Sequence-regulated vinyl polymers via iterative atom transfer radical additions and acyclic diene metathesis polymerization

Iterative ATRAs and ADMET polymerization enabled the synthesis of sequence-regulated vinyl polymers without statistical distribution of monomer compositions and sequences.

Ferrocene-Containing Conjugated Oligomers Synthesized by Acyclic Diene Metathesis Polymerization

A series of conjugated, symmetrical, and ferrocene-containing main-chain monomers was prepared following a gentle coupling reaction. Ferrocene-containing oligomers with all-trans-configured vinylene bonds could be synthesized via acyclic diene metathesis (ADMET) polymerization. These oligomers had a larger Stokes shift (2400 to 2600 cm−1) and both exhibited stable and reversible electrochemistry. Meanwhile, the copolymerization of 1,1’-bis[1-methyl-2-(4-vinylphenyl)ethenyl]ferrocene with 2,7-divinyl-9,9-dioctylfluorene was achieved. The structurally regular copolymers proved their optical and electrochemical properties. The fluorescence intensity of the copolymer gradually enhanced with the increasing number of fluorene units. At the same time, it was also found that the color of the copolymers had a significant change from yellow-green to red.

Synthesis of new polyesters by acyclic diene metathesis polymerization of bio-based α,ω-dienes prepared from eugenol and castor oil (undecenoate)

Synthesis of high molecular weight polymers by acyclic diene metathesis (ADMET) polymerization of α,ω-diene prepared from bio-renewable eugenol and castor oil (undecenoate) has been demonstrated.