Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath

The calculating of ionic equilibria in the system «Pb(CH3COO)2 - CdCl2 - Na3C6H5O7 - ‎(NH3)2(CH2)2 - N2H4CS» allowed us to find conditions and concentration regions of PbS and CdS co-deposition. The determined conditions provided the CBD obtaining of CdxPb1−xS (0 ≤ x ≤ 0.033) substitutional solid solutions films with a cubic structure B1 (space group Fm ) with the grains preferred orientation (200). We established the evolution of the surface morphology of the synthesized films from cubic crystallites to hierarchical structure of globular aggregates by scanning electron microscopy. A quantitative analysis of diffraction patterns showed a decrease of microstrains in CdxPb1−xS films by a about factor of 3 with an increase of the cadmium chloride concentration in the reaction mixture from 0.005 to 0.14 mol/l. The excess of the cadmium content, established by EDX analysis, in the studied films as compared to its content in the solid solution is associated with the additional formation of the amorphous CdS phase up to 72 mol %.

Structural Details of BaTiO3 Nano-Powders Deduced from the Anisotropic XRD Peak Broadening

In this study, nano-BaTiO3 (BTO) powders were obtained via the solvothermal method at different reaction times and were investigated using transmission electron microscopy (TEM), X-ray diffraction (XRD) and Raman spectroscopy. The results were compared with those obtained for a larger crystallite size BTO powder (BTO-m). The sizes of the cuboid crystallites (as determined by XRD and TEM) ranged from about 18 to 24 nm, depending on the reaction time. The evolution with temperature of the structure parameters of nano-BTO was monitored by means of X-ray diffraction and Raman spectroscopy and no signs of phase transition were found up to 170 °C. Careful monitoring of the dependence of the XRD peak widths on the hkl indices showed that the effect of the cubic crystallite shape upon the XRD peak widths was buried by the effect of hidden tetragonal line splits and by anisotropic microstrain. The good correlation of the line widths with the tetragonal split amplitudes, observed especially for BTO-m above the transition temperature, indicates tetragonal deformations, as also revealed by Raman spectroscopy. The large anisotropic microstrain shown by the nano-powders, which had a maximum value in the <100> directions, was considered evidence of the phenomenon of surface relaxation of cubic crystallites edged by {100} faces. The observed behavior of the nano-BTO structures with increasing temperature may suggest a correlation between the surface relaxation and tetragonal deformation in the nano-cubes. The experimental results for both nano-BTO and mezoscale-BTO are in agreement with the core-shell model.

Nonlinearly Elastic Constitutive Relation of Anisotropic Aggregate of Cube Crystallites

Under Voigt model, Barsch and Johnson gave the formula of nonliearly elastic constitutive relations for isotropic aggregates of cubic crystallites and orthorhambic aggregates of cubic crystallies, respectively. In this paper, a nonlinear elastic constitutive relation based on Voigt model, which is more general than Barsch's and Johnson's results, is derived for the set of anisotropic cubic grains. The anisotropy of metals is described by the texture coefficient.

Simulating the diffraction line profile from nanocrystalline powders using a spherical harmonics expansion

An accurate description of the diffraction line profile from nanocrystalline powders can be obtained by a spherical harmonics expansion of the profile function. The procedure outlined in this work is found to be computationally efficient and applicable to the line profile for any crystallite shape and size. Practical examples of the diffraction pattern peak profiles resulting from cubic crystallites between 1 and 100 nm in size are shown.

On the method of ultrasonic control of mechanical stresses

A method of ultrasonic control of the mechanical stresses which takes into account the heterogeneity of the material structure and does not require unloading of the structure or using reference samples is considered. The procedure is based on echo-method of measuring time of the bulk elastic wave propagation and determination of the relative values ν31 and ν32 related to the material structure and mechanical stresses. It is shown that stresses violate the linearity of the relationship observed between the parameters in the absence of the mechanical stresses in the rolled material. This effect formed a basis for developing a method of the deviator stress determination. The purpose of the study is to demonstrate the main advantages of the developed method against the known ultrasonic techniques used for evaluation of the mechanical stresses, give theoretical grounds to the effect which allows taking into account the heterogeneity of the material structure, and also to exemplify the procedure. An analytical expression is derived using bulk elastic wave velocity in an orthotropic material composed of cubic crystallites and an assumption on the existence of simple proportional relationship between the coefficients of the orientation distribution function in rolled metal. Presented results of the mathematical modeling confirm the experimentally observed linear dependence between the parameters ν31 and ν32 in the absence of mechanical stresses. The results of evaluating residual stresses in a welded steel plate are presented as an example of the applicability of the developed procedure. Data of ultrasonic technique and data of strain gage measurements are compared. The features of the described method of stress determination are marked and the applicability limits are specified.