Highly Enhancing Electrical, Thermal, and Mechanical Properties of Polypropylene/Graphite Intercalation Compound Composites by In Situ Expansion during Melt Mixing

Polypropylene/graphite intercalation compound (PP/GIC) composites are prepared via melt mixing at three different temperatures (180, 200, and 220 °C). The dispersion of GICs in the composites is clearly improved due to the increased interlamellar spacing caused by in situ expansion of GICs at higher temperatures, which facilitates the intercalation of PP molecular chains into the GIC galleries. As a result, the PP/GIC composite with 10 wt% GICs prepared at 220 °C (PG220) presents a dielectric constant of about 1.3 × 108 at 103 Hz, which is about six orders higher than that of the composite prepared at 180 °C (PG180). Moreover, the thermal conductivity of the PG220 sample (0.63 Wm−1K−1) is 61.5% higher than that of the PG180 sample. The well-dispersed GICs accelerates the crystallization of PP by increasing the nucleation point and enhances the thermal stability of the composites. The PG220 sample shows a Young’s modulus that is about 21.2% higher than that of the PG180 samples. The results provide an efficient approach for fabricating polymer/GIC composites without complex exfoliation and dispersion processes.

Slip distribution of the 2020 Elazığ Earthquake (Mw 6.75) and its influence on earthquake hazard in the Eastern Anatolia

SUMMARY We analysed coseismic surface displacements of the 2020 January 24 Elazığ (M 6.75) Earthquake using GPS (Global Positioning System) measurements to investigate the associated fault slip distribution and static stress change. Our geodetic analysis of 13 GPS sites surrounding the epicentre included data from four additional sites. We accurately located the nucleation point of the main shock at 38.310° N, 39.081° E (±1.4 km) and at a depth of 5.2 ± 1.2 km. Both seismograph and GPS-derived fault plane solutions confirmed that it has a nearly pure sinistral mechanism with a negligible obliquity. The main shock generated 29.2 cm average sinistral slip along an approximately 70 km long and 20 km wide section of the East Anatolian Fault. Based on its rupture size and average slip, its magnitude was found to be Mw 6.75. An average of 6.6 bars of stress drop occurred on the rupture plane. The rupture occurred bilaterally failing two separate segments both to the northeast and to the southwest of the nucleation point. Average sinistral slips were 14.6 and 47.4 cm along the southwestern and northeastern segments, respectively. Sinistral slip reached up to 53.1 cm along the southwestern segment and 110.5 cm along the northeastern segment. During the generation process of the 2020 earthquake, 78 per cent of the slip deficit had been released aseismically since 1875. Increasing Coulomb stress by an average of 2.5 bars, it substantially increased earthquake hazard on the 1874 (M 7.1) rupture zone, which might have already accumulated 1.51 m slip deficit on its fully locked patches. Furthermore, increasing Coulomb stress by an average of 0.5 bars, it raised earthquake hazard on the 1893 (M 7.1) rupture zone, which might have already stored 1.01 m slip deficit along the fully locked patches.

Understanding the dynamics of scaffold-mediated signaling

Many signaling networks involve scaffold proteins that bind multiple kinases in kinase cascades. While scaffolds play a fundamental role in regulating signaling, few hypotheses regarding their function have been rigorously examined. Here, we used dynamical models of scaffold signaling to investigate the impact scaffolds have on network behavior. We considered two paradigms of scaffold assembly: as either the nucleation point for assembly of discrete multi-subunit proteins (the machine paradigm) or a platform upon which kinases independently associate (the ensemble paradigm). We found that several well-accepted hypotheses regarding the role of scaffolds in regulating signal response either do not hold or depend critically on the assembly paradigm employed. In addition to providing novel insights into the function of scaffold proteins, our work suggests experiments that could distinguish between assembly paradigms. Our findings should also inform attempts to target scaffold proteins for therapeutic intervention and the design of scaffolds for synthetic biology.

Symmetry Breaking by Surface Blocking: Synthesis of Bimorphic Silver Nanoparticles, Nanoscale Fishes and Apples

A powerful approach to augment the diversity of well-defined metal nanoparticle (MNP) morphologies, essential for MNP advanced applications, is symmetry breaking combined with seeded growth. Utilizing this approach enabled the formation of bimorphic silver nanoparticles (bi-AgNPs) consisting of two shapes linked by one regrowth point. Bi-AgNPs were formed by using an adsorbing polymer, poly(acrylic acid), PAA, to block the surface of a decahedral AgNP seed and restricting growth of new silver to a single nucleation point. First, we have realized 2-D growth of platelets attached to decahedra producing nanoscale shapes reminiscent of apples, fishes, mushrooms and kites. 1-D bimorphic growth of rods (with chloride) and 3-D bimorphic growth of cubes and bipyramids (with bromide) were achieved by using halides to induce preferential (100) stabilization over (111) of platelets. Furthermore, the universality of the formation of bimorphic nanoparticles was demonstrated by using different seeds. Bi-AgNPs exhibit strong SERS enhancement due to regular cavities at the necks. Overall, the reported approach to symmetry breaking and bimorphic nanoparticle growth offers a powerful methodology for nanoscale shape design.

Control of the rate of evaporation in protein crystallization by the `microbatch under oil' method

Microbatch crystallization under oil is a powerful procedure for obtaining protein crystals. Using this method, aqueous protein solutions are dispensed under liquid oil, and water evaporates through the layer of oil, with a concomitant increase in the concentrations of both protein and precipitant until the nucleation point is reached. A technique is presented for regulating the rate of water evaporation, which permits fine tuning of the crystallization conditions as well as preventing complete desiccation of the drops in the microbatch crystallization trays.