agricultural, and industrial uses. Overall, our results were considered fulfilling the requirements for the inorganic component of the Water Framework Directive and Italian legislation for drinking purposes. The water quality for irrigation is from “good to permissible” to “excellent to good” although salinity and relatively high content of Mg2+ can occasionally be critical.

Study of Well Waters from High-Level Natural Radiation Areas in Northern Vietnam

The determination of natural radionuclide concentrations plays an important role for assuring public health and in the estimation of the radiological hazards. This is especially true for high level radiation areas. In this study, 226Ra, 228Ra and 238U concentrations were measured in well waters surrounding eight of the high-level natural radiation areas in northern Vietnam. The 226Ra, 228Ra and 238U activity concentrations vary from <1.2 × 10−3–2.7 (0.46), <2.6 × 10−3–0.43 (0.07) and <38 × 10−3–5.32 Bq/L (0.50 of median), respectively. 226Ra and 238U isotopes in most areas are in equilibrium, except for the DT-Thai Nguyen area. The calculated radiological hazard indices are generally higher than WHO (World Health Organization) recommendations. Average annual effective dose and excess lifetime cancer risk values due to drinking well water range from to 130 to 540 μSv/year and 7.4 × 10−6 to 3.1 × 10−5, respectively.

Assessment of the impact of Imzouren city’s WWTP on the quality of the surrounding groundwater, at the Rif Central (Northern Morocco)

The groundwater of the Ghis-Nekor aquifer (Central Rif of Morocco) is the main water resource used by the inhabitants for agricultural and domestic purposes. However, its low quality may affect the health of the consumer and weaken agricultural production. The existence of the WWTP at the level of this plain, makes it a probable source of pollution for these groundwater and requires urgent water managers’ intervention. Groundwater pollution in this area may be related to natural, anthropogenic and undefined sources (agricultural and industrial activities). To assess the impact of WWTP effluent on this aquifer, ten well water samples were collected upstream and downstream of this WWTP in 2018, and then analysed for physicochemical quality. Multivariate and principal Component Analysis (PCA) of the results obtained revealed two main components, in which the largest source of total variation being F1 presented at 54.75%. The PCA has visualized two groups that distinguish slightly mineralized well waters upstream to moderately from other wells downstream of the WTTP that are highly mineralized. Generally, the groundwater in the study area is characterized by high levels of salinization. The results of this study may be useful for monitoring and managing groundwater pollution in the study area.

Hydrochemical investigation of the wells water in Bayanzurkh, Ulaanbaatar

This study aimed to determine water-rock interactions depending on mineralization and assess to detailed water quality study of the well waters for drinking purpose in Bayanzurkh district. Totally, 55 well water samples were collected from 7subdistricts of Bayanzurkh district. Determinations of the all sample are performed by water quality parameters such as radiological, physico-chemical and chemical compositions and microbiological properties. The chemical data illustrates that the well waters were neutral to slightly alkaline, and total hardness observed in 46 water samples was soft to softer and 9 water samples was hard to very hard. The hydrochemical data indicates that 53 well waters belong to the HCO3- - Ca2+, Mg2+ type, and others are HCO3-- Mg2+ and SO42--Na+ type of water. The results were compared with National standard (MNS 0900:2018) and with World health organization (WHO, 2017) guidelines for drinking water quality. Among these 25 well waters were overrated by permissible concentration of MNS 0900:2018 and WHO guidelines for the following radiological, chemical compositions and microbiological properties. However, 30 well waters were suitable for drinking water by their permissible value of national standards. According to the Gibbs diagram, all studied well waters were belonging to the rock-water interaction dominance area which was indicated by hydrochemical processes. Баянзүрх дүүргийн гүний худгуудын усны гидрохимийн судалгаа Хураангуй: Энэхүү судалгаагаар Баянзүрх дүүргийн иргэдийн унд ахуйн хэрэгцээндээ ашиглаж буй гүний худгийн усанд нарийвчилсан судалгааг явуулсаны үндсэн дээр усны чанарыг үнэлэх мөн эрдэсжилтээс хамааруулан ус чулуулгийн харилцан үйлчлэлийг тодорхойлох зорилгоор энэхүү ажлыг хийж гүйцэтгэсэн. Баянзүрх дүүргийн 7 хороонд байрлах унд ахуйн зориулалтаар ашигладаг 55 гүний худгийн усны сорьцонд физик-хими, химийн найрлага, микроэлемент, бичил амь судлал болон цацрагийн аюулгүйн үзүүлэлтүүдийг тодорхойлсон болно. Судалгаанд хамрагдсан гүний худгуудын ус нь саармагаас сул шүлтлэг орчинтой, зөөлнөөс зөөлөвтөр устай 46 худаг, хатуувтараас хатуу устай 9 худаг байгаа ба 53 гүний худаг нь HCO3- - Ca2+, Mg2+-ийн төрлийн, бусад нь HCO3-- Mg2+ болон SO42--Na+ төрлийн усны ангилалд хамаарагдаж байна. Баянзүрх дүүргийн иргэдийн унд ахуйн хэрэгцээндээ ашиглаж буй нийт 55 гүний худгийн ус судалгаанд хамрагдсанаас 25 худгийн ус нь зарим анион, катион болон бичил амь судлал, цацрагийн аюулгүйн үзүүлэлтээрээ Монгол улсад мөрдөгдөж байгаа ундны усны стандарт MNS 0900:2018 болон Дэлхийн Эрүүл Мэндийн байгууллагаас гаргасан улс орнуудын мөрддөг ундны усны стандарт шаардлагыг хангахгүй байна. Харин 30 гүний худгийн ус нь бүх үзүүлэлтээрээ Монгол улсад мөрдөж буй MNS 0900:2018 стандартын шаардлагыг хангаж байна. Ус, чулуулгийн харилцан үйлчлэлийг Гиббсийн диаграмм ашиглан тодорхойлоход худгуудын ус нь чулуулаг давамгайлсан мужид оршиж байгаа нь худгийн усны найрлага тухайн орчны геологийн тогтоц болон чулуулгаас хамаарч байгаа бөгөөд ус, чулуулгийн харилцан үйлчлэлд орж байна. Түлхүүр үг: Баянзүрх дүүрэг, ундны ус, химийн найрлага, гүний худаг, ус, чулуулаг

