One-step Green Synthesis of Eco-friendly Novel N-P Synergistic Flame Retardant for Cotton Fabric

A novel N-P ammonium salt 1,3-propylene glycol diphosphate ester (APGDPE) flame retardant was tersely synthesized under solvent-free condition to lower cotton fabric fire hazard. The APGDPE structure was characterized by 1H NMR,13C NMR,31P NMR and IR spectroscopy. The reactive P=O(NH4+)2 and PO(OH)2 groups of APGDPE were successfully grafted into cotton fabric to form P-O-C covalent bond. The limiting oxygen indexes (LOI) of 20%, 30% and 40% APGDPE treated cotton reach 40-44.5%. After 50 laundering cycles (LCs), the LOI value of 40% treated cotton still maintains 27.3%. These results verified that the treated cotton has obtained outstanding flame retardancy and prominent durability. TG test indicates that the thermal stability and thermal oxidative stability of treated cotton are much higher than those of control cotton. TG-IR test displayed that treated cotton released less flammable volatile gases than those of control cotton. Cone calorimetry revealed that the PHRR and THR values of treated cotton decreased by 5.57 % and 26.8%,respectively. XRD results suggest that the crystallization zone of cotton fabric before and after treatment hardly change. TG-IR and cone calorimetry tests verified the APGDPE condensation phase mechanism for treated cotton.

Bulk Liquid for the Skaergaard Intrusion and Its PGE-Au Mineralization: Composition, Correlation, Liquid Line of Descent, and Timing of Sulphide Saturation and Silicate–Silicate Immiscibility

Preferred and modelled bulk composition of the Skaergaard intrusion are compared to coeval basaltic compositions in East Greenland and found to relate to the second evolved cycle of Geikie Plateau Formation lavas and coeval Skaergaard-like dikes in major and trace element (Mg# ∼45, Ce/Nb ∼2·5, (Dy/Yb)N ∼1·35), and precious metal composition (Pd/Pt ∼3, Au/Pt ∼2) as well as in age (∼56 Ma). Successful comparisons of precious metal compositions only occur with Skaergaard models based on mass balance. The bulk liquid of the intrusion evolved along the liquid line of descent to immiscibility between Si- and Fe-rich silicate liquids after ∼90% of crystallization (F = ∼0·10) in agreement with experimental constraints. Immiscibility led to accumulation and fractionation of the Fe-rich silicate melt in the mushy floor of the intrusion and continued accumulation of granophyre component in the remaining bulk liquid. The composition of plagioclase in the precious metal mineralized gabbro and modelling of Pd/Pt and Au/Pt in first formed droplets of sulphide melt suggest that sulphide saturation was reached in interstitial melts in crystal mushes in the floor and roof and in bulk liquid with a composition equivalent to that of the bulk liquid at lower UZa times and after crystallization of 82–85% of the bulk liquid (F = 0·19–0·16). Prior to sulphide saturation in UZa type melt, the precious metals ratios of the bulk liquid were controlled by the loss of Pt relative to Pd and Au in agreement with the low empirical and experimental solubility of Pt of ∼9ppb compared to a much higher value for Pd and Au. The relative timing between sulphide saturation (F = ∼0·18) and immiscibility between silicate melts (F = ∼0·10) and modelled precious metal ratios underpin the proposed multi-stage model for the mineralization, advocating initial accumulation in the mushy floor of the magma chamber controlled by sulphide saturation in mush melts rather than bulk melt, followed by redistribution of precious metals in a macro-rhythmic succession of gabbroic layers of the upward migrating crystallization zone.

Morphology of Dried Drop Patterns of Saliva from a Healthy Individual Depending on the Dynamics of Its Surface Tension

Background: The study of processes in the drying drops of biological fluids (dried drop patterns) and the method of dynamic surface tensiometry can be attributed to integral methods of assessing the state of the organism. Research objective: to establish the relationship between the type of crystallization patterns and the surface tension of human saliva in normal conditions. Methods: 100 volunteers (40 males, 60 females) that were aged 30–59 participated in the study. In all saliva samples, the parameters of dynamic tensiometry, types of crystallization patterns and 11 biochemical parameters were determined. Results: No statistically significant differences in the saliva crystallization patterns were observed, depending on the age and gender characteristics of the volunteers. A negative correlation of the area of the crystallization zone and the surface tension of saliva is shown. When considering the crystallization patterns, their considerable variability was noted; on this basis, the entire studied sample was divided into four clusters by surface tension. Conclusion: In general, the crystallization patterns that are inside the selected groups remain quite heterogeneous. This increases the likelihood of making an incorrect diagnosis when using visual methods to evaluate the crystallization patterns, which significantly limits the use of such diagnostic methods in clinical practice.

Influence of Continuous Casting Conditions on Segregation of Additions in EN AW 1350 Aluminum Alloy

Integrated continuous casting processes are an important element of the production process in modern industry. Requirements for quality and exploitation properties of products obtained using continuous casting processes necessitate a revision of the role of impurities distribution in the material. This paper concerns on the influence of the casting process on the distribution of alloy additions. Spectroscopy studies were performed for the most sensitive elements, from the segregation, (i.e. : iron and silicon) point of view. Next obtained research results were correlated with the parameters of chemical composition such as casting speed, the presence of a modifier and the processing of metal crystallization zone. Analysis of the results clearly shows the presence of iron and silicon normal macrosegregation. It was observed that the concentration of these elements is highest in the casting axis and, in the case of iron, is 50% higher in the axis than in the circumference of casts.

Corrosion Products in Cement-Based Materials under Sulfate Partial Soaking Attack

The deterioration mechanism of sulfate attack on cement- based materials under partial soaking condition is very complex. This paper investigated the surface morphology, microstructure and corrosion products in different zones of cement mortar under 5% sulfate solution partial soaking condition at 360 d by methods of SEM, EDS and XRD, respectively. Results show that under partial soaking condition, cement mortar are distinguished four zones – soaking zone, wet zone, crystallization zone and dry zone. Corrosion products in soaking zone and wet zone are predominantly ettringite, showing chemical corrosion take place in those zones. Corrosion products in crystallization zone are gypsum and crystals of Na2SO4 and Na2SO4.10H2O, showing both sulfate chemical corrosion in high concentration and physical crystallization attack occur in this zone. However, there is no any corrosion product founded in dry zone.