Quartz Microstructures from the Sambagawa Metamorphic Rocks, Southwest Japan: Indicators of Deformation Conditions during Exhumation

The Sambagawa metamorphic rocks in central Shikoku, southwest Japan consist of an inverted metamorphic sequence from the upper chlorite to oligoclase-biotite zones at the lower structural level (LSL), which is overlain by a normal metamorphic sequence consisting of the albite-biotite and garnet zones at the upper structural level (USL). These sequences form a large-scale recumbent fold called the Besshi nappe. To unravel the mechanism of recrystallization and physical conditions in quartz, and their relation to exhumation tectonics, microstructures of recrystallized quartz grains in quartz schist from the Asemi-Saruta-Dozan River traverse were analyzed. The recrystallized quartz grain size increases with increasing structural level from 40 µm in the upper chlorite zone to 160 µm in the garnet zone of the USL. Further, the mechanism of dynamic recrystallization of quartz changes from subgrain rotation to grain boundary migration with increasing structural level across the uppermost garnet zone of the LSL. From these data, the deformation temperatures in quartz schist are calculated to increase with increasing structural level within the range between 300 and 450 °C using paleopiezometers and experimental flow laws. It could be interpreted that a rapid cooling of the Besshi nappe from above is responsible for the deformation temperatures recorded in quartz schist.

Even the low-T garnet from the iconic Barrow’s zone is tetragonal

<p>Common (anhydrous) Fe-Mg-Ca-Mn garnet, the archetypal cubic mineral, has been recently discovered to be tetragonal in metapelites and metabasites from low-temperature regional metamorphic terranes (Cesare et al., 2018).</p><p>Despite the differences in bulk rock composition and pressure conditions, such low-T tetragonal garnets share common chemical features, namely high grossular (>25 mol%) and low pyrope (<7 mol%) contents. Similar compositions are documented in other contexts worldwide, both in blueschists-eclogites and in phyllites, including the metapelites from the garnet zone of the iconic Barrovian metamorphism of the Scottish highlands (Viete et al., 2011).</p><p>We have analysed a garnet crystal from a chlorite-biotite schist collected at the Barrow’s garnet zone in Glen Esk. The unit cell parameters were refined using diffraction reflections between 1.20 and 0.55 Å providing a tetragonal cell with a = 11.5731(5) Å and c = 11.5887(8) Å and volume V = 1552.15(15) Å3. Systematic absences analysis on complete intensity data collected up to 2theta = 80° indicated I41/acd space group confirming the cell parameters refinement.</p><p>Therefore, the garnet is tetragonal and not cubic, as suggested by its weak birefringence under crossed polarizers.</p><p>These results show that the tetragonal structure of common Fe-Mg-Ca-Mn garnet is verified whenever this mineral displays the Ca-rich, Mg-poor composition often observed in low-T metamorphic rocks. And support the hypothesis that the lowering of symmetry is composition-dependent.</p><p> </p><p>References</p><p>Cesare, B., et al. Garnet, the archetypal cubic mineral, grows tetragonal. Sci Rep <strong>9</strong>, 14672 (2019).</p><p>Viete, D.R., et al. The nature and origin of the Barrovian metamorphism, Scotland: Diffusion length scales in garnet and inferred thermal time scales. J. Geol. Soc. London <strong>168</strong>, 115–132 (2011).</p><p> </p>

Regional Quartz Inclusion Barometry and Comparison with Conventional Thermobarometry and Intersecting Isopleths from the Connecticut Valley Trough, Vermont and Massachusetts, USA

