Optical Property of Contained Fullerene Polymers

The presented study in the field of optical area is about receiving polymer new materials in the way of doping a small amount of fullerene С60. Under the method of preparing samples it is revealed characteristics of an interaction between polymer components and doping materials. Significant absorption of ultraviolet radiation by studied samples at the certain concentration of the doping material is presented in the result of the optical study. It is shown that metal-fullerene nanostructures which are on the polymer surface call surface resonance of plasmon absorption.

Fullerene Polymers: A Brief Review

This paper reviews the ways in which C60 and other fullerene molecules can be incorporated into polymeric structures. Firstly, polymers in which the fullerenes are incorporated into the structure by covalent or noncovalent bonding are discussed. These include “pearl necklace” structures, “charm bracelet” structures, organometallic polymers, crosslinked polymers, end-capped polymers, star-shaped polymers and supramolecular polymers. Secondly, all-carbon polymers, which are produced by fusing fullerenes together, are covered. The synthesis and properties of each class of fullerene polymer are outlined and the prospects for commercial applications considered.

The directional character of the piperazine double addition product, e{N(CH2CH2)2N}2C60, as a building block for forming crystalline fullerene polymers

The piperazine double addition product, e{N(CH2CH2)2N}2C60, has its donor atoms positioned to bind Lewis acids in two orthogonal directions. It has been used to construct crystalline, 1-d and 2-d polymers through reactions with diiodine and the rhodium(ii) acetate dimer.

Theoretical investigation of interactions between palladium and fullerene in polymer

Applying density functional theory (DFT) calculations, we predict the structural and electronic properties of different types of palladium–fullerene polymers.