Universal and versatile morphology engineering via hot fluorous solvent soaking for organic bulk heterojunction

After explosive growth of efficiency in organic solar cells (OSCs), achieving ideal morphology of bulk heterojunction remains crucial and challenging for advancing OSCs into consumer market. Herein, by utilizing the amphiphobic nature and temperature-dependent miscibility of fluorous solvent, hot fluorous solvent soaking method is developed to optimize the morphology with various donor/acceptor combinations including polymer/small-molecule, all-polymer and all-small-molecule systems. By immersing blend film into hot fluorous solvent which is utilized as liquid medium with better thermal conductivity, the molecular reorganization is accelerated. Furthermore, fluorous solvent can be miscible with the residue of chloroform and chloronaphthalene above upper critical solution temperature. This mixed solvent diffuses around inside the active layer and selectively promotes molecular reorganization, leading to optimized morphology. Compared to widely-used thermal annealing, this approach processed under mild conditions achieves superior photovoltaic performance, indicating the practicality and universality for morphological optimization in OSCs as well as other optoelectronic devices.

A metal-, oxidant-, and fluorous solvent-free synthesis of α-indolylketones enabled by an umpolung strategy

We have developed the first transition metal-, oxidant-, and fluorous solvent-free α-indolization of ketones using ammonium salts and enamines.

Swelling-induced pore generation in fluorinated polynorbornene block copolymer films

Synthesis of fluorinated polynorbornene BCPs and swelling-induced pore generation of their films using fluorous solvent.

Perfluoroalkylated-Pyridine Catalyzed the Mannich-Type Reaction: An Example on Elimination the Fluorous Solvent Requirement for Fluorous Catalysis

The three-component Mannich-type reactions of different ketones with various aromatic aldehydes and aromatic amines proceeds efficiently in the presence of catalytic amount of perfluoroalkylated-pyridine in a fluorous biphasic system without fluorous solvent, which has prompted various concerns involving cost, solvent leaching, and environmental persistence. The reactions give various β-arylamino ketones in good to excellent yield. The catalyst can be recovered by simple cooling and precipitation and used again.