The limits of near field immersion microwave microscopy evaluated by imaging bilayer graphene moiré patterns

Near field scanning Microwave Impedance Microscopy can resolve structures as small as 1 nm using radiation with wavelengths of 0.1 m. Combining liquid immersion microscopy concepts with exquisite force control exerted on nanoscale water menisci, concentration of electromagnetic fields in nanometer-size regions was achieved. As a test material we use twisted bilayer graphene, because it provides a sample where the modulation of the moiré superstructure pattern can be systematically tuned from Ångstroms up to tens of nanometers. Here we demonstrate that a probe-to-pattern resolution of 108 can be obtained by analyzing and adjusting the tip-sample distance influence on the dynamics of water meniscus formation and stability.

Phase-dependent Friction of Nanoconfined Water Meniscus

A water meniscus naturally forms under ambient conditions at the point of contact between a nanoscale tip and an atomically flat substrate. Here we study the effect of the phase...

Effective Thermal Conductivity of a Wet Porous Medium—Presence of Hysteresis When Modeling the Spatial Water Distribution for the Pendular Regime

This paper deals with the heat transfer between two spherical grains separated by a small gap; dry air is located around the grains and a liquid water meniscus is supposed to be present between them. This problem can be seen as a microscale cell of an assembly of solid grains, for which we are looking for the effective thermal conductivity. For a fixed contact angle and according to the volume of the liquid meniscus, two different shapes are possible for the meniscus, giving a “contacting” state (when the liquid makes a true bridge between the two spheres) and a “noncontacting” one (when the liquid is split in two different drops, separated by a thin air layer); the transition between these two states occurs at different times when increasing or decreasing the liquid volume, thus leading to a hysteresis behavior when computing the thermal flux across the domain.

Transmission X-ray scattering as a probe for complex liquid-surface structures

The need for functional materials calls for increasing complexity in self-assembly systems. As a result, the ability to probe both local structure and heterogeneities, such as phase-coexistence and domain morphologies, has become increasingly important to controlling self-assembly processes, including those at liquid surfaces. The traditional X-ray scattering methods for liquid surfaces, such as specular reflectivity and grazing-incidence diffraction, are not well suited to spatially resolving lateral heterogeneities due to large illuminated footprint. A possible alternative approach is to use scanning transmission X-ray scattering to simultaneously probe local intermolecular structures and heterogeneous domain morphologies on liquid surfaces. To test the feasibility of this approach, transmission small- and wide-angle X-ray scattering (TSAXS/TWAXS) studies of Langmuir films formed on water meniscus against a vertically immersed hydrophilic Si substrate were recently carried out. First-order diffraction rings were observed in TSAXS patterns from a monolayer of hexagonally packed gold nanoparticles and in TWAXS patterns from a monolayer of fluorinated fatty acids, both as a Langmuir monolayer on water meniscus and as a Langmuir–Blodgett monolayer on the substrate. The patterns taken at multiple spots have been analyzed to extract the shape of the meniscus surface and the ordered-monolayer coverage as a function of spot position. These results, together with continual improvement in the brightness and spot size of X-ray beams available at synchrotron facilities, support the possibility of using scanning-probe TSAXS/TWAXS to characterize heterogeneous structures at liquid surfaces.