Mechanisms of the copper third body as an interfacial media on copper matrix friction materials with different compositions

Purpose This paper aims to reveal the effects of the copper third body on different copper matrix friction materials with a novel experimental way called “exogenous powder.” Design/methodology/approach An accurate adding device of exogenous copper powder was designed to control the flow rate. The tribological properties with and without exogenous copper powder were investigated by a pin-on-disc tribometer during dry sliding. Findings Experimental results indicate that the Cu addition tends to increase the friction coefficient. For pure Cu material, the exogenous copper third body exhibits poor fluidity on the friction surface, causing serious adhesive wear on the friction interface. For the Cu 90% + 10% Gr material, the plasticity of exogenous copper powder may intensify the deformation of the third body of the surface, presenting layered accumulation distribution. For the pure Cu and Cu 95% + 5% SiO2 material, the Cu addition makes the composition and density of the third body uneven in the direction of depth. Originality/value The role of the copper component on different materials is revealed from a new perspective, and the relationship between the third body structure and the friction properties is explored.

Fabrication and Characterization of Ni60A Alloy Coating on Copper Pipe by Plasma Cladding with Induction Heating

Plasma cladding coupled induction heating was developed and successfully used to fabricate Ni60A coating on the surface of copper pipe. By matching the swing arc with the rotating copper pipe, the cladding efficiency was as high as 32.72 mm2/s. From the head to the tail of the coating, the wear resistance changed from 4.5 to 1.8 times that of pure copper. During the cladding process with constant current, the surface temperature of the cladding zone and the bath depth gradually increased. The corresponding dilution ratio increased, accompanied by the widening of the interface transition zone and the growth of precipitated phases (CrB and Cr23C6). Due to the gradient change of composition, the coating can be regarded as an in situ synthesized gradient coating. The critical point of sudden change of temperature in cladding zone was 850 °C, at which point the wear mechanism changed from abrasive wear to adhesive wear. The proper surface temperature of cladding zone should be controlled within 600–850 °C, which can be achieved by matching the cladding current and induction heating power. Results indicated that plasma cladding coupled induction heating is a potentially effective method to prepare high-quality coating on the surface of a large-complex-curved copper component.

Tube Drawing with Tilted Die: Texture, Dislocation Density and Mechanical Properties

Anisotropic behavior is a key characteristic for understanding eccentricity in tubes. In this paper, the effect of using a tilted die during tube drawing on eccentricity, texture, dislocation density, and mechanical properties is shown. Copper tubes were drawn with a ±5° tilted die for two passes. The increase or decrease in eccentricity can be controlled by controlling the angle of the tilted die. Two types of textures have been developed during tube drawing, namely plane strain and uniaxial types. Plain strain type texture is mainly characterized by the β fiber with a dominant copper component {112}<111>. The uniaxial deformation type is dominated by the <111> fiber, as commonly found by wire drawing. Texture sharpness increases with increasing drawing strain, and the texture varies significantly between the maximum and minimum wall thickness. This texture variation between maximum and minimum wall thickness has no significant influence on mechanical properties, which are more or less similar, but the increase in strength after each drawing pass is apparent. The dislocation density is low for the as-received tubes due to recovery and recrystallization. This is consistent with the as-received texture dominated by the cube component {001}<100>. During tube drawing, dislocation density increases as a function of the deformation strain. The variation of dislocation density between the maximum and minimum wall thickness in the tube deformed with −5° tilted die is higher than the variation in the tube deformed with +5° tilted die.

A Highly Efficient Heterogeneous Catalyst of Bimetal-Organic Frameworks for the Epoxidation of Olefin with H2O2

A series of bimetel organic framework MnxCu1−x-MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The catalytic activity of the developed catalyst was tested on various olefins by H2O2 as oxidant. The MOFs catalyst exhibits excellent catalytic activity for the epoxidations of various aromatic and cyclic olefins. Particularly, Mn0.1Cu0.9-MOF can achieve 90.2% conversion of styrene with 94.3% selectivity of styrene oxide at 0 °C after reaction 6 h. The MOF exhibited the catalytic activity of inverse temperature effect on epoxidation of styrene. The introduction of copper component can stabilize H2O2 and inhibit its decomposition to a certain extent. The catalyst can be reused at least five cycles without significant loss in activity towards epoxidation.

Separation of Ag and Cu from Their Aqueous Thiosulfate Complexes by UV-C Irradiation

In recent years, there has been renewed interest in the use of thiosulfate as a substitute for cyanide in silver leaching. Copper thiosulfate leaching without ammonia was applied to extract silver from silver sulfide, resulting in the production of Ag–Cu polymetallic thiosulfate complexes in solutions. It is necessary to separate Ag–Cu polymetallic thiosulfate complexes with the purposes of silver recovery and copper recycling. In this paper, the feasibility study on the use of UV-C irradiation to separate Ag–Cu polymetallic thiosulfate complexes was investigated based on the different photosensitivity of silver and copper. First, a kinetic study on the photolysis of silver and copper thiosulfate complexes by UV-C was investigated, indicating that the reactions follow first-order kinetics. The rate constant reactions were calculated, and it decreased with solution concentrations. On the other hand, the photoproducts of the silver and copper thiosulfate complexes were characterized by XRD and XPS in order to confirm the phase and chemical composition. It indicated that the silver photoproducts are Ag2S, S, Ag and the copper photoproducts are Cu2S, CuS, CuO, Cu, S. Finally, the four-step continuous separation of Ag–Cu polymetallic thiosulfate complexes by UV-C irradiation was investigated. The silver component was recovered with the accumulated recovery ratio of 97%, and the copper component was recycled with the accumulated recycle ratio of 51%, which made it possible for silver recovery and copper recycling.

Synthesis of Hexagonal Diamond under Shock Loading Using Single Stage Powder Gun

Hexagonal diamond is considered to be a metastable high-pressure phase of carbon. In previous ab-initio studies, elastic constants of hexagonal diamond were suggested to be higher than those of cubic diamond, which is the stiffest known material. However, the elastic constants of hexagonal diamond have not been investigated experimentally because the size of hexagonal diamond single crystal ever synthesized is not more than 0.5 μm. In this study, we synthesized hexagonal diamond with the size of more than 50 μm in order to measure the elastic constants accurately. Kish graphite powder was used as a starting material and a green compact of kish graphite and copper powder was fabricated as a target. The target was placed into a container made of stainless steel and shock-compressed by a copper projectile accelerated using a single stage powder gun with the velocity of approximately 800 m/s. The estimated shock pressure and temperature were 22 GPa and 1200 °C, respectively. After the shock compression, copper component of the target was dissolved in nitric acid for 24 hours and only carbon component was recovered. A clear (100) peak of hexagonal diamond was observed by a XRD result of the recovered carbon. No peak of cubic diamond was observed. Opaque particles including hexagonal diamond with the size of approximately 100 μm were separated from the graphite and SiO2 contaminations using heavy-liquid separation method with sodium polytungstate aqueous solution.