A comparative analysis of Raman shifts of quartz inclusions in garnet was made along two traverses across the Connecticut Valley Trough (CVT) in western New England, USA, to examine the regional trends of quartz inclusion in garnet (QuiG) Raman barometry pressure results and to compare this method with conventional thermobarometry and the method of intersecting garnet core isopleths. Overall, Raman shifts of quartz inclusions ranged from 1·2 to 3·5 cm–1 over all field areas and displayed a south to north decrease, matching the overall decrease in mapped metamorphic grade. Raman shifts of quartz inclusions typically did not show systematic variation with respect to their radial position within a garnet crystal, and indicate that garnet probably grew at nearly isothermal and isobaric pressure–temperature (P–T) conditions. The P–T conditions inferred from conventional thermobarometry were in the range of ∼500–575 °C and ∼7·4–10·3 kbar over the sample suite and are in good agreement with previous published thermobarometry throughout the CVT. These P–T results are broadly consistent with QuiG barometry and also suggest that garnet grew isothermally and isobarically at near peak P–T conditions. However, P–T conditions and P–T paths inferred using either garnet core thermobarometry or garnet core intersecting isopleths yield results that are internally inconsistent and generally disagree with the pressure results from QuiG barometry. Garnet core isopleth intersections consistently plotted between the nominal garnet-in curve on mineral assemblage diagrams and the P–T conditions constrained by QuiG isomekes for the majority of the sample suite. Additionally, most samples’ P–T results from QuiG barometry and rim thermobarometry show marked disagreement from those derived from garnet core thermobarometry, compared with the minority that showed agreement within uncertainty. Pressures calculated from QuiG barometry ranged from 8·5 to 9·5 kbar along the traverses in western Massachusetts (MA) and central Vermont (VT) and from 6·5 to 7·5 kbar in northern VT indicating an increase in peak burial of 3–6 km from north to south. Along the western end of the central VT traverse, there are differences in measured Raman shifts and inferred peak pressures of up to 1 kbar across the Richardson Memorial Contact (RMC), indicating a possible fault contact with minor post-peak metamorphic shortening of up to ∼3 km. In contrast, along an east–west traverse in the vicinity of the Goshen Dome, MA, there was little observed variation in Raman shifts across the contact. By contrast, QuiG barometry clearly indicates significant discontinuities in peak pressure east of the Strafford Dome in central VT. This supports the interpretation that post-peak metamorphic shortening was necessary to juxtapose upper staurolite–kyanite zone rocks next to lower garnet zone pelites. Overall, it is concluded that garnet core thermobarometry and garnet core isopleths may provide unreliable results for the P–T conditions of garnet nucleation and inferred P–T paths during garnet growth unless independently verified. The consistency of QuiG results with rim thermobarometry indicates that peak metamorphic conditions previously reported for the CVT using garnet rim thermobarometry are robust and that variation in QuiG barometry results is a valuable tool to analyze structural features within a metamorphic terrane.

Investigation of juxtaposed high- and low-pressure metamorphic field gradients rocks and its tectonic implications, a case study of Turvo-Cajati Formation, Ribeira Belt, Brazil

<p>The Turvo-Cajati Formation (TCF) is a metasedimentary unit composing the Curitiba Terrane, a major segment of the southern Ribeira Belt, SE Brazil. It is composed of rocks of greenschist (Low-TCF), amphibolite (Medium-TCF) and granulite (High-TCF) facies conditions. Previous studies in High-TCF indicates that the unit underwent extensive partial melting under high-pressure conditions (670-810 °C and 9.5-12 kbar), within the kyanite stability field. New data on the metamorphic zoning within Low and Medium-TCF were collected using petrography and thermodynamic modeling in the MnNCKFMASHTO system. Four metamorphic zones were recognized for Low-TCF and Medium-TCF: biotite, garnet, staurolite and sillimanite zones where sillimanite zone prevails. The pressure regime is estimated to be below 8 kbar, as staurolite breaks down straight to sillimanite. Thermodynamic modeling yielded metamorphic peak conditions of ~530-560 °C ,~6-7 kbar (garnet zone) and ~660-690 °C ,~6-7 kbar (sillimanite zone). The metamorphic field gradient is flat and of low to medium pressure, below the typical barrovian-type baric regime. It is inferred that Low and Medium-TCF were metamorphosed in a tectonic setting different from the High-TCF. Probability density plots(pdp) from detrital zircon indicate late-Cryogenian-Ediacaran arc-related and Rhyacian sources for all TCF sub-units, where High-TCF presents forearc depositional setting and Low-Medium-TCF back arc depositional setting. This scenario suggests that the TCF is made up of a collisional juxtaposition of an accretionary wedge (High-TCF) and a back-arc basin (Medium-TCF and Low-TCF) on the border of a microplate that includes a Rhyacian basement microcontinent (Atuba Complex). Available petrological and geochronological data suggest that the TCF comprises a paired low-P and high-P belt, associated with a major Ediacaran suture zone in the southern Ribeira Belt. The high metamorphic gradient recorded in the Medium-TCF and Low-TCF was related to asthenospheric upwelling in the back-arc region, which also produced extensive partial melting in the Atuba Complex basement. Metamorphic ages where previously obtained in High-TCF with ages around 589 ± 12 Ma and 584 ± 4 Ma. Petrochronology will be used to obtain the age of metamorphic events, using monazite and apatite grains from Low and Medium-TCF and compare them to available High-TCF data to understand and adjust the proposed model.</p>

