outer helmholtz plane
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2016 ◽  
Author(s):  
Silvia E. Braslavsky ◽  
André M. Braun ◽  
Alberto E. Cassano ◽  
Alexei V. Emeline ◽  
Marta I. Litter ◽  
...  

ChemPhysChem ◽  
2011 ◽  
Vol 12 (8) ◽  
pp. 1430-1434 ◽  
Author(s):  
Masashi Nakamura ◽  
Narumasa Sato ◽  
Nagahiro Hoshi ◽  
Osami Sakata

1984 ◽  
Vol 62 (8) ◽  
pp. 1497-1501 ◽  
Author(s):  
W. Ronald Fawcett ◽  
Kveta Markušová

The kinetics of electroreduction of the aquopentamminochromium(III) cation have been studied at a Hg electrode in acidified aqueous solutions of NaI+ NaClO4 with an ionic strength of 0.25 M. The rate of reaction increased with increase in iodide concentration due to the accelerating effect of this anion when it is adsorbed on the electrode. Analysis of the double layer effect indicates that the rate acceleration is greater than that predicted by the Frumkin theory chiefly because the reaction site is closer to the electrode than to the outer Helmholtz plane.


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