Free-Space Nonreciprocal Transmission Based on Nonlinear Coupled Fano Metasurfaces

Optical nonlinearities can enable unusual light–matter interactions, with functionalities that would be otherwise inaccessible relying only on linear phenomena. Recently, several studies have harnessed the role of optical nonlinearities to implement nonreciprocal optical devices that do not require an external bias breaking time-reversal symmetry. In this work, we explore the design of a metasurface embedding Kerr nonlinearities to break reciprocity for free-space propagation, requiring limited power levels. After deriving the general design principles, we demonstrate an all-dielectric flat metasurface made of coupled nonlinear Fano silicon resonant layers realizing large asymmetry in optical transmission at telecommunication frequencies. We show that the metrics of our design can go beyond the fundamental limitations on nonreciprocity for nonlinear optical devices based on a single resonance, as dictated by time-reversal symmetry considerations. Our work may shed light on the design of flat subwavelength free-space nonreciprocal metasurface switches for pulsed operation which are easy to fabricate, fully passive, and require low operation power. Our simulated devices demonstrate a transmission ratio >50 dB for oppositely propagating waves, an operational bandwidth exceeding 600 GHz, and an insertion loss of <0.04 dB.

Large asymmetry in the magnetoresistance loops of ferromagnetic nanostrips induced by Surface Acoustic Waves

In this work we show that Surface Acoustic Waves (SAW) can induce a very large asymmetry in the magnetoresistance loop of an adjacent ferromagnetic nanostrip, making it look as if it had exchange bias. The Surface Acoustic Wave induces a DC voltage in the ferromagnetic nanostrip. For measurements at constant current, this DC voltage makes the AMR loop asymmetric. In a series of different electrical experiments, we disentangle two different contributions to the induced DC voltage. One of them is independent on the external magnetic field and it is likely due to the acoustoelectric effect. A second contribution depends on the external magnetic field and it is a rectified voltage induced in the piezoelectric substrate as a response to the magnetization dynamics in the magnetostrictive nanostrip. The large asymmetry in the magnetoresistance loop reported in this work is a manifestation of an effective transfer of energy from the SAW to the magnetization dynamics, a mechanism that has been very recently appointed as a possible mean to harvest energy from a heat source.

Surface and Microstructure Analysis of CoCrPt Film on RuCoCrX (X = Ti, Re) Intermediate Layers

The microstructural and magnetic properties of perpendicular anisotropic CoCrPt films deposited on Ru or RuCoCrX (X = Ti, Re) intermediate layers were studied. The c-axis of CoCrPt grains were promoted by (0002) textured RuCoCr, and RuCoCrX (X = Ti, Re) intermediate layers due to smaller lattice misfit as compared to Ru. The narrower rocking width (Δθ50 = 3.76°) in RuCoCrRe intermediate layer and CoCrPt shows higher out of plane coercivity (Hc = 6.2 kOe), magnetic anisotropy constant (Ku = 6.2 × 106 erg/cm3) and nucleation field (HN = −2.8kOe) as compared to the Ru intermediate layer (Hc = 5.4 kOe, Ku = 5.9 × 106 erg/cm3, HN = −1.6 kOe). The partial intergranular exchange decoupling of CoCrPt grains was observed. The grain boundaries oxides were formed by the residual oxygen in targets and sputtering processes. The minor Cr2O3, CoO, TiO2, ReO3 oxides were investigated by surface analysis. Due to the minor oxides and Cr segregation at grains boundaries, the CoCrPt films present high coercivity. Samples CoCrPt/RuCoCr and CoCrPt/RuCoCrTi present a minimum at 45° but the values are much higher than the ideal Stoner-Wohlfarth theoretical value 0.5 which could be due to fewer natural oxides for magnetic grains separation. In sample CoCrPt/RuCoCrRe, there is an increase of intergranular interaction as indicated by the large asymmetry and the shift of the minimum at lower angles.

