Radial variation in bonding performance of preservative-treated wood within Pinus elliottii trees and its relationships with wood density and adhesive penetration

Pinus elliottii wood from different radial locations within trees was used to prepare two-layer preservative-treated wood joints with alkaline copper quaternary preservative and emulsion polymer isocyanates (EPI) or resorcinol-phenol-formaldehyde (RPF) adhesives. The radial variations in shear strength and wood failure percentage were analyzed. Radial variations in wood density and average penetration depth (AP) of adhesives were investigated to establish relationships between shear strengths and characteristics of bonded joints. The shear strengths of EPI- and RPF-bonded joints showed similar increasing trends from pith to bark, and they varied in ranges of 2.92 to 8.13 MPa and 2.03 to 7.12 MPa, respectively. The wood failure percentage of EPI joints (93% to 100%) had no significant differences in all the radial locations, but that of RPF joints (60% to 100%) showed a clear decreasing trend from pith to bark. High positive linear correlations were found between the shear strengths and wood density, and Pearson’s correlation coefficients for EPI and RPF were 0.934 (p < 0.01) and 0.931 (p < 0.01), respectively. Wood density is a very important factor influencing radial variations of bonding strengths. The correlation between the AP and shear strength was not significant at the 0.05 level.

Comparison of Bonding Performance Between Plywood and Laminated Veneer Lumber Induced by High Voltage Electrostatic Field.

High voltage electrostatic field (HVEF) was applied in order to improve wood surface characteristics, bonding and mechanical properties of wood composites. Masson pine (Pinus massoniana Lamp.) plywood and laminated veneer lumber (LVL) were selected in this study. Surface characteristics were conducted by the electron spin resonance (ESR) and X-ray photoelectron spectra (XPS). Bonding interphase and mechanical properties were investigated by fluorescence microscopy and vertical density profile (VDP), bonding strength, wood failure ratio, MOE and MOR. The results indicated that more increments were obtained in free radicals, O/C ratios and C2-C4 components. This is because electrons broke more wood chemical groups and new ions occurred among wood surface under HVEF. Significantly decreased PF adhesive penetration depth (PD) and increased density at bonding interphase was achieved in HVEF treated composites. More decrease of PD and increment of density were observed in plywood than that of LVL. This was attributed to cross linked wood fibers among bonding interphase in plywood. Mechanical properties of bonding strength, wood failure ratio, MOE and MOR were significantly increased under HVEF treatment both for two composites. Higher bonding strength, MOE and MOR were obtained in plywood and their increments were as 98.53%, 33.33%, 18.55% and 12.72%.

Characterizing Star-sawn Pattern–Produced and Orthogonally Glued Specimens of Southern Pine

In this study, triangular specimens of southern pine (Pinus spp.; SP) generated by a star-sawn process were characterized according to knots and deformation. SP specimens were used to understand the differences among glue-line combinations of radial-to-radial, radial-to-tangential, and tangential-to-tangential faces bonded with phenol resorcinol formaldehyde resin. The specimens were tested for shear strength, dimensional stability, wood failure, and delamination rate in accordance with ASTM D1037 and D2559 standards. Among the star-sawn triangular samples studied, bows in tangential-face sections occurred the most. The radial-face sections of SP triangular specimens had more knots but a much lesser degree of deformation than the tangential-face sections. The tangential-to-tangential face glue-line samples showed a lower shear strength, more wood failure, and a greater tendency of delamination and dimensional change, especially when subjected to wet conditions. Confocal microscopic pictures revealed that the tangential-to-tangential glue line showed a greater tendency of deformation in the earlywood part and helped to explain the reason for poor glue-line durability and low shear strength. This article revealed that the star-sawn–process generated wood radial-face samples were more stable than others tested and are perhaps a good alternative for massive panel manufacturing.

Improvement of shear strength, wood failure percentage and wet delamination of cross-laminated timber (CLT) panels made with superheated steam treated (SHST) layers of larch wood

Cross-laminated timber (CLT) panels – consisting of several cross-wise stacked layers of glued boards – have a high dimensional stability. However, the outer surfaces of CTL are exposed to environmental humidity changes and thus to swelling and shrinking. To improve CLT’s dimensional stability further, the layers of kiln dried (KD) CLT were substituted partly (on the surfaces) and entirely with superheated steam treated (SHST) wood. The effects of SHST wood and the performance of the one-component polyurethane resin (PUR) were tested by block shear and delamination tests after water soaking. Under various conditions, the shear strength ranged from 1.3 MPa to 4.7 MPa and the wood failure percentage (WFP) from 76% to 92%. The optimal parameter were ascertained as pressing time (30–45 min), pressure (0.98 MPa) and adhesive amount (175–200 g m−2). The water soaked delamination of CLT manufactured with SHST wood was approximately 50% lower than that of CLT made of KD wood.