charged radical
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scholarly journals Unexpected electrochemical behavior of an anolyte redoxmer in flow battery electrolytes: solvating cations help to fight against the thermodynamic–kinetic dilemma

2020 ◽  
Vol 8 (27) ◽  
pp. 13470-13479 ◽  
Author(s):  
Yuyue Zhao ◽  
Zhou Yu ◽  
Lily A. Robertson ◽  
Jingjing Zhang ◽  
Zhangxing Shi ◽  
...  
Keyword(s):  
Redox Potential ◽  
Electrochemical Behavior ◽  
Radical Anion ◽  
Flow Battery ◽  
Charged Radical

Solvating cations help to lift the thermodynamic-kinetic constrain of an anolyte redoxmer by achieving a synergetic improvement of two conflicting properties: a lower redox potential AND a higher stability of the charged radical anion.

Reactions of the Charged Radical (CH3)2S+-CH2.bul. with Cyclic Alkenes

1994 ◽  
Vol 116 (23) ◽  
pp. 10767-10772 ◽  
Author(s):  
Leonard J. Chyall ◽  
Michelle H. C. Byrd ◽  
H. I. Kenttamaa
Keyword(s):  
Charged Radical ◽  
Cyclic Alkenes
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