Geology and mineral resources of Khudi-Bahundanda area of west-central Nepal along Marshyangdi Valley

Geological study was carried out along the Khudi-Bahundanda area of the Marshyangdi Valley in the west central Nepal. The area lies partly in the Main Central Thrust (MCT) zone and partly in the Higher Himalayan Crystalline Zone. The aim of the study was to prepare a detail geological map and cross section in the scale of 1:25,000 to work out on stratigraphy, metamorphism and mineral resource potential of the area. The rocks of the Higher Himalaya have been mapped under a single unit as Formation I. This unit consists of kyanite-garnet para-gneiss. The lithological units of the MCT zone are mapped into three units as the Benighat Slate, the Malekhu Formation and the Robang Formation from the bottom to the top, respectively. The Benighat Slate consists of dark grey to black schist with some carbonate beds as members. The Malekhu Formation consists of creamy white siliceous dolomite marble with parting of schist. The Robang Formation comprises of light grey psammitic schist with garnet and white micaceous quartzite in various proportion. Many secondary structures are observed in the study area, but primary structures are missing due to extreme metamorphism. The large-scale structures are the MCT, which separates the Lesser Himalayan rocks to the south from the Higher Himalaya to the north, and the Bahundanda Thrust (BT). Numerous outcrop-scale structures like meso-scale folds, quartz veins, boudinage and ptygmatic folds are abundant. Folds in the MCT zone are mostly E-W trending, and rocks have experienced multiple metamorphism and dynamic crystallization of minerals. The Lesser Himalayan rocks resemble the garnet zone while the Higher Himalayan rocks resemble to the kyanite grade of metamorphism. As in the other sections of the Himalaya, the present section also clearly shows the inverted metamorphism in the MCT zone. The MCT zone is considered as the potential site for precious and semi-precious stones, of which the most potential ones are the garnet and kyanite.

Geology and micro-structure analysis of the MCT zone along Khudi- Bahundanda area of Lamjung District, west-central Nepal

Geological mapping was carried out along the Marsyangdi Valley in the Khudi-Bahundanda area of west-central Nepal covering the Main Central Thrust (MCT) zone. The main objectives of the study were to draw a clear picture of lithology, geological structures and micro-tectonics in the rocks. A detail survey on stratigraphy and correlation with central Nepal reveals geological rock units such as the Benighat Slate, the Malekhu Formation and the Robang Formation of the Lesser Himalaya and the Formation I of the Higher Himalaya. Both regional and small-scale geological structures have been studied. The MCT zone has been mapped as a major regional structure in the region. The Bahundanda Thrust (BT), which has brought the older Malekhu Formation over the younger Robang Formation, is an another significant structure mapped. The BT is marked on the basis of fault breccia, slickensides as well as large deposits of debris mass at the fault zone. The study area has undergone poly-metamorphism and dynamic crystallization of minerals. The Lesser Himalayan rocks resemble the garnet zone while the Higher Himalaya rocks resemble to the kyanite grade of metamorphism. The present section clearly shows the inverted metamorphism in the MCT zone as in the other sections of the Himalaya. Microscopic features like ribbon-quartz, polygonization of quartz crystals, grain boundary reduction, mica-fish and rotated garnet grains indicates the ductile shearing in the MCT zone suggesting the dynamic recrystallization during thrust propagation. Numerous outcrop-scale structures like meso-scalefolds, quartz veins, boudinage and ptygmatic folds are abundant folds in the MCT zone and these are mostly E-W trending.

