Monthmorillonite as an Effective Catalyst of the Polyphenences of Polyphenylene Sulphide

The synthesis of polyphenylene sulfide in the presence of catalytic systems based on montmorillonite and various lithium salts has been studied, and conditions have been identified that accelerate the process and obtain a polymer with a given microstructure. The rheological, thermal, and physicomechanical.

Investigation of mechanical and tribological behaviour of expanded perlite particle reinforced polyphenylene sulphide

In this study, polyphenylene sulphide was used as a matrix material due to its superior engineering properties. Expanded perlite is formed substantially from silica oxides, and it is a volcanic based and porous structure material. Its low price and low density make it very usable as a filler material. For this reason, expanded perlite reinforced polyphenylene sulphide matrix composites were prepared at various weight ratios (0, 1, 3, 5, and 10 wt%). Mechanical and tribological characterizations were done with tensile tests, hardness measurements, solid particle erosion, ball on disc, and scratch tests. According to the tensile test results, a synergistic effect was observed in mechanical properties by using perlite as a reinforcing agent. As expected, perlite reinforcement resulted in an increase in the modulus of 54% in composites. As well as tensile strength of the composite increased by approximately 13%. Furthermore, the perlite particle reinforcement improved the adhesion resistance by 73% and the scratch resistance by 30%. On the other hand, especially at low impact angles, perlite particle reinforcement decreased the erosive wear resistance of the pure polyphenylene sulphide polymer by 50%. Furthermore, expanded perlite reinforcement decreased the plastic deformation ability of polyphenylene sulphide. In consequence of this study, it has been found that expanded perlite particles can be used as an alternative filler instead of conventional reinforcing particles.

Modeling And Performance Analysis of A Centrifugal Impeller of Water Pump

An impeller is a rotating component equipped with vanes or blades used in centrifugal pumps. Flow deflection at the impeller vanes allows mechanical power (energy at the vanes) to be converted into pump power output. Impeller of a centrifugal pump, usually made of iron, steel, bronze, brass, aluminum or plastic, which transfers energy from the motor that drives the pump to the fluid being pumped by accelerating the fluid outwards from the center of rotation. A significant improvement is required for impeller design to resist corrosion, Erosion & weight less. The present work is to design, performance of centrifugal impeller made of Poly-phenylene Sulphide (PPS) and Cast Iron materials and compared the results. Centrifugal impeller is modeled in Solid works, and that model is imported in Ansys-Software, using Ansys-Software we investigated Static and Dynamic behavior of impeller and found that the impeller with Polyphenylene Sulphide (PPS) material is best compared to Cast Iron.

Influence of freeze/thaw cycling on the mechanical performance of resistance-welded carbon fibre/polyphenylene sulphide composite joints

This study evaluates the effects of freeze/thaw cycles on the mechanical performance and failure mode of resistance-welded carbon fibre/polyphenylene sulphide composite joints. Dry and moisture-saturated joints are subjected to 1000 temperature cycles varying between –40°C and 82°C. A silane coating is applied on the stainless steel mesh heating element to improve its adhesion with the polyphenylene sulphide polymer. Results show the limited impact that freeze/thaw cycles have on the lap shear strength of joints welded without any coating on the heating element. The silane coating improves the lap shear strength by 32% when no freeze/thaw cycles are applied to the joints. This improvement of 32% reduces when joints are subjected to freeze/thaw cycles but the mechanical performance remains superior to that of joints welded using uncoated heating element. Fracture surfaces show that fibre/matrix and stainless steel/matrix interfaces are both affected by the environmental conditions although it does not translate into lower lap shear strength.

Stability and Safety Assessment of Phosphorescent Oxygen Sensors for Use in Food Packaging Applications

Five types of new solid-state oxygen sensors, four based on microporous polypropylene fabric materials and one on polyphenylene sulphide films impregnated with phosphorescent platinum(II)-benzoporphyrin dye, were tested for their stability and safety in food packaging applications. All these sensors exhibit useful optical signals (phosphorescence lifetime readout) and working characteristics and are simpler and cheaper to produce and integrate into standard packaging materials than existing commercial sensors. When exposed to a panel of standard food simulants and upon direct contact with raw beef and chicken meat and cheddar cheese samples packaged under modified atmosphere, the sensors based on ungrafted polypropylene fabric, impregnated with PtBP dye by the swelling method, outperformed the other sensors. The sensors are also stable upon storage under normal atmospheric conditions for at least 12 months, without any significant changes in calibration.

Bond Joint Analysis of Thermoplastic Composite Made from Stacked Tailored Blanks

The interlaminar properties of a bond joint of stacked layers in a carbon fibre-reinforced composite with a thermoplastic matrix were evaluated under static loading. The un-precracked tension specimen with an external reinforcing layer was analysed in detail in the area of a bond joint. A detailed finite element method (FEM) analysis was performed to evaluate the influence of the bond joint shape on the interlaminar cohesive forces, which are simulated using the cohesive zone model (CZM). Simple lap and tapered joints were analysed. Continuum and shell elements were utilized in the FEM analysis, and the delamination results obtained using both solutions were compared to each other; however, no significant influence of the bond joint shape on the delamination onset was observed. The FEM analysis was supported using an experimental test on an un-precracked specimen made from prepreg with a carbon fibre fabric and a polyphenylene sulphide (PPS) matrix.