Electrokinetics Application in Concrete and Well Construction

Electrically induced or coupled transport processes including electrophoresis, electroosmosis and electromigration in solutions and porous media under an external electric field have been extensively studied and employed in many disciplines. For protection and rehabilitation of concrete structures, cathodic protection, electrochemical realkalization, and chloride extraction are extensively used. Other electrokinetic techniques are developed for the concrete industry, but have not been widely used so far, including electrokinetic treatment processes, for corrosion mitigation, recovery from sulfate attack, crack healing, and porosity and permeability reduction. These processes can improve the microstructure of the cement-based systems resulting in an improved performance in long-term and can be applied to repair failed structures. Application of electrokinetic processes are rapidly extended in well construction due to the increased interest in techniques enabling manipulation of micro- and nanosized particles. The techniques could be beneficial in building a robust cement sheath in oil and gas wells. Additionally, electrokinetic remediation techniques can possibly be introduced for repairing damaged structures in oil and gas wells. This review provides an overview of electrokinetic-based techniques, which has been introduced to cement-based materials, mainly reinforced concrete. The potential application of these techniques in oil well construction is discussed.

Heat and Mass Transport in Metal Hydride Based Hydrogen Storage Systems

Hydrogen storage technologies based on solid-phase materials involve highly coupled transport processes including heat transfer, mass transfer, and chemical kinetics. A full understanding of these processes and their relative impact on system performance is required to enable the design and optimization of efficient systems. This paper examines the coupled transport processes of titanium doped sodium alanates (NaAlH4, Na3AlH6) enhanced with excess aluminum and expanded natural graphite. Through validated modeling and simulation, we have illuminated transport bottlenecks that arise due to mass transfer limitations in scaled-up systems. Individual heat transport, mass transport, and chemical kinetic processes were isolated and experimentally characterized to generate a robust set of model parameters for all relevant operational states. The individual transport models were then coupled to simulate absorption processes associated with rapid refueling of scaled-up systems. Using experimental data for the absorption performance of a 1.6 kg sodium alanate system, comparisons were made to computed results to identify dominant transport mechanisms. The results indicated that channeling around the compacted porous solid can contribute significantly to the overall transport of hydrogen into and out of the system. The application of these transport models is generally applicable to a variety of condensed-phase hydrogen sorption materials and facilitates the design of optimally performing systems.