Metamorphism of Jhyallaphay-Barpak-Bhachchek area of Gorkha District, Lesser Himalaya and Higher Himalaya, Central Nepal

The study is focused on geological mapping, petrography and metamorphism of Jhyallaphat–Barpak–Bhachchek area, a part of Gorkha District, Central Nepal using a base of 1:25000 scale covering an area of 139.80 sq. km. The rocks of the study area can be broadly divided into two tectonic zones; the Lesser Himalaya consisting of fie lithological units, and the Higher Himalaya consisting of Formation I of the Tibetan Slab. Three metamorphic zones can be distinguished in the study area; biotite zone, garnet zone and kyanite zone. The biotite zone of the mineral assemblage in pelitic rocks consists of biotite+muscovite+chlorite+quartz, in psammitic rocks comprises of biotite+muscovite+chlorite+feldspar+quartz and in carbonate rocks comprises of biotite+muscovite+calcite/dolomite+feldspar+quartz, respectively. These mineral assemblages show that the area belongs to the greenschist facies. The mineral assemblage of the garnet zone in pelitic rocks constitutes garnet+biotite+muscovite+chlorite+quartz, and in psammitic rocks constitutes of garnet+biotite+muscovite+feldspar+quartz. The minerals assemblages found within the biotite and garnet zones represent the well-known inverted metamorphism in the Lesser Himalaya. Mineral assemblage of the kyanite zones constitutes of kyanite+garnet+biotite+muscovite+feldspar+quartz. The mineral assemblages of the both garnet and kyanite zones show that the area belongs to the epidote amphibolite facies. The bedding and foliation planes are almost parallel, showing that isograds also cut across the foliation. Therefore, the main metamorphic event should have followed development of foliation in the area. The rocks of the area show at least two metamorphic events: syntectonic prograde and post-tectonic retrograde. Syn-tectonic prograde metamorphism (M1), which has grown during a single phase of deformation and most frequently encountered garnet prophyroblast. Metamorphic deformation is represented by the presence of metamorphic foliation, stretching lineation, and S-C fabric. Post-tectonic retrograde metamorphism (M2), which is followed by retrograde mineral formation changing its P-T condition from high to low grade minerals, such as the formation of the biotite and chlorite minerals around the rims of the garnet porphyroblasts.

Barrovian metamorphism in the central Kootenay Arc, British Columbia: petrology and isograd geometry

A narrow, partly fault-bounded belt of Barrovian amphibolite facies rocks transects the central Kootenay Arc in the internal zone of the southeastern Canadian Cordillera. The following zones of increasing metamorphic grade are recognised in metapelites: chlorite/biotite, garnet, staurolite, kyanite, sillimanite, and sillimanite + K-feldspar. The garnet and higher-grade zones outline two joined domains: a N- to NNE-trending curved belt, >100 km long and 5–20 km wide, that is approximately parallel to the strike of stratigraphic units; and a SSE-trending belt, >70 km long and 10–15 km wide, that transects strike. Isograds in the N–NNE-trending belt outline an elongate bull’s-eye pattern with highest-grade rocks in the centre, coincident with the position of a structural culmination. Isogradic surfaces have an elongate domal form centred around this culmination. Rocks in the kyanite and sillimanite zones were metamorphosed at ~25 km (∼7 kbar (1 kbar = 100 MPa)) and >650 °C during Early Cretaceous crustal thickening; rocks in the garnet zone experienced peak temperature conditions (∼500 °C) at lower pressure, suggesting the piezothermic array for the belt has a positive slope. The western flank of the N- to NNE-trending belt is cut by the west-dipping Gallagher fault zone (GFZ), whereas the eastern boundary of the SSE-trending fork is marked by the Purcell Trench fault (PTF). These Palaeocene–Eocene normal faults truncate Early Cretaceous isogradic surfaces and juxtapose regions with contrasting structural and metamorphic histories. Low-grade rocks in the hanging wall of the GFZ underwent peak regional metamorphism during the Early–Middle Jurassic, prior to intrusion of the 159–173 Ma Nelson batholith at a depth of ∼12–14 km. With the exception of a zone along the southern “tail” of the Nelson batholith, rocks in the hanging wall of the GFZ were not affected by Cretaceous metamorphism or penetrative deformation. Rocks in the amphibolite-facies belt yield Palaeocene–Eocene K–Ar and 40Ar/39Ar mica cooling ages, whereas K–Ar biotite ages in the hanging wall of the GFZ record Jurassic – Early Cretaceous cooling, and those in the hanging wall of the PTF are mid-Cretaceous. Although the GFZ and PTF accommodated differential exhumation during the Palaeogene, significant relief on isogradic surfaces was established prior to normal faulting, during Early Cretaceous metamorphism and deformation.