rearrangement effect
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A theoretical study of the sulfenate-sulfoxide rearrangement. Effect of the hydrogen bond complexation

2010 ◽  
Vol 110 (13) ◽  
pp. 2391-2397 ◽  
Author(s):  
Krzysztof K. Zborowski ◽  
Ibon Alkorta ◽  
José Elguero
Keyword(s):  
Hydrogen Bond ◽  
Theoretical Study ◽  
Rearrangement Effect

The Effect of Water on Proton Transfer in Pyrazole

1977 ◽  
Vol 32 (11-12) ◽  
pp. 891-893 ◽  
Author(s):  
V. N. Babin ◽  
E. B. Zavelovich ◽  
Yu. A. Belousov
Keyword(s):  
Transition Metal ◽  
Proton Transfer ◽  
Metal Ions ◽  
Transition Metal Ions ◽  
Water Molecules ◽  
Effect Of Water ◽  
Rearrangement Effect

Abstract An NMR 13C study has shown that proton rearrangement in pyrazole is decreased by adding small amounts of water to the sample. Single water molecules as coordination centres pertrub the mechanism of cooperative proton transfer occurring in pyrazole selfassociates. The decrease of the rearrangement effect due to water is similar to the action of transition metal ions studied by the authors earlier.

Stereochemical and mechanistic aspects of the di-.pi.-methane rearrangement. Effect of structural constraints which preclude preferred modes

1976 ◽  
Vol 98 (19) ◽  
pp. 5899-5906 ◽  
Author(s):  
Patrick S. Mariano ◽  
Richard B. Steitle ◽  
Darrel G. Watson ◽  
Michael J. Peters ◽  
Elliott Bay
Keyword(s):  
Structural Constraints ◽  
Rearrangement Effect

Corrections to coupled Hartree-Fock theory: the rearrangement effect

1975 ◽  
Vol 9 (3) ◽  
pp. 385-392 ◽  
Author(s):  
A. K. Bhattacharya ◽  
R. K. Moitra ◽  
A. Mukherji
Keyword(s):  
Hartree Fock ◽  
Rearrangement Effect
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