Anomalous Behaviors of Spin Waves Studied by Inelastic Light Scattering

Magnonics, an emerging research field, aims to control and manipulate spin waves in magnetic materials and structures. However, the current understanding of spin waves remains quite limited. This review attempts to provide an overview of the anomalous behaviors of spin waves in various types of magnetic materials observed thus far by inelastic light scattering experiments. The anomalously large asymmetry of anti-Stokes to Stokes intensity ratio, broad linewidth, strong resonance effect, unique polarization selection, and abnormal impurity dependence of spin waves are discussed. In addition, the mechanisms of these anomalous behaviors of spin waves are proposed.

The Role of Multiple Pollutants and Pollution Intensities in the Policy Reform of Taxes and Standards

Countries with varying degrees of pollution intensities, facing increasing global competition and addressing emissions from multiple pollutants may undertake policy reforms inconsistent with cooperative outcomes, where global welfare is higher. Among others, this is because of the incentives to set laxer policy to be more cost competitive. A number of welfare-enhancing and emissions-reducing policy reforms consistent with the cooperative equilibrium, but also consistent with addressing concerns about global competitiveness are derived. The analysis indicates that the nature of multiple pollutants and asymmetries in pollution intensities are key in the design of policy reform and characterization of optimal policy. With complementarity and asymmetry in pollution intensities, laxer taxation and stricter standards are consistent with welfare gains. Laxer taxation arises with large asymmetry in pollution intensities regardless of whether pollutants are complements/substitutes. The policy reform of standards requires both complementarity and asymmetry in pollution intensities. Results are reversed if pollutants are substitutes.

Upper Critical Solution Temperature (UCST) Behavior of Coacervate of Cationic Protamine and Multivalent Anions

Complex coacervation is an emerging liquid/liquid phase separation (LLPS) phenomenon that behaves as a membrane-less organelle in living cells. Yet while one of the critical factors for complex coacervation is temperature, little analysis and research has been devoted to the temperature effect on complex coacervation. Here, we performed a complex coacervation of cationic protamine and multivalent anions (citrate and tripolyphosphate (TPP)). Both mixtures (i.e., protamine/citrate and protamine/TPP) underwent coacervation in an aqueous solution, while a mixture of protamine and sodium chloride did not. Interestingly, the complex coacervation of protamine and multivalent anions showed upper critical solution temperature (UCST) behavior, and the coacervation of protamine and multivalent anions was reversible with solution temperature changes. The large asymmetry in molecular weight between positively charged protamine (~4 kDa) and the multivalent anions (<0.4 kDa) and strong electrostatic interactions between positively charged guanidine residues in protamine and multivalent anions were likely to contribute to UCST behavior in this coacervation system.

New orientations of the Cooper pair momentum in FFLO state for asymmetric D-wave fermion superfluids

The Fulde–Ferrell–Larkin–Ovchinnikov (FFLO) state in asymmetric D-wave fermion superfluids is investigated generally. The angle dependence of the pairing gap (angle-dependent gap) for D-wave is also considered. Except the two special orientations of the Cooper pair momentum which are parallel/orthogonal to the symmetry-axis of ADG (called as FFLO-ADG-O and FFLO-ADG-P states), new orientations of the Cooper pair momentum between the two special ones are also found. These new orientations of the Cooper pair momentum correspond to new possible locally stable state (defined as FFLO-ADG-B state). Furthermore, the FFLO-ADG-O state is favored for small asymmetry and the FFLO-ADG-P state is located at large asymmetry, whereas the FFLO-ADG-B state is stable for moderate asymmetry. Moreover, the range of the asymmetry where the superfluids exists is enhanced strongly by taking the ADG to the FFLO state.

Capacitive Performance of Water-in-Salt Electrolyte in Supercapacitors: a Simulation Study

<div>Water-in-salts is a new family of electrolytes with very promising electrochemical properties for energy storage applications. Despite several studies involving them inside Li-ion batteries and supercapacitors, their interfacial properties remain largely unknown. Here we simulate the interface between electrified graphite electrodes and a highly concentrated waterin- salt (where the salt is Bis(trifluoromethane)sulfonimide lithium, LiTFSI) using constant applied potential molecular dynamics. We show that the capacitance differs markedly between the positive and the negative electrodes, which is due to the large asymmetry in size (and</div><div>shape) between the ions. By using importance sampling, we further investigate the changes in the structure of the salt at the interface and we observe that large variations occur, that are at</div><div>the origin of a series of peaks in the differential capacitance.</div>