Gold mobilization during metamorphic devolatilization of Archean and Paleoproterozoic metavolcanic rocks

Volcanic rocks in Archean and Paleoproterozoic greenstone belts are abundant and have been suggested as a potential Au source for orogenic Au deposits. The behavior of Au during metamorphism of these rocks is, however, poorly known. We present ultra-low-detection-limit Au analyses from a suite of variably metamorphosed rocks from the Archean La Grande subprovince, Canada, and the Paleoproterozoic Central Lapland greenstone belt, Finland. Both areas are well endowed in Au and have great potential for discovery of new orogenic Au deposits. The metavolcanic rocks in these belts are grouped into tholeiite and calc-alkaline magmatic series, for which the protolith Au contents are calculated using Au versus Zr/Y power-law regressions from greenschist facies samples. In the tholeiitic rocks, Au is compatible during magmatic processes and decreases with differentiation, whereas in the calc-alkaline rocks, Au is incompatible and increases with differentiation. Mass-variation calculations show that as much as 77% and 59% of the initial Au content is lost during progressive metamorphism to upper amphibolite facies conditions (>550 °C) in La Grande and Central Lapland respectively. This study highlights, first, that metavolcanic rocks release Au during metamorphism in Archean and Paleoproterozoic greenstone belts and are thus a good potential source rocks for orogenic Au deposits; second, that the Au fertility of the metavolcanic rocks is controlled by their mantle source and magmatic evolution; and third, that the metamorphic devolatilization model can be applied to Archean and Paleoproterozoic orogenic Au deposits.

The Mustajärvi orogenic gold occurrence, Central Lapland Greenstone Belt, Finland: a telluride-dominant mineral system

The Mustajärvi gold occurrence lies in the southern part of the Paleoproterozoic Central Lapland Greenstone Belt, in proximity to the first-order transcrustal Venejoki thrust fault system. The gold occurrence is structurally controlled by the second-order Mustajärvi shear zone, which is located at the contact between siliciclastic metasedimentary and mafic to ultramafic metavolcanic rocks. The main mineralization comprises a set of parallel veins and sulfidized rocks that are slightly oblique to the shear zone and are hosted by third-order structures likely representing Riedel R-type shears. The gold-mineralized rock at Mustajärvi is associated with pyrite that is present in 0.15- to 1-m-wide quartz-pyrite-tourmaline veins and in zones of massive pyrite in the host rocks with thicknesses ranging from 1.15 to 2 m. In unweathered rock, hypogene gold is hosted by Au- and Au-Bi-telluride micro-inclusions in pyrite, whereas strong weathering at near surface levels has caused a remobilization of gold, resulting in free gold deposited mainly in the cracks of oxidized pyrite. The geochemistry of both mineralization styles is typical of orogenic gold systems with strong enrichments comprising Au, B, Bi, CO2, Te, and Se; and less consistent anomalous amounts of Ag, As, Sb, and W. Unusual for orogenic gold deposits is the strong enrichment of Ni and Co, which leads to the classification of Mustajärvi as orogenic gold occurrence with atypical metal association.

A succession of near-orthogonal horizontal tectonic shortenings in the Paleoproterozoic Central Lapland Greenstone Belt of Fennoscandia: constraints from the world-class Suurikuusikko gold deposit

The relative and absolute timing of orogenic gold deposits in complex structural settings are active and challenging topics of research, especially in Precambrian greenstone belts. The Suurikuusikko gold deposit in Central Lapland Greenstone Belt is currently the largest primary gold producing deposit in Europe, located on a slight bend of the strike-slip Kiistala shear zone (KiSZ). Gold is refractory and locked inside arsenopyrite and pyrite. In this study, different structural features were investigated along the KiSZ from the recently stripped Etelä pit, which is the southern extension of the Suurikuusikko ore body. Our data source ranges from aeromagnetic to high-resolution aerial images, X-ray computed tomography scans of selected rock samples and regional geological and geophysical datasets. The KiSZ has recorded five discrete deformation phases, spanning between ca. 1.92 and 1.76 Ga. The refractory gold at the Suurikuusikko deposit formed during E-W contraction related to the D1 thrusting phase. This was followed by a N-S shortening event (D2), where most of the strain was taken up by the northern and southern thrusts. Tectonic vectors then switched from N-S to NE-SW and, as a result, dextral strike-slip regime (D3) commenced along the KiSZ. This event exsolved invisible gold from the sulfides and remobilized it along with fractures. A near-orthogonal switch of the regional stress regime from NE-SW to NW-SE flipped the kinematics of the KiSZ from dextral to sinistral (D4). The last deformation phase (D5) produced widespread veining under E-W contraction and secured gold mineralization at the Iso-Kuotko gold deposit within the KiSZ.