outer helmholtz plane
Recently Published Documents

TOTAL DOCUMENTS

14
(FIVE YEARS 0)

H-INDEX

5
(FIVE YEARS 0)
Latest Documents Most Cited Documents Contributed Authors Related Sources Related Keywords

Outer Helmholtz Plane (OHP)

2016 ◽  
Author(s):  
Silvia E. Braslavsky ◽  
André M. Braun ◽  
Alberto E. Cassano ◽  
Alexei V. Emeline ◽  
Marta I. Litter ◽  
...  
Keyword(s):  
Outer Helmholtz Plane

Outer Helmholtz Plane of the Electrical Double Layer Formed at the Solid Electrode-Liquid Interface

ChemPhysChem ◽  
2011 ◽  
Vol 12 (8) ◽  
pp. 1430-1434 ◽  
Author(s):  
Masashi Nakamura ◽  
Narumasa Sato ◽  
Nagahiro Hoshi ◽  
Osami Sakata
Keyword(s):  
Double Layer ◽  
Electrical Double Layer ◽  
Liquid Interface ◽  
Solid Electrode ◽  
Outer Helmholtz Plane

Discreteness-of-charge effects in electrode kinetics. III. The electroreduction of aquopentamminochromium(III) cation in the presence of specifically adsorbed iodide anions

1984 ◽  
Vol 62 (8) ◽  
pp. 1497-1501 ◽  
Author(s):  
W. Ronald Fawcett ◽  
Kveta Markušová
Keyword(s):  
Ionic Strength ◽  
Electrode Kinetics ◽  
Reaction Site ◽  
Charge Effects ◽  
Iodide Concentration ◽  
Rate Acceleration ◽  
Rate Of Reaction ◽  
Layer Effect ◽  
Kinetics Of ◽  
Outer Helmholtz Plane

The kinetics of electroreduction of the aquopentamminochromium(III) cation have been studied at a Hg electrode in acidified aqueous solutions of NaI+ NaClO4 with an ionic strength of 0.25 M. The rate of reaction increased with increase in iodide concentration due to the accelerating effect of this anion when it is adsorbed on the electrode. Analysis of the double layer effect indicates that the rate acceleration is greater than that predicted by the Frumkin theory chiefly because the reaction site is closer to the electrode than to the outer Helmholtz plane.

Load More ...
Sign in / Sign up

Export Citation Format

Share Document