Campanian Calciturbidites from Northeast Iraq, Kurdistan Region: Insight into Paleogeography and Source Areas of the Shiranish Formation

Calciturbidites are similar to siliciclastic turbidites in structure, texture, basin physiography and processes of deposition; nevertheless, their clasts (grains) are carbonate minerals. Turbidity currents transport carbonate grains from carbonate source areas and coastal areas to the deep basins after passing the shelf (peri-platform). These currents are triggered by short-lived catastrophic events, such as tsunamis, earthquakes, marine slides, and typhoons. The Late Cretaceous Zagros Foreland and Hinterland in NE-Iraq (Kurdistan Region) was an active source for the shedding of voluminous sediments to the deep basin of Zagros Foreland Basin. During late Campanian, Shiranish Formation was deposited in the foreland basin; it occurs in the most famous oil fields in the Middle East and represents hemplagite facies (much diluted turbidite facies). Previous studies have not broached the origins of Shiranish Formation, neither in detail or briefly. Conversely, the present study focused on linking the calciturbidite system to the origin of the deposition of the Shiranish Formation via derivation from main carbonate source areas. Along long distance, the sediments crossed the marginal slope, scoring submarine channels and depositing coarse detrital carbonates before reaching the basin plain. On the plain, mostly the fine fractions have settled down and mixed with pelagic sediment. The calciturbidite evidence could be tracked for more than 40 km in the studied area from the slope and outer shelf (present Thrust Zone) to the basin plain (High Folded zone). In several places, channelized detrital laminated limestones are found inside Shiranish Formation and in the most proximal area near Qaladiza town. Bouma sequences are clearly observable with erosional base and A, B, and C divisions. These calciturbidites are keys for picturing Campanian paleogeography and nature of the source area which was consisted of limestone.

Geochemical study of the early cretaceous Fahliyan oil reservoir in the northwest Persian Gulf

Three crude oil samples from the Fahliyan Formation in ‘KG’ and ‘F’ fields in the northwest Persian Gulf, namely KG-031, F9A-3H and F15-3H for the geochemical study. In this study, the physicochemical properties, gas chromatography (GC, GC Mass) and (Detailed Hydrocarbon Analysis) DHA analyses for the collected Fahliyan oils were carried out. The API, Trace Element (Ni, V) and S% parameters indicated that the Fahliyan oil was generated from a source rock which deposited in reducing environment condition with a carbonate-shale compound lithology. Moreover, low pour point, higher S% and low viscosity parameters of “KG” sample confirmed the existence of medium oil characteristics in this field. In addition, the geochemical outcomes of GC, GC–MS and DHA analyses indicated that the ‘KG’ oils are more aromatic compared with ‘F’ oil; while biomarkers revealed that Fahliyan reservoir oil is highly mature and was formed from a carbonate source rock containing types II, III kerogen. Thus, sterane/hopane biomarkers (C24/C23 and C22/C21 ratios) revealed that Fahliyan oil originated from carbonate source rocks deposited in an anoxic to dysoxic environment, which is consistent with the above analyses. It was identified that the source rock age is early Cretaceous to late Jurassic. It can be reported that the Fahliyan oils from both fields were generated in the same source rock and have almost the same physical properties, and will have the same production strategy.

Novel study on mechanical properties of pack carburizing SCM 420 steel with energizer dog conch

Dog conch shell powder (DCSP) and coconut shell powder (CSP) are used as the calcium carbonate source (energizer) and carbon source, respectively, in the pack carburizing of SCM 420 low carbon steel. The surface hardness of the carburized specimens is investigated for various CSP:DCSP ratios and carburizing temperatures. It is found that a significant improvement in the hardness level is obtained for a DCSP concentration of 40% and a carburizing temperature of 950[Formula: see text]C. It is additionally shown that while DCSP can be used as an energizer in the carburizing process, it cannot be used as an activated carbon source. Finally, it is shown that the surface hardness of the carburized specimens can be significantly improved through a further quenching operation in water. Overall, the results presented in this study confirm the potential for utilizing natural resources such as DCSP and CSP for the pack carburizing of low-to-medium carbon steels.

Method for identifying effective carbonate source rocks: a case study from Middle–Upper Ordovician in Tarim Basin, China

Hydrocarbon expulsion occurs only when pore fluid pressure due to hydrocarbon generation in source rock exceeds the force against migration in the adjacent carrier beds. Taking the Middle–Upper Ordovician carbonate source rock of Tarim Basin in China as an example, this paper proposes a method that identifies effective carbonate source rock based on the principles of mass balance. Data from the Well YW2 indicate that the Middle Ordovician Yijianfang Formation contains effective carbonate source rocks with low present-day TOC. Geological and geochemical analysis suggests that the hydrocarbons in the carbonate interval are likely self-generated and retained. Regular steranes from GC–MS analysis of oil extracts in this interval display similar features to those of the crude oil samples in Tabei area, indicating that the crude oil probably was migrated from the effective source rocks. By applying to other wells in the basin, the identified effective carbonate source rocks and non-source rock carbonates can be effectively identified and consistent with the actual exploration results, validating the method. Considering the contribution from the identified effective source rocks with low present-day TOC (TOCpd) is considered, the long-standing puzzle between the proved 3P oil reserves and estimated resources in the basin can be reasonably explained.