Atomistic-scale analysis of the deformation and failure of polypropylene composites reinforced by functionalized silica nanoparticles

Interfacial adhesion between polymer matrix and reinforcing silica nanoparticles plays an important role in strengthening polypropylene (PP) composite. To improve the adhesion strength, the surface of silica nanoparticles can be modified by grafted functional molecules. Using atomistic simulations, we examined the effect of functionalization of silica nanoparticles by hexamethyldisilazane (HMDS) and octyltriethoxysilane (OTES) molecules on the deformation and failure of silica-reinforced PP composite. We found that the ultimate tensile strength (UTS) of PP composite functionalized by OTES (28 MPa) is higher than that of HMDS (25 MPa), which is in turn higher than that passivated only by hydrogen (22 MPa). To understand the underlying mechanistic origin, we calculated the adhesive energy and interfacial strength of the interphase region, and found that both the adhesive energy and interfacial strength are the highest for the silica nanoparticles functionalized by OTES molecules, while both are the lowest by hydrogen. The ultimate failure of the polymer composite is initiated by the cavitation in the interphase region with the lowest mass density, and this cavitation failure mode is common for all the examined PP composites, but the cavitation position is dependent on the tail length of the functional molecules. The present work provides interesting insights into the deformation and cavitation failure mechanisms of the silica-reinforced PP composites, and the findings can be used as useful guidelines in selecting chemical agents for surface treatment of silica nanoparticles.

An Adaptive Autogram Approach Based on a CFAR Detector for Incipient Cavitation Detection

Cavitation failure often occurs in centrifugal pumps, resulting in severe harm to their performance and life-span. Nowadays, it has become crucial to detect incipient cavitation ahead of cavitation failure. However, most envelope demodulation methods suffer from strong noise and repetitive impacts. This paper proposes an adaptive Autogram approach based on the Constant False Alarm Rate (CFAR). A cyclic amplitude model (CAM) is presented to reveal the cyclostationarity and autocorrelation-periodicity of pump cavitation-caused signals. The Autogram method is improved for envelope demodulation and cyclic feature extraction by introducing the character to noise ratio (CNR) and CFAR threshold. To achieve a high detection rate, CNR parameters are introduced to represent the cavitation intensity in the combined square-envelope spectrum. To maintain a low false alarm, the CFAR detector is combined with the CNR parameter to obtain adaptive thresholds for different data along with sensor positions. By carrying out various experiments of a centrifugal water pump from Status 1 to 10 at different flow rates, the proposed approach is capable of cavitation feature extraction with respect to the CAM model, and can achieve more than a 90% detection rate of incipient cavitation and maintain a 5% false alarm rate. This paper offers an alternative solution for the predictive maintenance of pump cavitation.

Superplasticity and Sinter-Forging of Fine-Grained Si3N4-Si2N2O Composite

The Si3N4- Si2N2O composites are fabricated with amorphous nano-sized silicon nitride powders by the liquid phase sintering(LPS) method in this article. XRD analysis shows that the sintered body consists of β-Si3N4 and Si2N2O. SEM experiment conforms that the average grain size of sintered body is less than 300nm. The superplastic deep-drawing forming can be proceed at a low temperature of 1550°C with a forming velocity of 0.2mm/min. There are only a few small sintered defects before forming, but there are a lot of cavity groups after forming. Cavitation failure occurs by nucleation, growth and interlinkage of cavities. The complex-shape gears can be formed by a sinter-forging technology when the sintering temperature is 1600°C and the superplastic forging temperature is 1550°C.

A Comparative Study of Superplastic Deformation and Cavitation Failure in a Yttria Stabilized Zirconia and a Zirconia Alumina Composite

ABSTRACTA fine grained yttria stabilized zirconia and a zirconia composite containing 20% alumina exhibit superplastic characteristics, with optimum elongations to failure of ≥500%. There is microstructural evidence for deformation enhanced grain growth and concurrent cavitation in both of these superplastic ceramics. Grain sizes after superplastic deformation may be several times larger than the initial grain size, and the level of cavitation can attain values as high as ≥30% under some experimental conditions. This report presents in a comparative format some recent experimental results on the microstructural aspects of superplastic deformation and concurrent cavitation in these superplastic ceramics.