Effect of antiblock and slip additives on the properties of tubular quenched polypropylene film

In the present investigation, silica and talc were used as antiblock additives with slip additive to investigate their effects on tubular quenched polypropylene (TQPP) film properties. Polypropylene (PP) powder was compounded with additives in twin-screw extruder and subsequently processed through TQPP machine to prepare the films. Tear and tensile properties [in machine direction (MD) and transverse direction (TD)] and surface properties of the produced TQPP films were investigated in terms of optics and coefficient of friction (CoF). The effect of conditioning time on CoF was also studied. Addition of slip agent alone to PP did not show any significant change in tear strength, CoF and tensile properties, whereas CoF reduced drastically by adding both slip and antiblock agents in combination. Reduction in CoF values were found to be more pronounced in the presence of silica-based antiblock compared to talc-based antiblock. Film surface morphology was further examined by field-emission scanning electron microscopy. The tear strength and the gloss of TQPP film decreased slightly in presence of only antiblock agents, but the tensile strength was found to increase. It was also found that tensile properties of TQPP films were superior in silica-based formulation, whereas tear strength was better in talc-based formulation in MD and TD.

An Environmentally Friendly Recycled-Polyethylene Composite Reinforced by Diatomaceous Earth and Wood Fiber

This study aims to develop a new wood-plastic composite (WPC) material from recycled thermoplasctics. The recycled low-density polyethylene (rLDPE) and high-density polyethylene (rHDPE) were used as matrix, whereas the diatomaceous earth waste (D) and wood fiber (WF) as filler. Recycled-LDPE and rHDPE were recovered and pelletized by a plastic recycling process. The 10-30wt.% diatomaceous earth waste was heat-treated at 200°C to remove impurities. The diatomaceous earth, maleic anhydride grafted polyethylene (MAPE), CaCO3, slip agent, antioxidants and WF were then mixed at 160°C, for 10 minutes, at stirring speed 50 rpm to produce wood-plastic composite material. The mechanical strength and thermal properties of the composites were investigated. The composite containing D and rLDPE results in an increase the hardness of the material which is higher than that of the virgin-LDPE. The tensile and impact strengths of the composite material prepared by rLDPE and D were higher than those of the rHDPE composite material. It is found that LDPE has excellent fluidity, which is helpful for subsequent processing. In addition, the diatomaceous earth waste can be used to reduce the cost of the raw material, and the product has both effects of environmental protection and marketability.

Identification of 24 Unknown Substances (NIAS/IAS) from Food Contact Polycarbonate by LC-Orbitrap Tribrid HRMS-DDMS3: Safety Assessment

Twenty-four substances, mainly NIAS, have been tentatively identified in food contact polycarbonate through the application a new, fast, and automated analytical strategy for the investigation of unknowns in food contact materials. Most of the identified compounds were plasticizers, slip agents, antioxidants, and ultraviolet stabilizers and fragrances, and the majority of them have not been previously identified in PC food contact materials. The workflow setup includes an intelligent data acquisition applied using LC-Orbitrap Tribrid-HRMS (MS3), with an automated data processing using Compound DiscovererTM. To obtain a high confidence identification of unknown substances, a very strict criterion has been established, which comprises exact mass, isotopic profile, MS2 match, retention time, and MS3 match. To check for the safety of the migration from the food contact polycarbonate, a risk assessment was achieved using the threshold of the toxicological concern (TTC) approach. Except for the slip agent hexadecanamide, the compounds tentatively identified do not represent a risk.

Plastic Bottle Cap Recycling—Characterization of Recyclate Composition and Opportunities for Design for Circularity

In line with efforts to create a circular economy of plastics, recent EU legislation is strengthening plastic bottle recycling by ambitious separate collection targets and mandatory recycled content obligations. Furthermore, explicit design requirements on the caps of bottles and composite beverage packaging have been introduced. These caps are typically made of polyethylene or polypropylene and often contain additives such as slip agents and anti-statics. Commercially available bottle cap recyclates (BCRs) as well as specifically formulated model compounds were analyzed in terms of composition by means of infrared spectroscopy, differential scanning calorimetry, and high-performance liquid chromatography. Their composition was found to be heterogeneous due to polyolefin cross-contamination, directly reflecting the diversity of cap materials present in the market. Slip agent legacy additives originating from the initial use phase were found and quantified in both commercial and model cap recyclates. This highlights the opportunity for redesigning plastic bottle caps not only in response to regulatory requirements, but to pursue a more comprehensive strategy of product design for circularity. By including considerations of polymer resin and additive choice in cap manufacturing, more homogeneous waste streams could be derived from plastic bottle cap recycling, enabling recycling into more demanding and valuable applications.

The effect of the addition of a slip agent on the rheological properties of polyethylene: off-line and in-line measurements

The article describes an investigation into the effect of a slip agent on the rheological properties of low-density polyethylene. As a slip modifier, oleamide was used in the amounts of 0.5, 1.0, 2.0, 3.0 and 4.0 wt.%, respectively. The process of polymer modification was carried out in a twin-screw extrusion process. The effect of the slip agent on the mass flow rate index was determined. The specific plasticisation energy of the modified polymer was also assessed based on the change in the torque of a batch mixer. The assessment of the effect of the addition of oleamide on the change in the flow and viscosity curves was made using an off-line (plastometer) and an in-line (extruder rheometer) measuring technique. The rheological parameters were determined based on the Ostwald-de-Waele power law model. The operation of the plastometer was brought closer to the principles of operation of the capillary rheometer by applying variable piston loading. In in-line measurements, an extrusion head with replaceable cylindrical dies was used. Using two rheological measuring techniques made it possible to determine the low-density polyethylene viscosity variations and the values of flow power law index (n) and consistency factor (K) in a wide shear rate range.