THE ROLE OF THE WELL WATERS OF THE MAUSOLEUM OF KHOJA AHMED YASAVI IN THE FORMATION OF SALTS

The work is devoted to the study of the chemical composition of well waters located on the territory of the mausoleum complex of Khoja Ahmed Yasavi. On the basis of experimental studies, the salinity of well waters increases every year. It is especially different in 2019 when, compared to the previous 10 years (2009-2018), there was a sharp increase in the total salt content by 1,5 times in the inner well and about 2,3 times in the outer well. The reason for this is the intense pollution of atmospheric air, soil, plants and other environmental objects due to an increase in the volume of construction work resulting from this waste, the number of servicing vehicles and the emergence of a number of new anthropogenic factors. The article also considers data from the Kazhydromet of the Republic of Kazakhstan that characterize changes in natural and climatic conditions, exactly, the amount of precipitation by month. Based on the calculated data, we have shown that water evaporation is 4-5 times higher than the amount of precipitation in the region. As a result of evaporation, moisture rises through the capillaries and is further saturated with salts found in building materials. Further, the formed saturated salt solution, undergoing various transformations, such as crystallization, contributes to the formation of salt deposits on the surface of the foundation materials and further walls. This negative phenomenon is one of the factors that lead to a decrease in the stability and safety of the architectural monument.

Tekirdağ İli Yeraltı Suları Kalitesinin Sulama Suyu Açısından Değerlendirilmesi

This study includes some deep underground well waters opened to supply the irrigation water in Tekirdağ province. The sampling was done from 22 wells in the irrigation season period. The parameters such as pH, EC, TDS, Na, Ca, Mg, K, Cl, HCO3, B, NO3-N, Sodium Absorption Ratio and Residual Sodium Carbonate parameters, which were significant in terms of irrigation water classification, were examined in the samplings. According to the results, it was determined that thirteen well waters were in medium salty and eight well waters were in high salty water classes. Besides, Na and HCO3 harms were determined in five and three well waters, respectively. In seven well waters, it was concluded that RCE values were over 2,5 me L-1 and these water were not suitable in the usage of irrigation. As a result of the evaluations in terms of the specific ions, it was determined that CL, B and NO3-N concentrations which were found in three, two and one wells respectively, could create damages in some crops. As a result of the evaluations in terms of salinity and SAR parameters, it was concluded that the usage of T5, T6, T8, T10, T13 and T14 well waters was undesirable and the usage of T9, T11, T12, T16, T17 and T21 well waters can be suggested by the provision of some special conditions (appropriate drainage conditions, appropriate plant selection, coarse textured soils).