Wire-like Pt on mesoporous Ti0.7W0.3O2 Nanomaterial with Compelling Electro-Activity for Effective Alcohol Electro-Oxidation

Finding out robust active and sustainable catalyst towards alcohol electro-oxidation reaction is major challenges for large-scale commercialization of direct alcohol fuel cells. Herein, a robust Pt nanowires (NWs)/Ti0.7W0.3O2 electrocatalyst, as the coherency of using non-carbon catalyst support and controlling the morphology and structure of the Pt nanocatalyst, was fabricated via an effortless chemical reduction reaction approach at room temperature without using surfactant/stabilizers or template to assemble an anodic electrocatalyst towards methanol electro-oxidation reaction (MOR) and ethanol electro-oxidation reaction (EOR). These observational results demonstrated that the Pt NWs/Ti0.7W0.3O2 electrocatalyst is an intriguing anodic electrocatalyst, which can alter the state-of-the-art Pt NPs/C catalyst. Compared with the conventional Pt NPs/C electrocatalyst, the Pt NWs/Ti0.7W0.3O2 electrocatalyst exhibited the lower onset potential (~0.1 V for MOR and ~0.2 for EOR), higher mass activity (~355.29 mA/mgPt for MOR and ~325.01 mA/mgPt for EOR) and much greater durability. The outperformance of the Pt NWs/Ti0.7W0.3O2 electrocatalyst is ascribable to the merits of the anisotropic one-dimensional Pt nanostructure and the mesoporous Ti0.7W0.3O2 support along with the synergistic effects between the Ti0.7W0.3O2 support and the Pt nanocatalyst. Furthermore, this approach may provide a promising catalytic platform for fuel cell technology and a variety of applications.

Carbon nitride simultaneously boosted a PtRu electrocatalyst's stability and electrocatalytic activity toward concentrated methanol

Ruthenium dissolution is an inevitable issue for an anodic electrocatalyst in direct methanol fuel cells (DMFCs).

Stable CO anti-poisoning and high durability of a Pt electrocatalyst supported on carbon nanotubes

Stable CO anti-poisoning and high durability of an anodic electrocatalyst are very important for direct methanol fuel cells (DMFCs).

Simultaneous enhancements in stability and CO tolerance of Pt electrocatalyst by double poly(vinyl pyrrolidone) coatings

CO poisoning and low durability of the anodic electrocatalyst is one of the obstacles restricting the practical application of direct methanol fuel cells (DMFCs).