Extractive stripping voltammetry at a glassy carbon paste electrode for analysis of cow's milk and cream

In this paper, a procedure based on extractive accumulation of milk fat globules (MFGs) into a pasting liquid (lipophilic binder) of glassy carbon paste electrode (GCPE) with subsequent electrochemical detection by square-wave voltammetry (SWV) in 0.1 mol L-1 Britton-Robinson buffer of pH 4.0 has been tested to find out whether it can be utilized as a simple screening analytical method for cow's milk and cream nutrition control. Since there is assumption that the necessary alkaline hydrolysis of cow's milk and subsequent extraction of lipophilic vitamins into an organic solvent could be avoided, several GCPEs differing in type (atactic polypropylene, paraffin oil, paraffin wax, silicone oil, and vaseline) and content (5, 10, 15, 20, and 25%; w/w) of pasting liquid used were tested as part of complex optimization. The obtained results show that MFGs contain predominantly vitamin A (carotenoids and retinoids), especially all-trans-retinol, which could serve as significant marker of the fat content. However, their individual forms were not possible to distinguish due to the considerable anodic peak broadening (overlapping).

Fabrication of a new biosensor based on a Sn doped ceria nanoparticle modified glassy carbon paste electrode for the selective determination of the anticancer drug dacarbazine in pharmaceuticals

A new tin doped ceria nanoparticle modified glassy carbon paste electrode (Sn–CeO2NPs/GCPE) was fabricated for the determination of the anticancer drug dacarbazine (DTIC).

Electrochemical sensor for individual and simultaneous determination of guanine and adenine in biological fluids and in DNA based on a nano-In–ceria modified glassy carbon paste electrode

A novel, simple and sensitive electrochemical method for individual and simultaneous determination of guanine and adenine was developed using an In doped ceria nanoparticle modified glassy carbon paste electrode (In–CeO2/GCPE).